• Title/Summary/Keyword: Fine-particle

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Preparation and Characterization of Fine $TiO_2$ Powders by Vapor-Phase Hydrolysis of TiCl4 (사염화티타늄의 기상가수분해반응에 의한 $TiO_2$ 미분의 제조 및 입자특성)

  • 염선민;김광호;신동원;박찬경
    • Journal of the Korean Ceramic Society
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    • v.29 no.7
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    • pp.525-532
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    • 1992
  • TiO2 fine powder was synthesized in the gas phase by chemical vapor deposition using hydrolysis of TiCl4. Content of rutile phase in the powder was investigated. Powder characteristics such as size, crystallinity and morphology were also studied by means of TEM, SEM and XRD. Rutile phase in TiO2 powder started to be formed from 100$0^{\circ}C$ and the content increased with the reaction temperature and TiCl4 concentration. As the temperature increased from 80$0^{\circ}C$ to 140$0^{\circ}C$, the primary particle size increased while secondary particle size decreased. Spherical secondary particle with fine primary crystals agglomerated was produced at low temperature of 80$0^{\circ}C$ whereas the grown primary particle being final particle size was produced at higher temperature of 140$0^{\circ}C$. Other effects of TiCl4 and H2O partial pressures on particle size were also reported in this study.

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Effects of Particle Size of Barley on Intestinal Morphology, Growth Performance and Nutrient Digestibility in Pigs

  • Morel, P.C.H.;Cottam, Y.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.11
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    • pp.1738-1745
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    • 2007
  • A growth trial and a digestibility trial were conducted to examine the effect of feed particle size on the performance, nutrient digestibility, gastric ulceration and intestinal morphology in pigs fed barley-based diets. Barley was processed through a hammer mill to achieve four diets varying in particle size (average particle $size{\pm}standard $deviation): coarse ($1,100{\pm}2.19\;{\mu}m$), medium ($785{\pm}2.23\;{\mu}m$), fine ($434{\pm}1.70\;{\mu}m$) and mixed (1/3 of coarse, medium and fine) ($789{\pm}2.45\;{\mu}m$). Sixty-four entire male pigs were used in the growth trial and the diets were fed ad libitum between 31 kg and 87 kg live weight. Following slaughter, stomach and ileal tissues were scored for integrity (ulceration or damage) and histological measurements taken. Twenty-four entire male pigs were used in the digestibility trial, which involved total faecal collection. Over the entire growth phase, there were no differences (p>0.05) in average daily gain and feed conversion ratio between pigs fed diets of different particle size. Pigs fed the coarse and medium diets had lower (p<0.05) stomach ulceration scores (0.20 and 0.25, respectively, on a scale from 0 to 3) than those fed the mixed (0.69) or the fine diets (1.87). The stomachs of all animals fed the fine diet had lesions and stomach ulcerations were present only in this group. Pigs fed the fine diet had thicker (p<0.001) ileal epithelial cell layer with no differences (p>0.05) being observed for villous height or crypt depth. Faecal digestibility coefficients of neutral and acid detergent fibre were the highest (p<0.05) for the mixed diet, intermediate for the fine and coarse diets and the lowest for the medium diet. A similar numerical trend (p = 0.103) was observed for the apparent faecal energy digestibility coefficient. It is concluded that, with barley based diets, a variation in average particle size between $400{\mu}m$ and $1,100{\mu}m$ had no effect on pig performance but the fine dietary particle size affected the integrity of the stomach, as well as the structure of the small intestine, thus compromising overall gut health. Our data also demonstrate that changes in particle size distribution during the digestion process, rather than average particle size or particle size variation, are related to apparent faecal digestibility.

Characterizations of fine Bi-2223 precursor powder by spray pyrolysis process (분무 열분해법으로 제조된 미세 Bi-2223 전구분말의 특성)

  • Kim S. H.;Yoo J. M.;Ko J. W.;Kim Y. K.
    • Progress in Superconductivity
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    • v.6 no.2
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    • pp.124-128
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    • 2005
  • Homogeneous and fine powders for Bi-2223 tape were prepared by ultrasonic spray pyrolysis (SP) method from an aqueous solution of metal nitrates. Bi-2223 precursor powders were synthesized with various solutes concentration and pyrolysis temperature. The synthesized precursor powders had a narrow particle size distribution and an average particle size was $\~{\cal}um$. The reactivity of precursor powder by SP method is very high, attributed to the fine and narrow particle size distribution. Bi-2223/Ag tape was prepared using PIT method and followed by various sintering conditions. The precursor powder by SP method promoted a very quick formation of the Bi-2223 phase for short sintering time while the secondary phase such as large AEC phase and $Ca_2PbO_4$ were minimized for SP tapes.

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Physical Characteristics of Aerosol Concentrations Observed in an Urban Area, Busan (부산 도심지에서 측정된 에어로졸 농도의 물리적 특성)

  • Kim, Yun-Jong;Kim, Cheol-Hee
    • Journal of Environmental Science International
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    • v.19 no.3
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    • pp.331-342
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    • 2010
  • Aerosol physical properties have been measured at Pusan National University by using the 16-channel LPC(Laser Particle Counter), and particle characteristics have been examined for the period from Aug. 4 2007 to Dec. 30, 2008. Annual total average, seasonal average, and other averages of the meteorologically classified four categories such as Asian dust, precipitation, foggy, and clear days are respectively described here. Both annually and seasonally averaged number concentration show three peaks at the particle diameter of 0.3, 1.3, and $4{\mu}m$, respectively. However, the first peak for summer season tends to be shifted toward smaller size than other seasons, implying the strong fine particle generation. Meteorological condition shows strong contrast in aerosol concentrations. In Asian dust case, relatively lower number concentrations of fine particles (i.e., smaller than $0.5{\mu}m$) were predominant, while higher concentrations of coarse particles were found particularly for the size bigger than $0.5{\mu}m$. In precipitation day, number concentrations were decreased by approximately 30% due to the removal process of precipitation. Foggy day shows significantly higher concentrations for fine particles, implying the importance of the aerosol condensation process of micro-fine-particle growing to fine-particle. Finally the regressed particle size distribution function was fitted optimally with two log-normal distribution, and discussed the similarities and differences among four categorized cases of the Asian dust, precipitation, foggy, and clear days.

FE-simulation of Drawing Process for Al-1%Si Bonding Wire Considering Fine Si Particle (미세 Si 입자를 고려한 Al-1%Si 본딩 와이어의 신선공정해석)

  • Ko, D.C.;Hwang, W.H.;Lee, S.K.;Kim, B.M.
    • Transactions of Materials Processing
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    • v.15 no.6 s.87
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    • pp.421-427
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    • 2006
  • Drawing process of Al-1%Si bonding wire considering fine Si particle is analyzed in this study using FE-simulation. Al-1%Si boding wire requires electric conductivity because Al-1%Si bonding wire is used for interconnection in semiconductor device. About 1% of Si is added to Al wire for dispersion-strengthening. Distribution and shape of fine Si particle have strongly influence on the wire drawing process. In this study, therefore, the finite-element model based on the observation of wire by continuous casting is used to analyze the effect of various parameters, such as the reduction in area, the semi-die angle, the aspect ratio, the inter-particle spacing and orientation angle of the fine Si particle on wire drawing processes. The effect of each parameter on the wire drawing process is investigated from the aspect of ductility and defects of wire. From the results of the analysis, it is possible to obtain the important basic data which can be guaranteed in the fracture prevention of Al-1 %Si wire.

Monthly Variation in the Salmonella Mutagenicity by Suspended Particulate according to Particle Size in Seoul City (서울시 대기중 부유분진의 입도별 돌연변이원성의 월변화)

  • Jang, Jae-Yeon;Kim, Bak-Kwang;Jo, Seong- Joon;Chung, Yong
    • YAKHAK HOEJI
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    • v.32 no.5
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    • pp.362-369
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    • 1988
  • Monthly variation of mutagenicity by airborne particulate were studied according to particle size of the particulate. Airborne particulates were collected in Shinchon of Seoul which is commocial and traffic area in 1986. And those were separately collected into two parts such as fine particle (less than $2.5{\mu}m$ aerodynamic diameter) and coarse particle (greater than $2.5{\mu}m$). Extractable organic matters(EOM) were extracted and mutagenicity of the EOM was tested in Salmonella thyphimurium TA 98 by Ames method. While the concentration of coarse particle did not show the seasonal variation, that of fine particle showed great seasonal variation. The contents and mutagenicity of EOM in fine particles were higher than those of coarse particles. So fine particles were expected to contribute to the 90% of mutagenicity in atmosphere by suspended particulates. The content of EOM and mutagenicity by suspended particulates in atmosphere were highest in January all the year around and also higher as much as 6 and 30 times than in July, respectively.

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Performance Evaluation of Gas Cleaning Industrial Filters using a Bi-Modal Test Aerosol for Dust Loading Studies

  • Lee, Jae-Keun;Kim, Seong-Chan;Benjamin Y.H. Liu
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.131-137
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    • 1996
  • Typical size distribution of emission particulates is bi-modal in shape with particles in the fine mode (< 2.0 $\mu\textrm{m}$) and the coarse mode. An experimental study of pressure drop across the industrial gas cleaning filters has been conducted using particle mixture of fine alumina and coarse Arizona dusts with a rotating aerosol disperser to generate the bi-modal test aerosol. Pressure drop increased linearly with increasing mass loading. The pressure drop was found to be strongly dependent upon the mass ratio of fine to coarse particles. The smaller the mass ratio of fine to coarse particles and the higher face velocity are, the faster pressure drop rises. The fine particles and the greater inertia of the particle moving fast would cause a denser cake formation on the filter surface, resulting in a greater specific resistance to the gas flow.

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Influence of Atomizing Condition on Particle Size Distributions for High Pressure Water Atomized Powder

  • Nakabayashi, Koei;Tanaka, Yoshinari;Hirai, Masazumi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.18-19
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    • 2006
  • To improve the properties of fine metal powder, such as particle size distribution and geometric standard deviation, this work was done at various atomizing conditions. The new atomization mechanism and the correlation equation were proposed to estimate the mean particle diameter.

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Visibility Impairment by Atmospheric Fine Particles in an Urban Area

  • Kim, Young J.;Kim, Kyung W.
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.E3
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    • pp.99-120
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    • 2003
  • Visibility impairment in an urban area is mainly caused by airborne fine particulate matters. Visibility in a clean air environment is more sensitive to the change of PM$_{2.5}$ particle concentrations. However, a proportionally larger reduction in fine particle concentration is needed to achieve a small increment of visibility improvement in polluted areas. Continuous optical monitoring of atmospheric visibility and extensive aerosol measurements have been made in the urban atmosphere of Kwangju, Korea. The mean for fine particulate mass from 1999 to 2002 at Kwangju was measured to be 23.6$\pm$20.3 $\mu\textrm{g}$/㎥. The daily average seasonal visual range was measured to be 13.1, 9.2, 11.0, and 13.9 km in spring, summer, fall, and winter, respectively. The mean light extinction budgets by sulfate, nitrate, organic carbon, and elemental carbon aerosol were observed to be 27, 14, 22, and 12%, respectively. It is highly recommended that a new visibility standard and/or a fine particle standard be established in order to protect the health and welfare of general public. Much more work needs to be done in visibility studies, including long-term monitoring of visibility, improvement of visibility models, and formulating integrated strategies for managing fine particles to mitigate the visibility impairment and climate change.e.