• Title/Summary/Keyword: Fine powder

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Manufacture of Ordinary Portland Cement Clinker Using Cement Paste of the Waste Concrete (폐콘크리트로부터 회수된 시멘트 페이스트 미분말의 시멘트 원료화 연구)

  • Ahn, Ji-Whan;Kim, Hyung-Seok;Cho, Jin-,Sang;Han, Gi-Chun;Han, Ki-Suk;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.804-810
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    • 2003
  • The fine powder produced by heating and grinding of the waste concrete in the waste construction was investigated whether utilize as substitution raw material of SiO$_2$, CaO, and Al$_2$O$_3$ source for OPC clinker manufacture is possible or not. In order to synthesize OPC clinker, limestone, shale, converter slag and fly ash were used as main raw materials, and modulus was fixed LSF 91.0, SM 2.60, IM 1.60. The synthesized clinkers were characterized. The Main products of synthesized clinker were C$_3$S, ${\beta}$-C$_2$S, C$_3$A, C$_4$AF as OPC clinker at 1,43$^{\circ}C$. As a result of TG-DTA and burnability index(B.U) analysis of each raw mixtures, the formation temperature of clinker phases was similar and B.I was showed easy burning as 48.6∼51.4.

Synthesis and characterization of Mg-Si thermoelectric compound subjected to mechanical alloying (기계적 합금화에 의한 Mg-Si계 열전화합물의 합성 및 평가)

  • Lee, Chung-Hyo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.121-127
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    • 2007
  • We have applied mechanical alloying (MA) to get $Mg_2Si$ thermoelectric material with nano-sized grains. An optimal milling and heat treatment conditions to obtain the single phase of $Mg_2Si$ compound with fine microstructure were investigated by X-ray diffraction and differential scanning calorimetry (DSC) measurement. The $Mg_{66.7}Si_{33.3}$ MA samples ball-milled for $20{\sim}180\;hrs$ exhibit two broad exothermic heat releases around $220^{\circ}C$ and $570^{\circ}C$. On the other hand, MA sample ball-milled far 260 hrs exhibits only a sharp exothermic peak at $230^{\circ}C$ Single phase Mg2Si powder can be obtained by MA of $Mg_{66.7}Si_{33.3}$ mixture for 60 hours and subsequently heated up to $620^{\circ}C$. Sintering of the MA powders was performed in a spark plasma sintering (SPS) machine using graphite dies at $800{\sim}900^{\circ}C$ under 50 MPa. The shrinkage of sintering sample during SPS was significant at about $200^{\circ}C$. All compact bodies have a high relative density above 94% with metallic glare on the surface.

Effect of SiC Particle Size on the Microstructure and Mechanical Properties Of Al2O3-SiC Composite (Al2O3-SiC 복합재료의 미세조직 및 기계적 물성에 미치는 SiC 원료분말의 크기 영향)

  • 채기웅
    • Journal of the Korean Ceramic Society
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    • v.41 no.2
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    • pp.125-130
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    • 2004
  • The effect of SiC particle size on the microstructures and mechanical properties of A1$_2$O$_3$-SiC composite was investigated. Two types of SiC powders having average particle sizes of 0.15 ${\mu}{\textrm}{m}$ and 3 ${\mu}{\textrm}{m}$ were used. The grain growth in the specimen containing 0.15 ${\mu}{\textrm}{m}$ SiC was effectively inhibited due to the fine SiC particles. However, after the formation of some abnormal grains, fast and exaggerated grain growth occurred which led to the microstructure of large grains with irregular shape. Fracture strength decreased due to the abnormal large grains. On the other hand, for specimen containing 3 ${\mu}{\textrm}{m}$ SiC showed normal grain growth behavior from initial sintering stage. Large SiC particles, however, effectively inhibited exaggerated grain growth after nucleation of a few abnormal grains. As a consequence, microstructure consisted of homogeneous elongated grains. In the A1$_2$O$_3$-2.5SiC(0.15 ${\mu}{\textrm}{m}$)-2.5SIC(3 ${\mu}{\textrm}{m}$) composite fabricated by mixing the two types of SiC powder, abnormal grain growth occurred. However, the good fracture strength was maintained regardless of microstructural changes in this specimen.

Anticancer Activity and Quantitative Analysis of Glucosinolates from Green and Red Leaf Mustard (청갓과 적갓에 함유된 Glucosinolates의 항암 활성 및 정량 분석)

  • Kim, Hwal;Kim, Jun-Yeol;Kim, Hyo-Jin;Kim, Do-Kyung;Jo, Hye-Jin;Han, Byoung-Su;Kim, Heon-Woong;Kim, Jung-Bong
    • The Korean Journal of Food And Nutrition
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    • v.24 no.3
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    • pp.362-366
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    • 2011
  • The objective of this study was to compare the anticancer activity of glucosinolates against four different cancer cells; SNU-251, SNU-354, SNU-C4, MCF-7 and to determine the amounts of glucosinolates in mustard leaves. Green and red mustard leaves were cultivated on the field of Rural Development Administration from May to July, 2010. After the leaves were harvest and lypophilized, the fine powder was extracted with boiling 70% methanol(v/v) for the measurement of anticancer activity and then applied to the cancer cells obtained from Korean Cell Line Bank(KCLB). The anticancer activity of red leaf mustard was higher than that of green mustard leaf, particularly in SNU-251 for 24 hr and in SNU-C4 for 48 hr. In both green and red mustard leaf, sinigrin was the most abundant glucosinolte and was determined as 4.71 and 3.06 mg/g dry wt., respectively, but glucoiberin only presented 0.14 mg/g dry wt. with minor amounts.

Analysis of influential factors on respiratory symptoms of nail shop workers

  • Kim, Jung-ae;Kim, Su-min
    • International Journal of Advanced Culture Technology
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    • v.5 no.3
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    • pp.24-34
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    • 2017
  • Nail art is a kind of nail painting or decoration that adds to the beauty. Throughout making nail art, the worker was on a dusty operation with the smoothing of chemicals and nails. People working at nail shops not only use a variety of chemicals, but also experience a lot of fine powder during the process of nail trimmings. While drying the chemical adhesive, the workers often complain of eye, nose and throat discomfort. In addition, the acrylic brush is characterized by a lot of smell when washed with washing solution. Also nail art workers directly influence the worker's breathing through the work done by placing the guest's hands in a work space called a nail table. Chemical ingredients used in nail art procedures include acetone, ethyl acetic acid, toluene, butyl acetic acid, glue, and top coating of nail varnishes. Prolonged inhalation of these substances may cause dizziness, vomiting, as well as impaired respiratory system. The purpose of this study is to investigate the respiratory symptoms of nail shop workers who are likely to be affected by work in nail shop and to find out which factors have the greatest influence if they have respiratory symptoms. Therefore this study is to provide basic data on the health management system of people engaged in nail shop and to develop health education program. For this study, the data collection was collected on July 7, 2017 for the nail shop workers attending the nail art trend seminar held in Gwangju, in Korea. The data were all 236. However, except for the poor data, 208 data were used for the final analysis. The questionnaire consisted of 30 in general questions, questions about self-efficacy in 24 questions. elf-efficacy measuring tool developed by A.Y, Kim, I. Y, Park(2001). The self-efficacy questionnaire consists of 24 items and is self-reported 7-point Likert scale. The reliability of this tool was cronbach alpha = .934.The collected data were analyzed using spss 18.0. Information of Research participant performed frequency analysis. To examine the effects of personal characteristics on self-efficacy, $X^2$ analysis was conducted. And also $X^2$ analysis was conducted to analyze the coughing symptom appearance according to individual and environmental factors. A hierarchical regression analysis was used to determine which of the personal and environmental factors influenced cough symptoms.

An analysis of the properties of mortar according to the change of the replacement rate of waste foundry sands (폐주물사의 치환율 변화에 따른 모르타르의 특성 분석)

  • Ryu, Hyun-Gi;Kwon, Yong-Ju
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.99-104
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    • 2009
  • For recycling of waste foundry sands, researchers recently try to recycle them rather than depend on reclamation, and are studying on how to combine waste foundry sands with cement and use them for various kinds of construction material as the effective recycling method of waste foundry sand. In this research, The ways to find the proper replacement rate of waste foundry sands and to make use of them were suggested through the experiments on the range to apply waste foundry sands with two levels of 1:3 mixture rate of W/C 43% and 50%. The research result showed that in terms of liquidity as the characteristic of unhardened mortar, as the replacement rate of waste foundry sands increased, its flow tended to decrease. The amount of air also displayed a similar tendency to that of liquidity in that the higher the replacement rate of waste foundry sands became, the lower it became. With regard to the solidity trait of hardened mortar, it increased when the waste foundry sands were replaced more, and the replacement of waste foundry sands caused increased initial solidity. As for the amount of water permeated and that of water absorbed as the water tight proofing properties, the amount of permeated water was proved to decrease because of the gap recharge effect by the fine powder of waste foundry sands, and the replacement of waste foundry sands in the structures requiring watertightness is concluded to be very effective.

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Detection of Irradiated Milk Formulas using Electron Spin Resonance (전자스핀공명법(ESR)을 이용한 방사선조사 조제유류의 판별)

  • Woon, Jae-Ho;Park, Byeong-Ryong;Choi, Byung-Kook;Kim, Na-Young;Jeong, Hong-Jeom;Cheong, Ki-Soo;Kim, Hee-Sun;Kim, Chang-Seob
    • Journal of Dairy Science and Biotechnology
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    • v.28 no.2
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    • pp.13-18
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    • 2010
  • Electron Spin Resonance (ESR) spectroscopy has been used to detect the presence of radiation-induced free radicals in biological samples since the mid 1950s and to irradiate foods containing cellulose, crystalline sugar, and bone. Therefore, we analyzed the ESR spectrum of irradiated infant formula and its ingredients in this study. Samples were irradiated with 2 different radiation sources of $^{60}Co$ gamma rays and electron beams (EBs), and the absorbed doses were 0, 1, 3, 5, and 7 kGy. ESR measurements were performed under normal atmospheric conditions using a JEOL JES-FA100 spectrometer equipped with an X-band bridge. Irradiated infant formula showed anunsymmetrical spectrum ($g_1$=2.0050, $g_2$=2.0006); in contrast, non-irradiated samples showed asymmetrical spectrum. The ingredients of irradiated samples showed a multi-component ESR signal in glucose and lactose and a singlet-type spectrum in milk powder (g=2.0050). $R^2$ of the dose-response curve showed a fine linearity of over 0.95 across the entire sample. We also compared the spectra of identical samples irradiated with $^{60}Co$ gamma rays and EBs, because EBs can be used for food irradiation in foreign countries, although this is not permitted in Korea. However, we could not find any significant differences according to the types of radiation source. Thus, ESR spectroscopy can be used to detect irradiated infant formula and several types of primary ingredients in this formula.

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Fabrication of Environmental-friendly Materials Using Atomic Layer Deposition (원자층 증착을 이용한 친환경 소재의 제조)

  • Kim, Young Dok
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.1-7
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    • 2012
  • In this article, I will introduce recent developments of environmental-friendly materials fabricated using atomic layer deposition (ALD). Advantages of ALD include fine control of the thin film thickness and formation of a homogeneous thin fim on complex-structured three-dimensional substrates. Such advantages of ALD can be exploited for fabricating environmental-friendly materials. Porous membranes such as anodic aluminum oxide (AAO) can be used as a substrate for $TiO_2$ coating with a thickness of about 10 nm, and the $TiO_2$-coated AAO can be used as filter of volatile organic compound such as toluene. The unique structural property of AAO in combination with a high adsorption capacity of amorphous $TiO_2$ can be exploited in this case. $TiO_2$ can be also deposited on nanodiamonds and Ni powder, which can be used as photocatalyst for degradation of toluene, and $CO_2$ reforming of methane catalyst, respectively. One can produce structures, in which the substrates are only partially covered by $TiO_2$ domains, and these structures turns out to be catalytically more active than bare substrates, or complete core-shell structures. We show that the ALD can be widely used not only in the semiconductor industry, but also environmental science.

Analysis on the Components and Safety Evaluation of Abeliophyllum distichum Nakai Leaves and Stems (미선나무 잎과 줄기의 성분 분석 및 안전성 평가)

  • Kwon, Soonbok;Kang, Heejoo;Kim, Minjung;Kim, Jinhee;Shin, Haeshik;Kim, Kangsung
    • Journal of Environmental Health Sciences
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    • v.40 no.3
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    • pp.234-244
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    • 2014
  • Objectives: This study was carried out in order to analyze the composition of the leaves and stems of Abeliophyllum distichum Nakai, with the aim of obtaining basic data for utilizing the plant as a food ingredient, as well as for processing. Methods: Leaves and stems from Abeliophyllum distichum Nakai were harvested at Cheongcheon-myeon, Geosan-gun, Chungcheongbuk-do, and were subsequently freeze-dried and ground to a fine powder for chemical component analysis and safety evaluation. Results: The moisture contents of Abeliophyllum distichum Nakai leaves and stems were respectively 65.07% and 40.97%, and the crude ash contents were 1.32% and 0.91%. In addition, the crude protein contents were 11.97% and 3.77%, and the crude fat contents were 2.52% and 0.36%, respectively. The fructose and glucose contents were 32.13 mg/g and 56.17 mg/g for leaves, and 11.38 mg/g and 10.59 mg/g for stems. The major fatty acids of the leaves were palmitic acid (31.79%) and stearic acid (14.79%), and those for stems were linolenic acid (32.78%) and palmitic acid (26.75%). The ascorbic acid contents of leaves and stems were 1.32 mg/g and 0.30 mg/g respectively. The calcium content was found to be the highest among the minerals tested, both in the leaves and stems, with the levels being 166.17 mg/100 g for leaves and 592.34 mg/100 g for stems. The content of organic acid was greater in leaves than in stems, with that of malic acid accounting for more than 75% of total organic acids for both samples. The total phenolic compounds and flavonoid contents of Abeliophyllum distichum Nakai were 50.64 mg/g and 13.53 mg/g in leaves and 96.47 mg/g and 18.53 mg/g in stems, respectively. No changes were shown in the number of micronucleated polychromatic erythrocytes (MNPCE) among 2,000 polychromatic erythrocytes compared to the negative control. Abeliophyllum distichum Nakai was administered orally to rats in order to investigate acute toxicity. The $LD_{50}$ values in rats were above 2,000 mg/kg. Conclusion: These results indicate that the leaves and stems of Abeliophyllum distichum Nakai can be used as natural ingredients in the development of nutritional and functional materials.

SiC powders synthesized from rice husk (왕겨로부터 합성된 탄화규소 분말)

  • Park, Tae-Eon;Hwang, Jun Yeon;Lim, Jin Seong;Yun, Young-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.5
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    • pp.188-192
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    • 2016
  • In this work, the SiC powders were synthesized through the carbonized matter from the mixture of silica powder and rice husks. The SiC powders, obtained from the carbothermal reduction reaction of silica and carbonized rice husks, were investigated by XRD patterns, XPS, FE-SEM and FE-TEM. In the XRD patterns, the specimens showed clearly very high strong peak of (111) plane near $35^{\circ}$ as well as weak (220) and (311) peak respectively at approximately $60^{\circ}$ and $72^{\circ}$. Under Ar atmosphere, the power synthesized from the mixture (in case of mixing ratio, 6 : 4) of carbonized rice husks and silica showed mainly cubic SiC crystalline phase showing relatively lower ratio of hexagonal phase without residual carbon in XRD pattern. In the TEM analysis, the specimen, synthesized from carbonized rice husks and silica with mixing ratio of 6 : 4 under Ar atmosphere, showed relatively fine particles under $5{\mu}m$ and a crystalline SiC phase of (100) diffraction pattern.