• Title/Summary/Keyword: Film formation

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A Study on the Factors of Fuel-Film Formation in an EGI Gasoline Engine (전자 제어식 가솔린 엔진의 벽류 생성 요인에 관한 연구)

  • Kim, Bong-Gyu;Lee, Ki-Hyung;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.11
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    • pp.1530-1537
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    • 1998
  • Mixture formation is one of the significant factors to improve combustion performance of an spark ignition engine. This is affected by spray and atomization characteristics of injector. In the case of EGI system, air-fuel mixing period is so short that a lot of fuel-film and liquid-fuel flow into cylinder. Since this fuel-film is not burnt perfectly in cylinder, it is exhausted in the form of HC emission. In this paper, three measurement techniques were utilized to measure spray characteristics and the amount of fuel-film in the cylinder. At first, PMAS was used to measure the spray characteristics such as size distributions, SMD, and spray angle. Secondly the amount and distribution of fuel-film which flow into through intake valve could be measured quantitatively using the fuel-film measuring device. And lastly, by optical fiber type spark plug used to detect the diffusion flame, the amount of unburned HC was measured. As the result of these experiments, the information of optimal spray characteristics and injection condition to minimize fuel-film could be built up.

Effect of Latex Particle Morphology on the Film Properties of Acrylic Coatings (II);Film Forming Behavior of Model Composite Latex (라텍스 입자구조가 필름형성 및 필름물성에 미치는 영향 (II);모델 복합 라텍스 입자의 필름형성 거동)

  • Ju, In-Ho;Wu, Jong-Pyo
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.2
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    • pp.132-139
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    • 2004
  • Film forming behavior of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. The film forming behavior was evaluated using pseudo on-line measurements of the cumulative weight loss, the UV transmittance, and the tensile fracture energy. Each stages of film formation I, II were not sensitive to the morphology of model latexes, but stage-ill was largely dependent on the morphology of model latexes. The chain mobility of polymer which composed the shell component was found to dominantly determine the behavior of film forming stage-III.

Metallization of Polymers Modified by Ton-Assisted Reaction (IAR)

  • J.S. Cho;Bang, Wan-Keun;Kim, K.H.;Sang Han;Y.B. Sun;S.K. Koh
    • Journal of the Microelectronics and Packaging Society
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    • v.8 no.1
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    • pp.53-59
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    • 2001
  • Surfaces of PTFE and PVDF were modified by ion-assisted reaction (IAR) in which 1 keV $Ar^{+}$ ions were irradiated on the surface of the polymer with varying ion dose in an oxygen gas environment, and Cu, Pt, Al and Ag thin films were deposited on the modified polymers. Wettability of the modified polymers was largely improved by the formation of hydrophilic groups due to chemical reaction between polymer surface and the oxygen gas during IAR. The change in wettability in the modified polymers was also related to the change in surface morphology and roughness. Adhesion between metal films and polymers modified by IAR was significantly improved, so that no detachment was possible in the $Scotch^{TM}$ tape test. The increase of adhesion strength between the metal film and the modified PVDF was mainly attributed to the formation of hydrophilic groups, which interacted with the metal film. In the case of the modified PTFE, the enhanced adhesion to metal film could be explained by the change in surface morphology together with the formation of hydrophilic groups. The electrical properties of the metal films on the modified polymers were also investigated.

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Inhibition of Hydrogen Formation with Calcium Hydroxide on Zinc Electrode of Film-type Manganese Battery

  • Yun, Je-Jung;Kim, Nam-In;Hong, Chang Kook;Park, Kyung Hee
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.3
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    • pp.135-138
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    • 2015
  • A manganese dioxide (MnO2) layer and zinc (Zn) layer are used as the cathode and the anode to develop filmtype manganese battery, in which a stack of a MnO2 layer, gel electrolyte, and Zn layer are sandwiched between two plastic layers. This paper describes the chemical equation of swelling control upon the film-type manganese battery. We examined the reduction of hydrogen formation, by using calcium hydroxide Ca(OH)2 as an additive in the electrolyte of film-type manganese battery. The phenomena or an effect of reduced hydrogen gas was proven by cyclic voltammogram, X-ray photoelectron spectra (XPS), and volume of hydrogen formation. The amount of H2 gas generation in the presence of Ca2+ ion was reduced from 4.81 to 4.15 cc/g-zinc (14%), and the corrosion of zinc electrode in the electrolyte was strongly inhibited as time passed.

Effective Silicon Oxide Formation on Silica-on-Silicon Platforms for Optical Hybrid Integration

  • Kim, Tae-Hong;Sung, Hee-Kyung;Choi, Ji-Won;Yoon, Ki-Hyun
    • ETRI Journal
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    • v.25 no.2
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    • pp.73-80
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    • 2003
  • This paper describes an effective method for forming silicon oxide on silica-on-silicon platforms, which results in excellent characteristics for hybrid integration. Among the many processes involved in fabricating silica-on-silicon platforms with planar lightwave circuits (PLCs), the process for forming silicon oxide on an etched silicon substrate is very important for obtaining transparent silica film because it determines the compatibility at the interface between the silicon and the silica film. To investigate the effects of the formation process of the silicon oxide on the characteristics of the silica PLC platform, we compared two silicon oxide formation processes: thermal oxidation and plasma-enhanced chemical vapor deposition (PECVD). Thermal oxidation in fabricating silica platforms generates defects and a cristobalite crystal phase, which results in deterioration of the optical waveguide characteristics. On the other hand, a silica platform with the silicon oxide layer deposited by PECVD has a transparent planar optical waveguide because the crystal growth of the silica has been suppressed. We confirm that the PECVD method is an effective process for silicon oxide formation for a silica platform with excellent characteristics.

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The Changes of Mechanical Properties of Used Oil in Gasoline Engine (가솔린 엔진오일의 사용에 따른 기계적 성질의 변화에 관한 연구)

  • 강석춘;신성철;김동길;노장섭
    • Tribology and Lubricants
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    • v.9 no.2
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    • pp.36-48
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    • 1993
  • This study is concerned with the changes (deterioration) of the mechanical properties of used oil in the gasoline engine. The analysed properties of used oil were friction, antiwear, wear debris, load-carrying ability and the formation of surface film. From this study, it was found that the oil used in engine was deteriorated to increase the wear and fricion and decrease the load-carrying ability as the running distance of oil was increased. Also the main cause of deterioration was related to the formation of the protective film on the contact zone. When the film was composed with rich additives (sulfur), this could properly protect contact zone from the increase of wear and friction. But as oil was deteriorated, it could not form such a film and therefore the protective ability of sliding surface diminished.

Characteristics of Friction Torques and Lubrication in High Speed Angular Contact Ball Bearings (고속 앵귤러 콘택트 볼베어링의 마찰 토크 및 윤활 특성)

  • 반종억;김경웅
    • Tribology and Lubricants
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    • v.13 no.4
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    • pp.47-52
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    • 1997
  • Friction torques, electrical contact resistances and bearing temperatures were measured on high speed angular contact ball beatings for the spindle of machine tools. The test bearings ran with oil-air lubrication at the thrust loads from 320 N to 1920 N and at the rotational speed of up to 12000 rpm. Electrical contact resistances between balls and races were measured to evaluate the formation of the lubricant film in the contact area. The test results with sufficient lubrication showed that the variations of friction torques were sensitive to the thrust loads and the rotational speeds, and that the friction torques were higher than those with insufficient lubrication. With insufficient lubrication and high thrust loads, the collapse of the lubricant film was detected even at a high rotational speed. It was concluded that these high speed beatings to run in condition of fluid lubrication should require monitoring not only the temperature increase of the bearing but also the lubricant film formation in contact areas resulting from the change in the applied load and the lubricant amount.

Formation of Switching Zones in an AFM Tip/Ferroelectric Thin Film/BE System (AFM팁/강유전박막/전극 시스템에서의 스위칭 영역의 형성)

  • Kim, Sang-Joo;Shin, Joon-Ho;Kim, Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.6
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    • pp.849-856
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    • 2003
  • A three-dimensional constitutive model for polarization switching in ferroelectric materials is used to predict the formation of switching zones in an atomic force microscopy(AFM) tip/ferroelectric thin film/bottom electrode system via finite element simulation. Initially the ferrolectric film is poled upward and the bottom electrode is grounded. A strong dc field is imposed on a fixed point of the top surface of the film through the AFM tip. A small switching zone with downward polarization is nucleated and grows with time. It is found that initially the shape of the switched zone is that of a bulgy dagger, but later turn to the shape of a reversed cup with the lower part wider than the upper part. It can also be concluded that the size of switching zones increases with the period of applied electric potential. The present results are qualitatively consistent with experimental observations.

Electronic Behaviors of Passive Films Formed on Fe-Cr and Fe-Cr-Mo Ferritic Stainless Steels Studied by Mott-Schottky and Cyclic Voltammetry Techniques

  • Kim, Suk-Won;Yoon, Sang-In;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.2 no.1
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    • pp.12-17
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    • 2003
  • The effects of Cr content and film formation potential on electronic behaviors of the passive film on Fe-Cr alloys were investigated in borate buffer solution. Influence of pH on passive films of both Fe-Cr and Fe-Cr-Mo alloys was also investigated. Mott-Schottky and cyclic voltammetry techniques were used to elucidate electronic behaviors of passive films and their electrochemical characteristics. AES analysis of passive films was carried out. Results showed that doping density decreased as Cr content and film formation potentials increased. The addition of Mo to Fe-Cr alloy had little influence on donor densities in pH 9.2 solution but some effects on the decrease in donor densities in pH 1.6 acidic solution.

Instability of Nanoscale Thin Film;a Molecular Dynamics Study (분자동역학 전산모사를 이용한 박막의 불안정성 및 나노 구조물 형성에 관한 연구)

  • Han, Min-Sub;Lee, Joon-Sik;Park, Seung-Ho;Choi, Young-Ki
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.228-232
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    • 2003
  • It has recently been shown that the instability of thin film of a nanoscale can be used in the processes of building nano-size structures, which have potential practical importance in nanotechnology. Molecular dynamics simulation is conducted to probe the thin fluid film of a nano-size and its dynamic behavior during destabilization and structure formation. Non-continuum characteristics are shown in the properties like pressure tensor, viscosity, and thermal conductivity. The thermocapillary force induces a slow growth of long waves in the scale considered. A long-range interaction with the solid wall induces vertical structures, whose formation time and space between neighbors are proportional to the strength of the interaction.

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