• Title/Summary/Keyword: Ferric oxide

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Thermal Decomposition Characteristics on Sodium Azide and Metallic Oxide Mixtures (나트륨 아지드와 금속산화물과의 혼합물에 대한 열분해 특성)

  • 이내우;최재욱;박광수;설수덕;왕석주
    • Journal of the Korean Society of Safety
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    • v.12 no.3
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    • pp.106-113
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    • 1997
  • The thermal characteristics of two binary mixtures by sodium azide/manganese dioxide and ferric oxide, two ternary mixtures by sodium azide/silicon dioxide/manganese dioxide and ferric oxide were studied to obtain the basic data of gas-generating agents for air bags. The thermal reaction for all mixtures started at about $420^{\circ}C$, but the temperature at which the reaction rate reached a maximum was different with the states of samples. According to reaction results, nitrogen, nitrogen oxide and nitrogen dioxide were detected by GC-MS and so many kinds of new chemicals from sodium azide and metal oxide mixtures by XRD. NMS is considered as most stable and reasonable mixture for this types of gas-generating agents.

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Effect of Batch Melting Temperature and Raw Material on Iron Redox State in Sodium Silicate Glasses

  • Mirhadi, Bahman;Mehdikhani, Behzad
    • Journal of the Korean Ceramic Society
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    • v.48 no.2
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    • pp.117-120
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    • 2011
  • In this study, the redox state of iron in sodium silicate glasses was varied by changing the melting conditions, such as the melting temperature and particle size of iron oxide. The oxidation states of the iron ion were determined by wet chemical analysis and UV-Vis spectroscopy methods. Iron commonly exists as an equilibrium mixture of ferrous ions, $Fe^{2+}$, and ferric ions $Fe^{3+}$. In this study, sodium silicate glasses containing nanoparticles of iron oxide (0.5% mol) were prepared at various temperatures. Increase of temperature led to the transformation of ferric ions to ferrous ions, and the intensity of the ferrous peak in 1050 nm increased. Nanoparticle iron oxide caused fewer ferrous ions to be formed and the $\frac{Fe^{2+}}{Fe^{3+}}$ equilibrium ratio compared to that with micro-oxide iron powder was lower.

State of Stain Particle's ADhesion and Its Influence on Visual Consequence of Soil-Removal (오염입자의 부착상태가 시각적인 세정효과에 미치는 영향)

  • 신영선
    • Journal of the Korean Home Economics Association
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    • v.20 no.2
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    • pp.45-51
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    • 1982
  • Degree of separation and adhesion of dye and stain particles has been measured usually by the rate of reflection of light. However, it could be proved that the relation between the quantity of stain and the rate of reflection greatly varied with kinds of stain and states of adhesion. For this study, several pieces of cotton and polyester having different states of stain adhesion were prepared by staining them with two kinds of artificial stain different in color: Ferric Oxide and Ferric Oxynate. Every piece went through soilremoval test which employed two surfactants: Anionic LAS and Cationic M2-100. After the operation, relations between quantity of pre-soilremoval stain and rate of reflection were measured, as well as those between quantity of post-soilremoval stain and rate of reflection. Rate of reflection and quantity of stain were not proportional in measurement to the pieces stained with Ferric Oxide and Ferric Oxynate. The consequence was also the same with cotton and polyester. That held true of the fat-stained textile. With the same quantity of stain, rate of reflection varied according to the magnitude of stain particles, and the state of adhesion influenced the magnitude of stain particles a great deal.

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Evaluation of dynamic behavior of coagulation-flocculation using hydrous ferric oxide for removal of radioactive nuclides in wastewater

  • Kim, Kwang-Wook;Shon, Woo-Jung;Oh, Maeng-Kyo;Yang, Dasom;Foster, Richard I.;Lee, Keun-Young
    • Nuclear Engineering and Technology
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    • v.51 no.3
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    • pp.738-745
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    • 2019
  • Coprecipitation using hydrous ferric oxide (HFO) has been effectively used for the removal of radionuclides from radioactive wastewater. This work studied the dynamic behavior of HFO floc formation during the neutralization of acidic ferric iron in the presence of several radionuclides by using a photometric dispersion analyzer (PDA). Then the coagulation-flocculation system using HFO-anionic poly acrylamide (PAM) composite floc system was evaluated and compared in seawater and distilled water to find the effective condition to remove the target nuclides (Co-60, Mn-54, Sb-125, and Ru-106) present in wastewater generated in the severe accident of nuclear power plant like Fukushima Daiichi case. A ferric iron dosage of 10 ppm for the formation of HFO was suitable in terms of fast formation of HFO flocs without induction time, and maximum total removal yield of radioactivity from the wastewater. The settling time of HFO flocs was reduced by changing them to HFO-PAM composite floc. The optimal dosage of anionic PAM for HFO-anionic PAM floc system was approximately 1-10 ppm. The total removal yield of Mn-54, Co-60, Sb-125, Ru-106 radionuclides by the HFO-anionic PAM coagulation-flocculation system was higher in distilled water than in seawater and was more than 99%.

Microbial Reduction of Iron(III) Oxides: Implication for Permeable Reactive Barriers. (철환원 미생물을 이용한 3가 철의 환원에 관한 연구)

  • 임현정;박재우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.250-253
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    • 2002
  • Remediation of groundwater using zero valent iron filings has received considerable attention in recent years. However, zero valent iron is gradually transformed to iron(III) oxides at permeable reactive barriers, so the reduction of iron(III) oxides can enhance the longevity of the reactive barriers. In this study, microbial reduction of Fe(III) was performed in anaerobic condition. A medium contained nutrients similar to soil solution. The medium was autoclaved and deoxygenated by purging with 99.99% $N_2$ and pH was buffered to 6, while the temperature was regulated as 2$0^{\circ}C$. Activity of iron reducing bacteria were not affected by chlorinated organics but affected by iron(III) oxide. Although perchloroethylene(PCE) was not degraded with only ferric oxide, PCE was reduced to around 50% with ferric oxide and microorganism. It shows that reduced iron can dechlorinate PCE.

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Determination of Surface Diffusivities of Oxides by the Combined Sintering (소결에 의한 산화물촉매의 표면확산계수의 측정)

  • 문세기;유경옥;김형진
    • Journal of the Korean Ceramic Society
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    • v.14 no.2
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    • pp.73-77
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    • 1977
  • The surface diffusion coefficients for nickel, nickel oxide, cuppric oxide, cobalt oxide, alumina and ferric oxide have been determined at various temperatures using the sintering technique. This investigation is based on the model accounting for the sum of the contribution of volume and surface diffusion to the overall shrinkage rate during the initial stage of sintering. Simultaneous measurements of shrinkages and shrinkage rates of the materials compacts were conducted for various annealing times, the results of which were then correlated to the diffusion coefficient.

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Effect of Fluxes on the Wear of MgO Coating Materials for Tundish (턴디쉬용 MgO Coating 재의 손상에 미치는 Flux의 영향)

  • 홍기곤;박재원;김효준
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.677-684
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    • 1997
  • The effects of fluxes on MgO coating materials for tundish were investigated. As the number of charge in continuous casting was increased, the basicity of tundish slag was decreased due to the increase of silica formed by dissolution from rice hull. As a result, the wear of magnesia lining was increased. In aggregates of MgO coating materials, magnesioferrite was formed by the reaction between magnesia and ferric oxide formed by the oxidation of molten steel, while matrix parts of MgO coating materials were worn by CaO-Al2O3-SiO2 compounds. Silica in rice hull extracted to the molten slag reduced basicity of slag and formed forsterite in the result of its reaction with magnesia lining. Also, fayalite was formed from the reaction between silica and ferric oxide and it caused the increment of magnesia lining's wear. The wear of magnesia lining by flux of CaO-SiO2 was larger than that of Cao-Al2O3 and calcia in the flux increased the wear of magnesia lining through the formation of rankinite.

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Role of Added Metal Oxide in the Adherence Mechanism of Low Melting Glass to Several Metal Seals (저융점유리와 각종금속과의 봉착기구에 있어서 금속산화물의 역할)

  • 정창주
    • Journal of the Korean Ceramic Society
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    • v.11 no.1
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    • pp.3-9
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    • 1974
  • The role of added metal oxide in the adherence mechanism of low melting glass to several metal plates such as oxygen free high conducting copper, low carbon steel, chrominum galvanized on copper, and stainless steel was investigated. The metal oxide which added to glass were cupric oxide, ferric oxide, chromic oxide, and stainless steel oxide. The glass to that various metla oxide were added, sealed with several metal plates in the electric furnace at $650^{\circ}C$ for 5 minutes. The results as follows; 1) The interfacial reaction was promoted and strong chemical bonding with glass and metals by which the surface energy was decreased showed excellent sealing by addition of metal oxide. 2) When the interfacial reaction of glass and metals was promoted by addition of metal oxide found out that various adhernece mechanism were related to the sealing. 3) When the amount of metal oxide addition was 3-5% the excellent sealing was achieved.

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Compressibility Characteristics of the Lime Treated Clay (생석회 혼합토의 압축특성에 관한 연구)

  • 민덕기;황광모;오미희
    • Journal of the Korean Geotechnical Society
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    • v.19 no.6
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    • pp.23-29
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    • 2003
  • In this paper, effects of the acidification of ground and the chemical additive materials-ferric oxide, calcium chloride and calcium sulphate on the compressibility characteristics of the marine clay treated with quick lime were investigated. The rapid inflection point method was carried out. Results showed that the compression index of the untreated marine clay increased as the pH of pore water decreased. Also, the preconsolidation pressure, the coefficient of consolidation and the coefficient of permeability of the untreated marine clay decreased with pH of pore water. In the case of the marine clay treated with the quick lime-calcium chloride, the compression index decreased and the coefficient of consolidation and the coefficient of permeability increased. Specially, the preconsolidation pressure of sample treated with the quick lime-ferric oxide was higher than that of another samples.