• Restorative Dentistry and Endodontics
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• 제19권1호
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• pp.45-63
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• 1994

128 freshly extracted human molars were used to study the interaction between dentinal smear layer removal with various agents, and the shear bond strength of a light cured glass ionomer cement to dentin. It was proposed that the removal of smear layers using acidic cleaners followed by incorporation of Fe mordant with dentin could enhanced the infiltration of monomer component in light curing glass ionomer cement and resulted in a high bond strength. For the first treatment process for removal of smear layers on the surfaces of dentin, 50 % citric acid, 10% maleic acid and 10 % phosphoric acid were used, and for the second treatment process, 15% ferric chloride, 6.8% ferric oxalate or 30% potassium oxalate were used. Distilled water was used as a control. After double sequential treatment on dentin, a light curing glass ionomer cement was bonded to dentin. After being immersed in water at 31'C for 24 hours, shear bond strengths were measured Instron testing machine(Model No.4202, USA). Surface changes were also observed using SEM (Hitachi, S-2300, Japan) after treatment process with each agents. The following conclusions were drawn : 1. Dentin surface cleaned with maleic acid and treated with ferric oxalate showed the highest bond strength with light curing glass ionomer cement. 2. Bond strengths of glass ionomer cement to dentin treated with maleic acid or citric acid were the highest, and that treated with phosphoric acid showed the lowest. 3. The effect of ferric oxalate on shear bond strength to dentin was always higher than that of ferric chloride. 4. The smear layers were clearly removed and the orifices of dentinal tubules were opened widely by the citric acid, maleic acid and phosphoric acid. 5. The orifices of dentinal tubules opened after using the first solution were closed with the treatment of ferric chloride. 6. The precipitate like crystals were formed on dentin surfaces and tubules, but a significant decrease in bond strength of glass ionomer cement to dentin surface treated with potassium oxalate.

• 연구논문집
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• 통권23호
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• pp.29-43
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• 1993

Photoetching of AISI 304 stainless steel in ferric chloride solution has been studied. This paper investigated on the single side etching characteristics of 304 stainless steel, especially influence of etching temperature, spray pressure of ferric chloride etchant, and etching time with $50\mum$ and $75\mum$ line width photomask.

• 한국염색가공학회지
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• 제9권6호
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• pp.26-32
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• 1997

In order to remove the pollutants effectively in the dye-processing wastewater by chemical precipitation, coagulation and flocculation test was carried out using several coagulants on various reaction conditions. It was found that the Ferric sulfate was best coagulant for the treatment of mixed dye-processing wastewater. When the Ferric sulfate dosage was 1,100mg/$\ell$, the COD removal rate was very high(50%), and the color was removed very effectively. The COD was decreased relatively well up to 40%, when Alum was dosed as coagulant. But it was difficult to remove the color effectively. Test results about COD removal for the Ferrous sulfate and the Ferric chloride used were mostly same as those of the Alum used. However, the color removal by the Ferrous sulfate was much better than the case of the Alum or the Ferric chloride. It was found that the COD removal was increased and the sludge yield was decreased by pH control before polymer flocculant addition, during the jar test for the Ferrous sulfate and the Ferric sulfate as a coagulant.

• 공업화학
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• 제16권4호
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• pp.496-501
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• 2005

Iron계 금속 촉매의 존재 하에서 ABS의 열분해 거동을 TGA (Thermogravimetric Analysis)를 통해서 조사하였다. Iron계 금속 촉매(ferric nitrate nonahydrate, ammonium ferric sulfate dodecahydrate, iron sulfate hydrate, ammonium ferric oxalate, iron(II) acetate, iron(II) acetylacetonate 및 ferric chloride)는 ABS의 열분해 과정에서 화학반응을 야기하여, 질소분위기에서 촤(char)형성이 관찰되었으며, $600^{\circ}C$에서 3~23 wt%의 비휘발성 촤를 형성하였다. 이와 같은 질소분위기에서의 ABS의 촤 생성은 iron계 금속 촉매의 가교효과(crosslinking effect)로 추정된다. 한편, 공기분위기에서는 생성된 촤가 고온 산화반응에 의해서 열분해되었다.

• 환경위생공학
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• 제16권3호
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• pp.96-103
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• 2001

This study was carried out to investigate the major factors for the removal of NOMs (Natural Organic Matters) by alum ferric chloride and blended coagulants that consisted of alum and ferric chloride. Investigated factors were pH, the dosage of coagulant, alkalinity, hardness and bloc strength. The particle size contained in the test water came from the Han River was also measured. DOC(Dissolved Organic Carbon) removal at pH 6 was two to three times higher than at pH 8.5. The blended coagulant showed 9 to 10 percent higher DOC removal efficiency and 2 to 4 percent higher turbidity under the same condition. Alkalinity consumption of alum, ferric chloride and blended coagulant was 81%, 90% and 86% of theoretical value, respectively. The limit concentration of alkalinity to avoid pin floe was 10 mg $CaCO_3/L$ when alum was used. Hardness had no apparent effect on coagulation. The residual turbidity and $UV_{254}$ showed a tendency of increasing with floc strength($sec^{-1}$) increase. The order of floe strength was the following; alum >blended coagulant > ferric chloride. The particle counter test showed 89 percent of the small particle size(SPS, $1~5{\;}{\mu}textrm{m}$) and 11 percent of the medium to large particle size(M.LPS, $5~125{\;}{\mu}textrm{m}$). At PH7.85, the particle removal efficiencies of SPS($1~5{\;}{\mu}textrm{m}$) and M.LPS($5~125{\;}{\mu}textrm{m}$) in the coagulation process were 81% and 95%, respectively.

• 생약학회지
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• 제44권2호
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• pp.131-137
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• 2013

The present study has been undertaken to investigate the effect of the extract of Cirsium japonicum var. ussuriense leaves (CLE) on blood circulation in a rat model of topical ferric chloride ($FeCl_3$)-induced carotid artery damage. $FeCl_3$ treatment seriously damaged the carotid artery such as the walls of the artery, blood flow and inflammation. However, CLE administration has ameliorated blood circulation and suppressed vessel inflammation. CLE administration also has ameliorated the $FeCl_3$-induced artery tissue damage. Furthermore, CLE significantly suppressed the expression of adhesion molecules. These results suggest that CLE ameliorate blood circulation through suppress inflammatory mediator and adhesion molecule production.

• 약학회지
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• 제3권1호
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• pp.23-25
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• 1957

The herb of Geranium sibirium L, a drug knwon as "Chui Sonni Poul" distributed widely, has been used as a folk-medicine for the treatment of diarrhea. The dried entire herb is boiled with methanol and methanol is distilled of from the filtered methanol extract under reduced pressure. Then the extract is boiled with water and filtered off. From the filtrate, the following substances are isolated and identified by treating with organic solvents as ether, ethyl acetate, and etc.: 1. Gallic acid: a colorless needle crystal which is soluble in alcohol and water. mp.235.deg. C, positive (dark blue) against the ferric chloride reagent. 0.76 percent of gallic acid is yielded from the herb. 2. Quercetin: a light yellow crystal. mp.194.deg. C. negative against the ferric chloride reagent. 3. Ellagic acid: a light yellow crystal which is insoluble in ehter and acetone and slightly soluble in alcohol. Positive (blue) against the ferric chloride reagent. The crystal obtained by recrystalisation from pyridine, does not melt by 360.deg. C. Represent a yield of 0.03 percent from the herb. 4. Crude tannin: a approximately 7.6 percent of crude tannin is yielded by treating with ethyl acetate. gallic acid and querceetin are yielded by hydrosis with dliute sulfuric acid. Based on the above results, the following suggestion could be recommendable; Geraed in the Japanese Pharmacoeia VI.acoeia VI.

• Journal of Applied Biological Chemistry
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• 제61권4호
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• pp.383-389
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• 2018

Degradation of the insecticide O,O-diethyl O-3,5,6-trichloro-2-pyridyl phosphorothioate (chlorpyrifos) in aqueous solution was investigated using iron salts and potassium persulfate during ZVI treatment through a series of batch experiments. The degradation rate of chlorpyrifos increased with increases in the concentrations of iron salts and potassium persulfate in the aqueous system. Ferric chloride was found to be the most effective iron salt for the ZVI-mediated degradation of chlorpyrifos in aqueous solution. Further, the iron salts tested could be arranged in the following order in terms of their effectiveness: $FeCl_3$> $Fe_2(SO_4)_3$> $Fe(NO_3)_3$. The persulfate-ZVI system could significantly degrade chlorpyrifos present in the aqueous medium. This revealed that chlorpyrifos degradation by treatment with $Fe^0$ was promoted on adding ferric chloride and potassium persulfate. The kinetics of the degradation of chlorpyrifos by persulfate-amended $Fe^0$ was higher than that for iron-salt-amended $Fe^0$. This suggests that using a sequential $Fe^0$ reduction-ferric chloride or $Fe^0$ reduction-persulfate process may be an effective strategy to enhance the removal of chlorpyrifos in contaminated water.

• 폴리머
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• 제29권4호
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• pp.338-343
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• 2005

Chloride계 전이금속 촉매의 존재 하에서 ABS/PC/triphenyl phosphate 컴파운드의 열분해 거동을 TGA(thermogravimetric analysis)를 통해서 조사하였다. Chloiide계 전이금속 촉매(cobalt chloiide, ferric chloride, nickel chloride 및 zinc chloride)는 ABS/PC/triphenyl phosphate 컴파운드의 열분해 과정에서 화학반응을 야기하여, 질소분위기에서 숯(char) 형성이 관찰되었으며, $600^{circ}C$에서 $3\~l3\%$의 비휘발성 눈을 형성하였다. 이와 같은 질소분위기에서의 ABS/PC/triphenyl phosphate 컴파운드의 숯 생성은 chloride계 전이금속 촉매의 가교효과(crosslinking effect)로 추정된다. 한편, 공기분위기에서는 생성된 숯은 고온 산화반응에 의해서 역분해되었다.

• 대한소아치과학회지
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• 제48권4호
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• pp.460-466
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• 2021

이 연구의 목적은 유치의 상아질면에서 염화알루미늄 지혈제와 황화철 지혈제의 적용이 레진강화형 글라스아이오노머(RMGIC)의 결합에 미치는 영향을 전단결합강도를 통하여 평가하는 것이다. 20개의 우식이 없는 유구치가 이용되었으며 상아질이 노출되도록 시편을 제작하여 지혈제의 종류에 따라 3개의 군으로 분류하였다. I군은 치면에 25% polyacrylic acid(PAA)를 10초간 사용한 군, II군은 21.3% 염화알루미늄 지혈제를 1분간 사용한 뒤 PAA를 10초간 적용한 군, III군은 20% 황화철 지혈제를 1분간 사용한 뒤 PAA를 10초간 적용한 군으로 설정하였다. 각 군당 10개의 시편에 RMGIC를 중합하여 전단결합강도를 측정하였다. 결합강도는 I군이 10.07 ± 1.83 MPa, 2군에서 7.62 ± 0.78 MPa, 3군에서 5.23 ± 0.78 MPa였다. 모든 군의 결합강도는 유의한 차이를 보였다. 이 연구를 통해 염화알루미늄 지혈제, 황화철 지혈제 모두 상아질에서 RMGIC의 전단결합강도를 감소시키며 황화철 지혈제가 염화알루미늄 지혈제보다 RMGIC의 전단 결합강도를 더 많이 감소시키는 것을 알 수 있었다.