• 제목/요약/키워드: Fe-Si-C

검색결과 909건 처리시간 0.033초

AC2B 알루미늄합금의 고온용해에 의한 금속간화합물 ${\beta}-AlFeSi$상 형상계량 효과 (Effects of Melt Super-heating on the Shape Modification of ${\beta}-AlFeSi$ Intermetallic compound in AC2B Aluminum Alloy)

  • 김헌주
    • 한국주조공학회지
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    • 제21권3호
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    • pp.179-186
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    • 2001
  • Melt super-heating which promotes shape modification of ${\beta}$ intermetallic compounds was conducted to improve mechanical properties of recycled AC2B aluminum alloy. Modification of needle-shape ${\beta}$ intermetallic compounds was effective for the specimens of AC2B aluminum alloys containing 0.85wt.% Fe by melt super-heating, in which the melts had been held at $850^{\circ}C$ or $950^{\circ}C$ for 30 minutes respectively. Owing to the modification of needle-shape of ${\beta}$ intermetallic compounds by melt superheating of the alloy with containing 0.85wt.% Fe to $950^{\circ}C$, increases in elongation and tensile strength were prominent to be more than double and 55% respectively in comparison with the melt heated to $740^{\circ}C$. Moreover, modification of needle-shape ${\beta}$ intermetallic compounds in the alloy containing O.85wt.% Fe by $950^{\circ}C$ melt super-heating led to 48% improvement of the value of impact absorbed energy as compared with the melt heated to $740^{\circ}C$.

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수직자기이방성 NdFeB 박막자석의 자기특성 (Magnetic properties of NdEeB thin films with perpendicular anisotropy)

  • 김만중;유권상;양재호;김윤배;김택기
    • 한국자기학회지
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    • 제10권6호
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    • pp.280-294
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    • 2000
  • RF-DC 마그네트론 스퍼터링을 이용하여 5$\times$$10^{-3}$ Torr의 알곤 가스 분위기에서 [(300nm)Ta/(500nm)NdFeB/(300nm)Ta] 영구자석 박막을 제조한 후 이의 미세구조 및 자기특성을 조사하였다 650-75$0^{\circ}C$로 가열된 Si 기판위에 성막한 [Ta/ NdFeB/Ta] 박막은 수직자기이방성과 함께 우수한 경자기특성을 나타내었으며, 특히 기판온도 $650^{\circ}C$$700^{\circ}C$에서 제조된 박막은 막면에 수직한 방향으로 각각 20 MGOe의 최대자기에너지적과 18.9 kOe의 큰 고유보자력을 나타내었다.

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Fe-30%Mn-6% Si 합금의 형상기억효과에 미치는 Training(SIM↔γ)의 영향 (Effect of Training( SIM↔γ) on Shape Memory Effect of Fe-30%Mn-6%Si Alloy)

  • 한상호;전중환;최종술
    • 열처리공학회지
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    • 제7권2호
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    • pp.118-128
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    • 1994
  • Five alloys were selected randomly in the composition range showing the best shape memory effect in Fe-Mn-Si system reported by Murakami. The shape memory effects of those alloys were mainly investigated through the training treatment which consisted of the repetition of 2% tensile deformation at room temperature and subsequent annealing at $600^{\circ}C$ above $A_r$ temperature. At the same deformation degress in rolling $600^{\circ}C$-annealing for 1 hr. showed the best shape memory effect, and 10%-deformation degrees represented maxima of the shpae memory effects at all annealing temperatures, $500^{\circ}C$, $600^{\circ}C$ and $700^{\circ}C$. The shape memory effects of the alloys were increased by increasing training cycle up to 5 cycles. This was because a large number of dislocations introduced by training process gave rise to increase in the austenite yield stress, and acted as nucleation sites for stress induced ${\varepsilon}$ martensite. The thermal cycling treatment, repetition of cooling in nitrogen at $-196{\circ}C$ and heating to $300^{\circ}C$ for 5 min., did not improve the shape memory effect.

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강판 표면의 Temper Color층 분석 (Analysis of the Temper-Colored Layer at the Surface of Steel Sheet)

  • 홍재화;강정수;정재인;전인준;이영백
    • 한국진공학회지
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    • 제1권2호
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    • pp.259-268
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    • 1992
  • 냉연강판의 성능은 그 표면 상태에 의해서 많은 영향을 받는다. Temper-color(T/C)층은 tempering 과정 중 형성되는 다양한 색깔의 얇은 산화층으로서, 우 수한 표면 품질을 갖기 위해서는 방지 또는 제어되어져야 한다. T/C 현상을 이해하기 위하 여 여러 가지 표면 분석방법이 동원되었다. 유백색 T/C층의 표면은 1$mu extrm{m}$ 크기의 구형의 미 세구조로 구성되어 있었다. thens과정 중 C, Si, Mn과 Al이 표면으로 농화됨을 알았고, Mn 과 C은 정상시료에서 보다 T/C 시료에서 농화가 심하였다. T/C 시료에서의 산화층 두께는 정상시료의 60-$\AA$ 보다 매우 두꺼웠으나, 발생 정도에 따라 변화하였다. T/C층 내의 각 원소 산화 상태는, Si은 SiO2의 상태로, Mn은 MnO나 MnO2의 상태로 Fe는 극표면층의 Fe2O3 상태를 제외하고는 metallic 상태로 분석되었다.

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NOx제거를 위한 Fe/ZSM-5와 Co-Pt/ZSM-5의 상승 효과 (Synergy Effect of Fe/ZSM-5 and Co-Pt/ZSM-5 for NOx removal)

  • 김진걸;유승준;김성수
    • 한국산학기술학회논문지
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    • 제10권9호
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    • pp.2390-2395
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    • 2009
  • 공간속도 $30000\;hr^{-1}$에서 Fe/ZSM-5 촉매의 $SiO_2/Al_2O_3$ 몰비가 감소함에 따라 $NO_x$ 제거 수율은 증가하였다. Fe/ZSM-5는 반응 온도 $350^{\circ}C$ - $400^{\circ}C$ 사이에서 최대 50%의 질소 산화물 제거 수율을 나타내지만 높은 CO 발생량이 관찰된다. Fe/ZSM-5 촉매에서 생성되는 CO를 제거하기 위하여 Co-Pt/ZSM-5 촉매를 직렬로 연속하여 사용하였으며, 공간속도 $30000\;hr^{-1}$, 반응 온도 $250^{\circ}C$ 조건에서 90% 이상의 질소 산화물과 CO 제거 수율을 나타내었다.

SLS(Solid-Liquid-Solid) 성장기구에 의한 탄화규소 나노튜브의 성장 (Growth of SiC Nanotube by SLS (Solid-Liquid-Solid) Growth Mechanism)

  • 노대호;김재수;변동진;양재웅;김나리
    • 한국재료학회지
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    • 제14권2호
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    • pp.83-89
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    • 2004
  • SiC nanotubes were synthesized by SLS growth mechanism using various metal catalysts. Synthesized nanotubes had mean diameters of 20~50 nm and several $\mu\textrm{m}$ length. The kind of catalysts affected microstructures of SiC nanotubes by different diffusion routes. These differences are attributed to catalysts' physical properties and relative activities to the graphite substrate. Fe acted as a good catalyst of SLS growth mechanism. But in case of Ni, SiC nanotubes grew slowly. Optical property was measured by photoluminescence measurement. Relatively broad peak was obtained and mean peak positioned at about 430 nm. This result was the same as other nanocrystalline SiC materials, but was different from the results of bulk SiC probably due to quantum confinement effect and defect in the grown SiC nanotube.

Plasma CVD에 의해 제조된 Iron Silicide 박막의 광학적 특성 (Optical Characteristics of Iron Silicide Films Prepared by Plasma CVD)

  • 김경수;윤용수;정일현
    • 공업화학
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    • 제10권3호
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    • pp.343-348
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    • 1999
  • 저온 공정이 가능한 rf-plasma를 이용한 화학증착법으로 기판의 온도, 출력, $SiH_4$와 천음 함유한 유기화합불 진구체의 희석비 등을 변수로 각 실험 조건에 따라 iron silicide를 제조하였다. 일반적으로 iron silicide 막은 다단계 공정의 Ion Beam Synthesis (IBS)법으로 성장시키고 있으나, 플라즈마를 사용함으로써 단일공정에 의해 $Fe_aSi_bC_cH_d$로 결합된 iron silicide 및 ${\beta}$-상이 형성될 수 있음을 확인하였다. 철 전구체와 실란 (silane)의 희석비에 따라 막 내에 존재하는 탄소와 수소양의 차이로 인해 서로 다른 막의 특성을 나타내었다. 기관의 온도에 따른 광학에너지갭 ($E_b^{opt}$)은 박 표면에 존재하는 수소가 탈착되면서 제공할 수 있는 활성점이 한정되어 있기 때문에 큰 변화가 없었다. 240 watt 이하의 출력에서는 광학에너지갭이 감소하였고, 240 watt 이상의 높은 출력에서는 식각에 의해 미결합수가 증가하여 광학에너지갭은 높게 나타났다.

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Immobilization and Performance of Penicillin G Acylase on Magnetic Ni0.7Co0.3Fe2O4@SiO2-CHO Nanocomposites

  • Lv, Zhixiang;Yu, Qingmei;Wang, Zhou;Liu, Ruijiang
    • Journal of Microbiology and Biotechnology
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    • 제29권6호
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    • pp.913-922
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    • 2019
  • Magnetic $Ni_{0.7}Co_{0.3}Fe_2O_4$ nanoparticles that were prepared via the rapid combustion process were functionalized and modified to obtain magnetic $Ni_{0.7}Co_{0.3}Fe_2O_4@SiO_2-CHO$ nanocomposites, on which penicillin G acylase (PGA) was covalently immobilized. Selections of immobilization concentration and time of fixation were explored. Catalytic performance of immobilized PGA was characterized. The free PGA had greatest activity at pH 8.0 and $45^{\circ}C$ while immobilized PGA's activities peaked at pH 7.5 and $45^{\circ}C$. Immobilized PGA had better thermal stability than free PGA at the range of $30-50^{\circ}C$ for different time intervals. The activity of free PGA would be 0 and that of immobilized PGA still retained some activities at $60^{\circ}C$ after 2 h. $V_{max}$ and $K_m$ of immobilized PGA were 1.55 mol/min and 0.15 mol/l, respectively. Free PGA's $V_{max}$ and $K_m$ separately were 0.74 mol/min and 0.028 mol/l. Immobilized PGA displayed more than 50% activity after 10 successive cycles. We concluded that immobilized PGA with magnetic $Ni_{0.7}Co_{0.3}Fe_2O_4@SiO_2-CHO$ nanocomposites could become a novel example for the immobilization of other amidohydrolases.

Effect of Crystallization Treatment on the Magnetic Properties of Amorphous Strips Based on Co-Fe-Ni-B-Si-Cr Containing Nitrogen

  • Cho H.J.;Kwon H.T.;Ryu H.H.;Sohn K.Y.;You B.S.;Park W.W.
    • 한국분말재료학회지
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    • 제13권4호
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    • pp.285-289
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    • 2006
  • Co-Fe-Ni-B-Si-Cr based amorphous strips containing nitrogen were manufactured via melt spinning, and then devitrified by crystallization treatment at the various annealing temperatures of $300^{\circ}C{\sim}540^{\circ}C$ for up to 30 minutes in an inert gas $(N_2)$ atmosphere. The microstructures were examined by using XRD and TEM and the magnetic properties were measured by using VSM and B-H meter. Among the alloys, the amorphous ribbons of $Co_{72.6}Fe_{9.8}Ni_{5.5}B_{2.4}Si_{7.1}Cr_{2.6}$ containing 121 ppm of nitrogen showed relatively high saturation magnetization. The alloy ribbons crystallized at $540^{\circ}C$ showed that the grain size of $Co_{72.6}Fe_{9.8}Ni_{5.5}B_{2.4}Si_{7.1}Cr_{2.6}$ alloy containing 121 ppm of nitrogen was about f nm, which exhibited paramagnetic behavior. The formation of nano-grain structure was attributed to the finely dispersed Fe4N particles and the solid-solutionized nitrogen atoms in the matrix. Accordingly, it can be concluded that the nano-grain structure of 5nm in size could reduce the core loss within the normally applied magnetic field of 300A/m at 10kHz.

Field Enhanced Rapid Thermal Process for Low Temperature Poly-Si TFTs Fabrications

  • Kim, Hyoung-June;Shin, Dong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.665-667
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    • 2005
  • VIATRON TECHNOLOGIES has developed FE-RTP system that enables LTPS LCD and AMOLED manufacturers to produce poly-Si films at low cost, high throughput, and high yield. The system employs sequential heat treatment methods using temperature control and rapid thermal processor modules. The temperature control modules provide exceptionally uniform heating and cooling of the glass substrates to within ${\pm}2^a\;C$. The rapid thermal process that combines heating with field induction accelerates the treatment rates. The new FE-RTP system can process $730{\times}920mm$ glass substrates as thin as 0.4 mm. The uniform nature of poly-Si films produced by FE-RTP resulted in AMOLED panels with no laser-Muras. Furthermore, FE-RTP system also showed superior performances in other heat treatment processes involved in poly-Si TFT fabrications, such as dopant activation, gate oxide densification, hydrogenation, and pre-compaction.

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