• Transactions on Electrical and Electronic Materials
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• v.2 no.3
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• pp.28-32
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• 2001

It was studied in the present work how the thermal cycling performance of LOC (lead on chip) packages depends on the package construct or leadframe materials. First, package body thickness and Au wire diameter were manipulated for the selection of proper package design. Secondly, two different types of leadframe materials (i.e. copper and 52%Fe-48%Ni alloy) were tested to determine the better material for improved reliability margin of plastically encapsulated microelectronic packages. This work shows that manipulating package body thickness was more effective than an increase of Au wire from 23$\mu\textrm{m}$ to 33$\mu\textrm{m}$ for the prevention of wire debonding failure. Further, this work indicates that the LOC packages including the copper leadframes can be more susceptible to thermal cycling reliability degradation due to chip cracking than those including the alloy leadframes.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.422-423
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• 2006

Ultrasonic-milling of metal oxide nanopowders for the preparation of tungsten heavy alloys was investigated. Milling time was selected as a process variable. XRD results of metal oxide nanopowders ultrasonic-milled for 50 and 100h showed that mean crystallite size reduced with increasing milling time and there was no evidence of contamination or change of composition by impurities. It was found that nanocomposite powders reduced at $800^{\circ}C$ in $H_2$ atmosphere had a composition of 93.1W-4.9Ni-2.0Fe by EDX analysis. Hardness of sintered samples of 50 and 100h was 390 and 463 Hv, respectively, which corresponds to the hardness of commercial products.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.560-563
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• 2004

Invar is a compound metal of Fe-Ni system and contain 36％ Ni. The most distinction characteristic of Invar is the coefficient of thermal expansion is 1.0 10$^{-6}$ /$^{\circ}C$. That is a tenth of general steel material. This low thermal expansion characteristic of Invar is applied to the missile, aircraft, monitor CRT and frontier display's shadow mask such as FED and OLED. The usage of the Invar shadow mask for display is increasing due to the requirement of larger size and flatness monitor. The Invar shadow mask is machined by two ways electro-forming and laser now. However the electro-forming takes a too long time and the laser machining is accompanied with Burr. In this study, PEMM(pulse electrochemical micro machining) is conducted to machine the micro hole to the Invar and 80${\mu}{\textrm}{m}$ hole was machined.

• Journal of the Korea Institute of Military Science and Technology
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• v.18 no.5
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• pp.548-557
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• 2015

This paper is results on Chemisorption of organic compound for the sea water fire fighting line of naval vessels. The quantitative analysis of Chemisorption has been investigated in seawater after immersion in 0.1 % of NaDDTC solutions for 43 hours. The morphology and topography were investigated by FE-SEM and AFM. The chemical elements were analyzed by SEM-EDS, XPS and the depth of chemical elements was measured by depth profiles. The effect of NaDDTC comes from Chemisorption between Copper and Sulfur of NaDDTC. As a result, test results showed that sulfur is helpful to protect a corrosion of seawater line.

• Transactions of the Korean hydrogen and new energy society
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• v.8 no.1
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• pp.31-41
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• 1997

In order to investigate the mechanism of electrochemical hydrogenation reaction on Zr-based Laves phase hydrogen storage alloy electrodes, electrochemical charge/discharge characteristics, potentiostatic/dynamic polarizations and electrocehmical impedance spectroscopy(EIS) of Zr-Ti-Mn-Ni and Zr-Ti-Mn-Ni-M(M=Fe, Co, Al) alloys were examined. Electrochemical discharge capacities of the alloys were quite different with gas charge capacities. Therefore, it was considered that discharge capacities of the alloys depend on electrochemical kinetic factors rather then thermodynamic ones. Discharge efficiencies were increased linearly with exchange current densities. The results of potentiostatic/dynamic polarization measurements showed that electrochemical charge and discharge reaction of Zr-based Laves phase hydrogen storage alloys is controlled by charge transfer process at the electrode surface. The EIS measurements also confirmed this result.

• Journal of the Korean Society for Heat Treatment
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• v.15 no.4
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• pp.166-171
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• 2002

The effects of Ni and N addition to 304 stainless steel on mechanical properties and microstructure were investigated within temperature ranged from $-196^{\circ}C$ to $25^{\circ}C$. The addition of nickel and nitrogen induced the stability against the formation of provide significantly enhanced ductility at $-196^{\circ}C$ and reduce the Md temperature. Fe-18Cr-10Ni-0.2N alloy showed the ${\gamma}$ phase in deformed structure which it was beneficial to enhance the tensile strength and elongation at $25^{\circ}C$ and $-196^{\circ}C$.

• Journal of Korea Foundry Society
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• v.22 no.1
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• pp.42-48
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• 2002

Effects of coating treatment of metallic Cu, Ni-P film on $SiC_p$, for $SiC_p$/iron aluminide composites were studied. Porous hybrid preforms were fabricated by reactive sintering after mixing the coated $SiC_p$, Fe and Al powders. Then the final composites were manufactured by squeeze casting after pouring AC4C Al alloy melts in preforms. The change of reactive temperature, density, microstructure of the preforms and microstructure of the composites were investigated. The exprimental results were summarized as follows. The thickness of Cu and Ni-P metallic layer formed on $SiC_p$ by electroless plating method were about $0.5{\mu}m$ and coated uniformly. There was no remakable change in the ignition temperature with variation of the mixing ratio of Fe and Al powder while in the case of coated $SiC_p$ it was lower about $20^{\circ}C$ than in the non-coated $SiC_p$. The maximum reaction temperature increased with increasing Al contents, but decreased with increasing $SiC_p$ contents. Expansion ratio of preform after reactive sintering increased with amount of Cu coated $SiC_p$. In the case of Fe-70at.%Al, the expansion ratio was about 7% up to 8wt.% of $SiC_p$, addition but further addition of $SiC_p$, increased the ratio significantly. And in the case of Fe-50 and 60at.%Al, it was about 20% up to 16wt.% of $SiC_p$ addition and about 28% in 24wt.% of $SiC_p$, addition. The microstructures of compounds showed that the grains became finer as amount of $SiC_p$, and mixing ratio of iron powder increased and the shape of compounds was changed gradually from irregular to spheroidal.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1195-1198
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• 2013

Nickel hexacyanoferrate supported palladium nanoparticles (Pd-NiHCF NPs) were synthesized and studied for oxygen reduction reactions in direct methanol fuel cell. The NiHCF support was readily synthesized by a comixing of $Ni(OCOCH_3)_2$ and equimolar $K_3[Fe(CN)_6]$ solution into DI water under rigorous stirring. After the preparation of NiHCF support, Pd NPs were loaded on NiHCF via L-ascorbic acid reduction method at $80^{\circ}C$. Pd-NiHCF NPs were electrochemically active for oxygen reduction reaction in 0.1 M $HClO_4$ solution. X-ray absorption near edge structure analysis was conducted to measure the white line intensity of Pd-NiHCF to verify the OH adsorption. As a comparison, carbon supported Pd NPs exhibited same white line intensity. This study provides a general synthetic approach to easily load Pd NPs on porous coordination polymers such as NiHCF and can provide further light to load Pd based alloy NPs on NiHCF framework.

• Proceedings of the Korean Magnestics Society Conference
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• 2010.06a
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• pp.148-150
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• 2010

Two-layered ferromagnetic alloy films ($Ni_{80}Fe_{20}$, $Co_{90}Fe_{10}$) with a Conetic intermediate soft magnetic layer of different thickness were investigated to correlate the coercivity values and magnetization process with the strength of the hard saturation field. The interpretation of strong, medium and weak coupling is proposed.

• Journal of Korea Foundry Society
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• v.41 no.6
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• pp.543-549
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• 2021

Aluminum cast iron has excellent oxidation resistance and good resistance to sulfide and corrosion. Compared to Ti and Ni alloys, it is expected to be a substitute material for structural materials and stainless steels because it is relatively inexpensive to use Fe, which is a non-strategic element. This results in a weight reduction effect of about 30% as compared to the use of stainless steel. With regard to aluminum as an alloying material, it is an element that has been widely used for the alloying of cast iron in recent years. Practical use has been delayed owing to the resulting lack of ductility at room temperature and the sharp decrease in the strength above 600℃ of this alloy, however. The cause of the weak room temperature ductility is known to be environmental embrittlement by hydrogen, and the addition of various alloying elements has been attempted in order to mitigate these shortcomings. Although alloying elements such as vanadium, chromium, and manganese are mainly used to increase the hardness and wear resistance of gray cast iron, the price of finished products containing these elements and the problems associated with alloys with this material impose many limitations.