• 한국자기학회지
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• 제5권5호
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• pp.442-446
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• 1995

Electronic structures of Fe overlayers on Cr(Fe/Cr) films, with an Fe coverage of $1-20{\AA}$, have been investigated by using photoemission spectroscopy. Experimental results are compared with supercell band structure calculations for a system with monolayer (ML) Fe on each side of five layer Cr, Fe(1ML)/Cr(5ML)/Fe(1ML). The extracted Fe 3d partial spectral weight in Fe/Cr exhibits very interesting features for very thin Fe overlayers. First, a sharp emissionnear the Fermi energy is observed, which is expected to originate primarily from hybridization between Fe and Cr 3d electrons at the Fe/Cr interface, and partially from the Fe 3d surface states in the Fe overlayer. Second, other structures are observed at higher binding energies which resemble the Cr 3d valence bands, also suggesting large hybridization between Fe and Cr 3d states at the Fe/Cr interface. These conjectures are confirmed by band structure calculations for Fe(1ML)/Cr(5ML)/Fe(1ML).

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 초전도 자성체 연구회
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• pp.84-87
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• 2003

The interfacial diffusion in Fe/Cr/MgO(001) multilayers has been studied using synchrotron x-ray techniques, such as x-ray reflectivity, extended x-ray absorption fine structures (EXAFS), and anomalous x-ray scattering (AXS). The results of x-ray reflectivity indicated that the interfacial roughness of Fe/Cr multilayers with Cr-$4{\AA}$-thick was larger than that with Cr-$4{\AA}$-thick. The results of EXAFS indicated that the Fe element dominantly diffuse into the stable Cr layers at the Fe/Cr interface. The AXS was certified the existence of the interdiffused Fe element in the Cr layers. Our study revealed that the rough interface of the Fe/Cr multilayers was caused by the interfacia diffusion of Fe element into the Cr layers.

• 한국자기학회지
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• 제4권1호
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• pp.20-24
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• 1994

CoCr/NiFe 이중매체의 기록, 재생특성은 CoCr 기록층뿐만 아니라 NiFe연자성층의 자기적 특성에도 강하게 영향을 받는다. NiFe/Ge의 다층화로 CoCr/NiFe 매체의 기록감도와 재생전압을 증 가시킬 수 있었으며 이것은 연자성층의 높은 투자율과 CoCr기록층의 높은 수직이방성에 기인하였다. 그러나 연자성층의 투자율의 향상이 기록감도의 현저한 향상에 비해 재생전압의 현저한 증가를 가 져오지 못하는데 이것은 유한요소수치해석에서도 확인할 수 있었다. 반면에 NiFe/Ge 다층연자성박 막을 사용한 CoCr/NiFe 매체의 피크이동(peak shift)특성은 NiFe 단층연자성박막을 사용한 CoCr/NiFe 매체에 비해 악화되었다. 그러나 CoCr층과 NiFe층 사이에 10 nm의 CoZrNb 박막을 삽입시키면 높은 재생전압과 낮은 파크이동을 동시에 얻을 수 있었다. 이 연구에서 는 이러한 기록, 재생특성을 미 세구조와 연관시켜 검토하였다.

• 한국재료학회지
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• 제11권1호
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• pp.34-38
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• 2001

Fe-28%Al($Fe_3Al$)과 Fe-28%Al-4%Cr($Fe_3Al-4Cr$) 금속간화합물을 대기중 1073, 1273, 1473k의 온도에서 최고 17일까지 장시간 산화시켰다. $Fe_3Al-4Cr$의 산화저항은 근본적으로 $Fe_3Al$과 거의 비슷하거나, 약간 우수하였다. $Fe_3Al$ 위에 형성된 산화물은 거의 순수한 ${\alpha}-AL_2O_3$로만 구성되어 있었으며, $Fe_3Al-4Cr$ 위에 형성된 산화물은 약간의 Fe와 Cr 이온이 고용된 ${\alpha}-AL_2O_3$로 구성되어 있었다. 외부산화막을 형성하기 위해 모재원소의 외부확산에 의해 산화물-모재 계면에는 Kirkendall 기공이 존재하였다. $Fe_3Al(-4Cr)$ 표면에 형성된 산화막은 1273k가지는 비교적 얇고 치밀하였으나, 1473k에서 산화막의 박리와 함께 상대적으로 큰 무게증가가 발생하였다.

• Corrosion Science and Technology
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• 제14권3호
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• pp.127-131
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• 2015

Model alloys Fe-9Cr, Fe-20Cr and Fe-20Cr-20Ni (wt. %) with 0.1 and 0.2 % Si were exposed to $Ar-20CO_2-20H_2O$ gas at $818^{\circ}C$. The undoped alloys formed a thick iron-rich oxide scale. The additions of Si reduced scaling rates of Fe-9Cr to some extent but significantly suppressed the formation of iron oxide scales on Fe-20Cr and Fe-20Cr-20Ni. Carburisation also occurred in all undoped alloys, but not in Si-containing Fe-20Cr and Fe-20Cr-20Ni. Protection against carburisation was a result of the formation of an inner scale layer of silica.

• 한국전기전자재료학회논문지
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• 제17권2호
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• pp.223-227
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• 2004

We have studied the interfacial diffusion of Fe/Cr multilayers using synchrotron x-ray techniques, such as x-ray reflectivity, extended x-ray absorption fine structures (EXAFS), and high-resolution x-ray scattering. The results of x-ray reflectivity indicated that the interfacial roughness of Fe/Cr multilayers increased with the Cr-layer thickness. The Fourier transform (FT) of EXAFS data clearly showed that the Fe atoms dominantly diffused into the stable Cr layers at the Fe/Cr interface. The results of high-resolution x-ray scattering supported the interfacial diffusion of Fe atoms. Out study revealed that the dominantly interfacial diffusion of Fe atoms into the Cr layers effects the interfacial roughness of the Fe/Cr multilayers.

• Journal of Welding and Joining
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• 제23권2호
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• pp.75-80
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• 2005

The effect of chemical constituents of $(Cr,\;Fe)_7C_3$ carbide phase on its hardness in the chromium-carbide type Cr white iron hardfacing weld deposits has been investigated. In order to examine $(Cr,\;Fe)_7C_3$ carbide phase, a series of filler metals with varying chromium contents was used. The alloys were deposited once or twice on a mild steel plate using the self?shielding flux cored arc welding process. The hardness of $(Cr,\;Fe)_7C_3$ carbide phase was measured by the micro-Vickers hardness test. It was shown that hardness of $(Cr,\;Fe)_7C_3$ carbide phase increased with increasing Cr content in $(Cr,\;Fe)_7C_3$ carbide phase. This behavior of the hardness of $(Cr,\;Fe)_7C_3$ carbide phase was explained by the types of chemical bonds that hold atoms together in $(Cr,\;Fe)_7C_3$ carbide phase.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1999년도 추계학술발표회
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• pp.81-84
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• 1999

The aqueous geochemical characteristics of Cr(III) and Cr(Ⅵ) in environmental systems are very different from one another: Cr(Ⅵ) is highly soluble, mobile and toxic relative to Cr(III) Reduction of Cr(Ⅵ) to Cr(III) are beneficial in aquatic systems because of the transformation of a highly mobile and toxic species to one having a low solubility in water, thus simultaneously decreasing chromium mobility and toxicity. Fe(II) species are excellent reductants for transforming Cr(Ⅵ) to Cr(III), and in addition, keeping Cr(III) concentrations below the drinking water standard of 52 ppb at pH values between 5 and 11. Investigations of the effects of NOM on Cr(Ⅵ) reduction are for examining the feasibility of using ferrous iron to reduce hexavalent chromium in subsurface environments. Experiments in the presence of soils, however, showed that the solid phase consumes some of the reducing capacity of Fe(II) and makes the overall reduction kinetics slower. The soil components bring about consumption of the ferrous iron reductant. Particular attention is devoted to the complexation of Fe(II) by NOM and the subsequent effect on Cr(Ⅵ) reduction. Cr(Ⅵ) reduction rate by Fe(II) was affected by the presence of NOM (humic acid), The effects of humic acid was different from the solution pH values and the concentration of humic acid. It was probably due to the reactions between humic acid and Cr(Ⅵ), humic acid and Fe(II), and between Cr(Ⅵ) and Fe(II), at each pH.

• 대한금속재료학회지
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• 제48권11호
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• pp.981-988
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• 2010

The effects of Cr and Al contents in Fe-Al and Fe-Cr alloys on oxidation resistance, hardness, and the thermal expansion coefficient were investigated. Fe-Al and Fe-Cr alloys above 10wt.%Al and 20wt.%Cr contents have a high oxidation resistance. The hardness of the Fe-Al and Fe-Cr alloys increased with an increase in Al and Cr contents due to solid solution or formation of an intermetallic compound. The coefficients of thermal expansion of the Fe-Al alloys were higher than those of the Fe-Cr alloys because the coefficient of thermal expansion of Al was higher than that of Fe and Cr.

• 한국표면공학회지
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• 제51권6호
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• pp.354-359
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• 2018

NaCl-induced hot corrosion behavior of ASTM T22 (Fe-2.25Cr-1Mo), T91 (Fe-9Cr-1Mo), T92 (Fe-9Cr-1.8W-0.5Mo), 347HFG (Fe-18-Cr-11Ni), and 310H (Fe-25Cr-19Ni) steels was studied after spraying NaCl on the surface. During corrosion at $600-800^{\circ}C$ for 50-100 h, thick, non-adherent, fragile, somewhat porous oxide scales formed. All the alloys corroded fast with large weight gains owing to fast scaling and destruction of protective oxide scales. Corrosion rates increased progressively as the corrosion temperature and time increased. Corrosion resistance increased in the order of T22, T91, T92, 347HFG, and 310H, suggesting that the alloying elements of Cr, Ni, and W beneficially improved the corrosion resistance of steels. Basically, Fe oxidized to $Fe_2O_3$, and Cr oxidized to $Cr_2O_3$, some of which further reacted with FeO to form $FeCr_2O_4$ or with NiO to form $NiCr_2O_4$.