• Title/Summary/Keyword: Fe-Co alloys

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Effect of Small Additives on the Microstructure of Strip-Cast Nd-Fe-B Alloys (소량의 첨가원소가 Strip-Cast Nd-Fe-B 향금의 미세 조직 형성에 미치는 영향)

  • Lee, D.H.;Jang, T.S.;Kim, D.H.;Kim, Andrew-S.
    • Journal of the Korean Magnetics Society
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    • v.14 no.5
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    • pp.196-200
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    • 2004
  • In order to improve dendritic formation of Nd$_2$Fe$\_$14/B phase in the strip-cast Nd-Fe-B alloys that are frequently used for production of high energy sintered magnets, effect of small substitutional additives such as Cu (0.3~1.0 at. %) and Co (0.5~1.5 at.%) on the phase formation and microstructures of the strip-cast alloys based on Nd$\_$14/Fe$\_$80/B$\_$6/ were investigated. As the amount of Cu addition increased, formation of Nd$_2$Fe$\_$14/B dendrites along the direction normal to the strip surface was suppressed with the reduction of the strip thickness mainly due to the increase of fluidity of the melt. However, both the dendrites and their <001> preferred orientation along the direction normal to the strip surface were improved with the increase of the strip thickness as the amount of Co addition increased. The dendrites became finer after small amount of Cu or Co was added. While small copper additions tended to stabilize the formation of primary Fe, small cobalt additions suppressed it. When small amount of Zr was added, however, the dendrite structures were totally collapsed with excessive grain growth of Nd$_2$Fe$\_$14/B.

Electrochemical Behavior and Biocompatibility of Co-Cr Dental Alloys

  • Kang, Jung-In;Yoon, Jun-Bin;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.107-107
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    • 2015
  • In order to investigate electrochemical behavior and biocompatibility of Co-Cr dental alloy by electrochemical corrosion test and MTT assay, the xCo-25Cr-yW-zNi alloys were used in this study. Samples of Co-Cr-W-Ni alloys were manufactured using arc melting furnace. The microstructure of the alloys was examined by optical microscopy (OM), Field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), MTT assay, and corrosion test. Corrosion resistance increased slightly as cobalt (Co) content increased. And bioactivity was concerned with nickel (Ni) and tungsten (W). Biocompatibility of Co-Cr alloy depended on Ni and W contents.

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Magnetic and Magnetostrictive Properties of Nanogranular Co-Fe Based Alloys: A Particular Emphasis on High Frequency Applications

  • Sohn, J.C.;Byun, D.J.;Lim, S.H.
    • Journal of the Korean Magnetics Society
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    • v.13 no.4
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    • pp.133-154
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    • 2003
  • A comprehensive review is given in this article on magnetic and magnetostrictive properties of nanogranular Co-Fe based alloys, with a particular emphasis on high frequency applications. Structural and physical properties are firstly described, followed by magnetic and magnetostrictive properties. Materials of both thin film and bulk forms are considered. A detailed description on high frequency characteristics of Co-Fe based soft magnetic thin films is then presented.

Enhanced Exchange Coupling of $Nd_2Fe_{14}B/Fe_3B$ Magnet Via Magnetic Field Treatment

  • Choong Jin Yang;Con Byung Park
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.31-36
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    • 1996
  • An externally applied magnetic field during heat treating the $Nd_2Fe_{14}B/Fe_3B$ based spring magnet was found to enhance the exchange coupling between the hard and soft magnetic grains. More than 30% increase in $M_r/M_s$ values for melt-spun $Nd_2Fe_{73.5}Co_3$$(Hf_{1-x}Ga_x)B_{18.5}$ (x=0, 0.5, 1) alloys was resulted from a uniform distribution of $Fe_3B, \alpha-Fe$ and $Nd_2Fe_{14}B$ phases, and also from a reduced grain size of those phases by 20%. The externally applied magnetic field induced a uniform distribution of fine grains. A study of Mossbauer effect also report that the enhancement of total magnetization of nanocomposite $Nd_2Fe_{14}B/Fe_3B$ alloys is attributed to an increased formation of $Fe_3$B after magnetic annealing.

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The Effect of Additional Elements on the Tailored Magnetic Properties of Electrochemically Prepared CoPtP-X Alloys (전기화학적으로 제조한 CoPtP-X합금의 첨가제 효과에 따른 맞춤형 자기적 성질)

  • Park, H.D.;Lee, K.H.;Kim, G.H.;Jeung, W.Y.;Choi, D.H.;Lee, W.Y.
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.94-98
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    • 2005
  • Coptp films with the additive elements (X=Fe, Mn) of varying concentrations were prepared by in-situ electrodeposition, to tailor their magnetic properties. Alloys of CoPtP-X (X=Fe, Mn) were synthesized by changing the solution concentrations of Fe and Mn for electrodeposition. In the electrodeposited CoFePtP alloys, preferred orientation of the electrodeposited films changed from hexagonal (001) to (100) direction with increasing iron contents as revealed by X-ray diffraction, and these films exhibited various magnetic properties ranging from a typical hard magnetic to a soft magnetic property in accordance with microstructural variations. In the case of Mn addition, excellent hard magnetic property was observed at a specific Mn concentration of 0.0126 M in the electrolyte, with the coercivity of 4630 Oe and squareness of 0.856 and this was attributed to the fact that magnetization easy-axis (hexagonal c-axis) coincides with the preferred growth orientation of the film confirmed by transmission electron microscopy.

Microstructures and Mechnical Properties of Ni-Al-Fe Ternary Alloys (Ni-Al-Fe 3 원계합금의 미세조직 및 기계적 특성)

  • Choi, Dap-Chun;Bae, Dae-Sung
    • Journal of Korea Foundry Society
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    • v.24 no.6
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    • pp.356-365
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    • 2004
  • Mechanical properties and microstructures of the Ni-AI-Fe and Ni-AI-Fe-(B, Zr) alloys which containing $10{\sim}30at$.%Fe, 0.1at.%B and/or 0.1at.%Zr have been investigated. The experimental results showed that the microstructures of Ni25Al were changed from a single phase ${\gamma}$ to dual phase ${\gamma}$ and ${\beta}$ by addition of 27at.%Fe. Ni45Al, however, kept the single ${\beta}$ phase even though Fe was added upto 30at.%. The hardness of Ni25Al were increased from $H_RB$ 70 to $H_RC$ 39 by addition of 27at.%Fe. In the case of Ni45Al which have $H_RC$ 37, the hardness was decreased by lOat.%Fe addition, but increased with 30at.%Fe. The yield strength and ultimate compressive strength in the compressive test have showed a similar trend with the hardness change. The strain to fracture was 14% at maximum and achieved in Ni25Al-27at.%Fe and Ni25Al-27at.%Fe-0.1 at.%B alloys. The Ni45Al showed a relatively low strain to fracture as 4%. The impact absorption energy of Ni25Al increased from 0.74 kg-m to 1.81 kg-m by addition of 27at.%Fe. In case of Ni45Al, the addition of lOat.%Fe and lOat.%Fe with small amounts of Band Zr did not change significantly the impact absorption energy of 0.60 kg-m, whereas the addition of 30at.%Fe with small amounts of B and Zr increased it slightly. In fracture tests, both of two basic materials showed the same intergranular fracture but by adding Fe it changed to the cleavage fracture mode or co-existing of cleavage and intergranular fractures.

Preparations and Magnetic Properties of Aluminum Anodic Oxidized Films Electrodeposited Cobalt-Iron Alloys (코발트-철을 전해석출한 양극산화피막의 제작과 자기특성)

  • 강희우
    • Journal of the Korean Magnetics Society
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    • v.4 no.1
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    • pp.25-31
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    • 1994
  • The magnetic properties of aluminum anodized film in which Co-Fe alloy electrodeposited are investigated with regard to the alloy composition of magnetic films. The electrodeposited Co-Fe particles are confirmed to be single phase Co-Fe alloys by X-ray diffractions. At 34 at% Co, the sample with small pore diameter(particle diameter $150\;{\AA}$) has a large magnetic energy product($B_{max}$) of about 1.44 MGOe due to the large saturation magnetization, the high coercive force and good squareness of the M-H curve. However, for the samples with particle diameter larger than $450\;{\AA}$, the bottom of each particle forms abnormal particle claaed branch-shaped unlike the sample of the particle diameter $150\;{\AA}$. In this case, the magnetic anisotropy energy was about zero at the compositions of 45 and 75 at% Co. Moreover, at the compositions from 50 to 70 at% Co, the anisotropy became negative value. This means that an easy axis of magnetization of the film is in plane in plane in spite of the perpendicular shape anisotropy of the particle. It was found that the bottom extremity of the particle contains FeC from the X-ray diffraction. Thus the effect of the bottom extremity, that is, an unusal magnetic property was removed by electrodepositing Cu at the bottom extremity of the particle. Itis clear that the magnetic properties of the ilms are influenced by he branch-shaped bottom extremity filled with FeC.

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