• Title/Summary/Keyword: Fe:ZnSe

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주암댐 호저 퇴적물에서의 수직적 중금속 분산과 $^{210}Pb$를 이용한 퇴적속도산정 (Vertical Distribution of Heavy Metal Concentrations in Sediment Cores and Sedimentation Rate Using $^{210}Pb$ Dating Technique in the Juam Reservoir)

  • 이평구;염승준;연규훈;지세정;김지욱;오창환;김선옥
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제10권1호
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    • pp.43-57
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    • 2005
  • 주암댐에 유입된 호저퇴적물의 입도(2mm-200{\mu}m,\;200-100{\mu}m,\;100-50{\mu}m,\;50-20{\mu}m,\;<20{\mu}m)별 중금속(As, Cd, Cr, Cu, Ni, Pb, Zn)의 이동과 퇴적 후 중금속의 수직적 분산 특성을 규명하기 위하여 12개 지점의 호저퇴적물과 3개 지점의 코아시료를 채취하였으며, 코아시료는 2-5 cm 간격으로 절단하여 깊이별 간극수와 퇴적물의 중금속 함량을 측정하였다. 호저퇴적물의 퇴적속도를 측정하기 위하여 코아시료에 대한 $^{210}Pb$ 동위원소 연구를 수행하였다. 주암댐 호저 퇴적물의 중금속 및 미량원소의 함량은 퇴적위치와 상관없이 거의 일정한 함량을 보이며.,평균 함량은 $As\;14.9\;{\mu}g/g,\;Cd\;0.81\;{\mu}g/g,\;Cu\;30.7\;\;{\mu}g/g,\;Ni\;34.7\;{\mu}g/g,\;Pb\;63.3\;{\mu}g/g,\;Zn\;87.9\;{\mu}g/g$이다. Cu, Pb, Zn, Ni 및 Cd의 함량은 $20\;{\mu}m$ 이하 입도의 퇴적물에서 가장 높은 반면, As는 $2mm-200{\mu}m$ 혹은 $200-100\;{\mu}m$ 입도의 퇴적물에서 가장 높다. 간극수에 용해된 원소 중에서 가장 함량이 높은 것은 Fe와 Mn 이었으며, 코아시료의 상부로부터 심부로 갈수록 함량이 증가하는 수직적 분산특성을 나타낸다. 반면에 용존 Zn과 Cu함량은 코아시료의 최상부에서 가장 높게 나타나며, 이는 산화:환원 전위차에 따른 유기물질 및 산화광물의 용해작용과 관련이 있다. 코아시료의 퇴적물 내 Cu, Ni, Pb 및 Zn 함량은 0-4 cm구간에서 가장 높은 표면집적 현상이 관찰되며, Pb와 Cu 함량이 현저하게 높은 데, 이는 인위적인 오염에 기인하는 것으로 해석된다. $'unsupponed\;^{210}Pb'$을 이용하여 계산된 호저퇴적물의 퇴적 속도는 $\omega=0.91\;cm\;year^{-1}$ 이며, 이를 적용하면 주암댐이 완공된 이후 약 10 cm의 퇴적물이 평균적으로 퇴적된 것으로 추정된다. 이러한 자료는 주암댐 호수 바닥에 퇴적된 퇴적물의 관리방안을 마련하는 데 중요한 정보로 사용될 수 있을 것이다.

용접공정에서 발생된 공기중 흄의 조성과 농도에 영향을 미치는 요인에 관한 연구 (A Study on Factors Affecting Airborne Fume Composition and Concentration in Welding Process)

  • 신용철;이광용;박승현;이나루;정지연;박정근;오세민;문영한
    • 한국산업보건학회지
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    • 제7권2호
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    • pp.181-195
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    • 1997
  • The purpose of this study was to investigate factors affecting the composition and concentrations of fumes generated from various types of welding processes. The results are as follows. 1. Iron(Fe), zinc(Zn) and manganese(Mn) were predominant in Welding fumes. The Fe content in total fumes was 25.5% in coated electrode and 28.2% in $CO_2$ are welding, and the Zn content was 4.5% and 9.1%, respectively, and the Mn was 3.6% and 7.8%, respectively. 2. It was found that the important factors determining composition and concentration of fumes were type of industries, type of welding processes, type and composition of electrodes, composition of base metals, confinement of workplaces or condition of ventilation, work intensity, coated metals such as lead and Zn in paint. 3. The Mn content in airborne fumes was highly correlated with that of electrode(r=0.77, p<0.01) and was about 4 times higher than that in electrodes or base metals. The results lindicate that Mn is well evaporated into air during welding. The higher vapor pressure of Mn may explain this phenomenon. 4. the airborne total fume concentrations were significantly different among types of industries(p<0.001). The airborne total fume concentration was higher in order of sleel-structure manufacturing($GM=15.1mg/m^3$), shipbuilding($GM=13.2mg/m^3$), automobile-component manufacturing ($GM=7.8mg/m^3$) and automobile assembling industry($GM=3.0mg/m^3$) 5. The airbone total fume concentration was 6 times higher in $CO_2$ welding than in coated electrode welding, and approximately 3 times higher in confined area than in open area, in steel-structure manufacturing industry. 6. The concentration of welding fume outside welding helmet was about 2 times higher than that inside it. It is recommened that air sampling be done inside helmet to evaulate worker's exposure accurately, for it has an outstanding effect on reducing worker exposure to fumes and other contaminants.

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Al-Si-Cu계 합금의 주조법과 용체화처리 조건이 기계적 특성변화에 미치는 영향 (Effects of the Solid Solution Treatment Conditions and Casting Methods on Mechanical Properties of Al-Si-Cu Based Alloys)

  • 문민국;김영찬;김유미;최세원;강창석;홍성길
    • 한국주조공학회지
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    • 제38권6호
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    • pp.111-120
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    • 2018
  • In this study, the effects of two different casting methods (gravity casting and, diecasting) and various solid-solution conditions on the mechanical properties of ASC (Al-10.5wt%Si-1.75wt%Cu) and ALDC12 (Al-10.3wt%Si-1.72wt%Cu-0.76wt%Fe-0.28wt% Mn-0.32wt%Mg-0.9wt%Zn) alloys were investigated. A thermodynamic solidification analysis program (PANDAT) was used to predict the liquidus, solidus, and phases of the used alloys. In the results of an XRD analysis, ${\beta}$-AlFeSi peaks were observed only in the ALDC12 alloy regardless of the casting method or SST (solid-solution treatment) conditions. However, according to the results of a FE-SEM observation, both ${\theta}(Al_2Cu)$ and ${\beta}$-AlFeSi were found to exist besides ${\alpha}$-Al and eutectic Si in the gravity-casted ASC alloy at $500^{\circ}C$ after a SST of 120min. The ${\alpha}$-AlFeSi and ${\beta}$-AlFeSi phases including the eutectic phases were also found to exist in the ALDC12 alloy. The results of a microstructural observation and analyses by XRD, FE-SEM and EDS were in good agreement with the PANDAT results. The gravity-casted ALDC12 and ASC specimens showed the highest Y.S. and UTS values after aging for three hours at $180^{\circ}C$ after a SST at $500^{\circ}C$ for 30min. At longer solid-solution treatment times at $500^{\circ}C$ in the gravity-casted ALDC12 and ASC specimens, the elongations of the ASC alloys increased, whereas they decreased slightly in the ALDC12 alloys.

비타민 A 섭취가 에탄올을 급여한 흰쥐의 체내 항산화 영양소 상태에 미치는 영향 (Effect of Dietary Vitamin A on the Status of Antioxidants in Ethanol-Treated Rats)

  • 서정숙;양경미;최미정
    • 한국식품영양과학회지
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    • 제24권6호
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    • pp.848-858
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    • 1995
  • 본 연구는 만성적인 에탄올 급여에 의한 조직내 항산화 영양소 함량의 변화에 대하여 비타민 A의 형태별 급여효과를 조사하고자 실시되었다. 실험동물은 Sprague-Dawley종 숫컷 흰쥐를 사용하였으며 에탄올 공급과 동시에 비타민 A 결핍군(FE), ${\beta}-carotene$ 섭취군(${\beta}E$), retinyl acetate 섭취군(RE) 그리고 13-cis-retinoic acid 성취군(RAE)과 에탄올 대신 동일 열량을 sucrose으로 공급 시킨 각각의 pair-fed군 등 모두 8군으로 나누어 7주 동안실섬 식이를 공급하였다. 항산화 영양소로 비타민 E, C, glutathione 그리고 무기질 함량의 분석을 통해서 에탄올에 의해 변화되는 생체내 항산화 영양소 상태와 이에 비타민 A의 형태별 급여 효과를 조사하여 다음과 같은 결과를 얻었다. 혈장내 ${\alpha}-tocopherol$ 함량은 에탄올­ 급여로 감소되었으나 간 조직내에서는 ${\beta}-carotene$ 섭취군만이 낮은 함량을 보였다. 그러나 간 조직내 tocopheryl acetate 함량은 pair-fed군에 비해서 에탄올 급여로 현저히 저하되었다. 혈장과 간 조직내에서 에탄올 급여에 의한 비타민 E 함량 감소는 retinyl acetate 공급으로 그 감소 정도가 가장 저하되었다. 혈장내 총 비타민 C 함량은 에탄올 급여와 동시에 ${\beta}-carotene$이나 retinyl acetate 섭 취군이 pair-fed군에 비해서 낮았으며 환원형과 산화형 비타민 C 함량비는 에탄올 급여로 낮았으나 ${\beta}-carotene$ 섭취시킨 군만이 높게 나타났다. 간 조직내 총 비타민 C 함량은 13-cis-retinoic acid 섭취군을 제외한 전 군에서 에탄올 급여로 증가하였으여 환원형과 산화형 비타민 C 비는 에탄올 급여군 중 ${\beta}-carotene$을 섭취시켰을 때 가장 높았다. 간 조직내 총 glutathion 함량은 에탄올 공급군과 pair-fed군 사이에 유의적인 차이를 보이지 않았으나 환원형과 산화형의 함량비에서는 에탄올과동시에 retinyl acetate나 13-cis-retinoic acid 섭취군에서 pair-fed군에 비해 높았다. 혈장내 Zn, Cu, Se, Fe 함량은 에탄올 급여군과 pair-fed군 사이에 일정한 경향을 보이지 않았으나 간 조직내 Zn, Cu 함량은 에탄올 급여로 감소된 반면 Fe 함량은 증가되었다. 이러한 결과들로 보아 에탄올은 체내 항산화 영양소 상태의 변화를 초래하며 비타민 A의 공급여부 뿐만 아니라 형태별 섭취에 의해서 항산화 영양소 상태가 변화될 수 있는 것으로 나타났다. 그러나 생체내 항산화 영양소들은 서로 상쇄, 상승 혹은 길항작용을 통해서 상호영향을 미치므로 각각의 항산화 영양소 상태 변화에 대한 정확한 기전 규명을 위해서는 다각적인 연구가 요구된다고 볼 수 있다. 그러나 지질과산화물의 함량과 체내 항산화 영양소 상태는 상호관련성이 있었으며 본 실험에서 에탄올 공급에 의한 항산화 영양소 함량의 감소는 대체로 비타민 A를 retinyl acetate 형태로 섭취시켰을 때 다소 경감되는 것으로 나타났다.

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Study on minerals status of dairy cows and their supplementation through area specific mineral mixture in the state of Jharkhand

  • Bhanderi, B.M.;Goswami, Ajay;Garg, M.R.;Samanta, Saikat
    • Journal of Animal Science and Technology
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    • 제58권12호
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    • pp.42.1-42.8
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    • 2016
  • Background: Deficiency of macro and micro-minerals in the ration of dairy cows adversely affects growth, milk production and reproduction efficiency. It is essential to examine mineral concentrations in feeds offered to dairy cows in practical farms. Methods: Two villages from each taluka were selected at random for taking representative samples of feeds, forages and hair. Within the village, help was sought from village milk producers and district animal husbandry officer for identification of 4 to 5 farmers and collection of representative samples. All the samples were processed and analyzed for chemical composition as well as major macro and micro-minerals, using Inductively Coupled Plasma-Optical Emission Spectrometer. Results: Ca content in wheat straw (0.29%), crushed maize (0.02%) and wheat bran (0.12%) was found to be below the critical level (0.30%). The P content in concentrate ingredients was high (0.26-0.96%), but low in dry roughages (0.06-0.12%). Cereal straws (0.14%) and grains (0.12%) were deficient in Mg. Feeds and forages were found to be adequate in K (1.50%). Cereals straws were found to be deficient in S (0.11%). Greens were good source of Cu (12.02 ppm). Wheat straw was found to be low in Zn (18 ppm), but high in Mn (225 ppm) and Fe (509 ppm). Local grasses and azolla green were found to be rich source of Co (>1.00 ppm). Se (0.63 ppm) was present in appreciable quantities in most of the feedstuffs. Conclusions: From the present study, it was apparent that the feeds and forages available in the state of Jharkhand may not meet the requirements for Ca, P, Mg, Cu, Zn and Co in order to sustain a milk production of ~10 kg/day. Therefore, it is necessary to supplement these deficient minerals through area specific mineral mixture in the ration of dairy cows for improving productivity and reproduction efficiency.

정장액내의 금속성분이 정액지표 및 가임능에 미치는 영향 (Effect of Metal Components in Seminal Plasma on Seminal Parameter and Male Fertile Ability)

  • 박남철;김민수;윤종병
    • Clinical and Experimental Reproductive Medicine
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    • 제24권1호
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    • pp.67-81
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    • 1997
  • To determine the concentration and the physiologic role of metal components in blood plasma and seminal plasma in relation to male infertility, the concentrations of twelve metal components in blood plasma and seminal plasma including Na, Mg, K, Ca, Cr, Mn, Fe, Cu, Zn, Se, Cd and Pb were measured by atomic absorbance spectrophotometery or ion selective electrode analysis. Semen and blood samples were obtained from a total of 110 men including 70 male infertility patients, 20 vasectomized persons and 20 fertility proven volunteers visited to the Male Infertility Clinic of Pusan National University Hospital. The concentrations of Ca, Zn, Mg, Cr and Cd in control group were higher in seminal plasma than in blood plasma, and additionally Pb were higher in infertility group. The concentrations of all metal components revealed no significant difference according to patients' age, resident, occupation, sperm density, motility and hormone level in blood plasma, but some metal components including Ca, Mg, Cu, Mn, Cd and Pb revealed a significant difference according to each these parameters except patient's age in seminal plasma. The concentrations of Mn, Cd and Pb in the vasectomy persons were higher than in the infertility group III including testicular and epididymal factors, but not in blood plasma. We conclude that the quantitative changes of metal components in the seminal plasma may have effects on not only spermatogenesis and sperm function, but also contribute to diagnostic parameter according to organ specificity of the metal in the male reproduction.

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Evaluation of the health status of preschool children stratified based on the weight-length index (WLI)

  • Shin, Kyung-Ok;Chung, Keun-Hee;Park, Hyun-Suh
    • Nutrition Research and Practice
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    • 제4권5호
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    • pp.383-392
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    • 2010
  • This study was conducted to prepare basic materials and offer advice regarding dietary habits to prevent and cure childhood obesity by comparing and analyzing dietary habit, nutritional status, blood factors, and mineral contents of hair. All subjects were stratified by their weight-length index (WLI). According to the standard WLI values, 64.9% of children were within the normal value, 13.5% of children were underweight, and 21.6% of children were overweight and obese (WLI ${\geq}$ 110%). Overall, the score assessed dietary habit for all children was $21.32{\pm}2.55$ point (921 subjects), with 5.1% of children having excellent dietary habits and 3.1% having poor dietary habits. Additionally, 37.9% of underweight children, 37.6% of normal weight children, and 43.2% of overweight and obese children consumed higher amounts of protein than underweight children did (meat, fish, eggs, and soy products) (P < 0.05). Overweight and obese children consumed more fried foods than underweight or normal weight children (P < 0.05). Moreover, 38.0% of the children had hemoglobin levels of 12 g/dl, while 7.6% were anemic (11.1 g/dl). When a hematocrit level of 33% was taken as the standard, 11.0% of children were anemic. The plasma transferrin content was $263.76{\pm}54.52$ mg/dl in overweight and obese children. The mean values of Fe, Cu, Ca, Cr, Mn, Se, Na, K, Li, V, Co, and Mo were within the reference values, but the Zn concentrations of underweight, normal weight, and overweight and obese children were $67.97{\pm}28.51$ ppm, $70.09{\pm}30.81$ ppm, and $73.99{\pm}30.36$ ppm, respectively. The Zn concentration of overweight and obese children ($73.99{\pm}30.36$ ppm) was lower than that of the standard value (180~220 ppm). Therefore, a nutritional education program and new guidance for dietary pattern should be developed to reduce the number of underweight and overweight and obese children.

MINERAL CONCENTRATION IN RICE STRAW AND SOIL IN KYONGBUK PROVINCE, KOREA

  • Ramirez, C.E.;Kumagai, H.;Hosoi, E.;Yano, F.;Yano, H.;Jung, K.K.;Kim, S.W.
    • Asian-Australasian Journal of Animal Sciences
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    • 제7권1호
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    • pp.125-129
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    • 1994
  • A field survey was carried out in Korea to assess the mineral composition of rice straw since it is a cheap and available cattle feedstuff. Forage and soil samples were collected in 4 localities in the Kyongbuk province. Soil analysis were also carried out in order to establish the relationships between soil composition and mineral content in the rice straw. Based on NRC tables, the rice straw samples provided adequate amounts of Mg, Ca, K, S, Mo, Mn and Zn. Percentages of samples deficient in P, Na, Cu and Se were 83, 50, 67 and 83 respectively. Soil samples, whose mean pH was 5.8 and mean organic matter content was 3.99%, were comparatively acidic and had high organic matter content. They also had high amounts of extractable Fe and Mn. Correlation coefficients between mineral content in soil and rice straw were low, i.e., 0.42 for Me (p < 0.05), and 0.37 for Mo (p < 0.05). The low or nonexistent correlation between soil and forage composition indicates the difficulty of establishing appropriate methods of mineral availability to the plants.

Association between Trace Element and Heavy Metal Levels in Hair and Nail with Prostate Cancer

  • Karimi, Golgis;Shahar, Suzana;Homayouni, Nasim;Rajikan, Roslee;Bakar, Nor Faizah Abu;Othman, Mohd Sham
    • Asian Pacific Journal of Cancer Prevention
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    • 제13권9호
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    • pp.4249-4253
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    • 2012
  • While associations between trace elements and heavy metals with prostate cancer are still debatable, they have been considered as risk factors for prostate cancer. Thus, this study aimed to detect any links between selected minerals and heavy metals including Se, Zn, Cu, Mn and Fe with prostate cancer. A case control study was carried out among 100 subjects (case n=50, control n=50), matched for age and ethnicity. Trace elements and heavy metals level in hair and nail samples were determined by ICP-MS. Mean selenium levels in hair and nail of the cases were significantly lower as compared to controls. A similar trend was noted for zinc in both hair and nail samples, whereas the mean level of copper was significantly higher in cases than controls. Similar elevation was noted for iron and manganese (p<0.05 for all parameters). Low levels of selenium and zinc and high levels of copper, iron and manganese appear to be associated with the risk of prostate cancer. Further studies to elucidate the causal mechanisms and appropriate chemopreventive measures are needed.

시화호 주변 해역에 서식하는 진주담치 체내 위생세균 및 미량금속 함량분포특성

  • 김평중;박승윤;송기철;변한석;박영철;이완석;윤이구
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2008년도 추계학술발표회 발표논문집
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    • pp.297-299
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    • 2008
  • 시화호 주변 해역에 서식하는 진주담치 내의 위생세균 및 비소(As), 카드뮴(Cd), 크롬(Cr), 철(Fe), 수은(Hg), 망간(Mn), 니켈(Ni), 납(Pb), 셀렌니움(Se) 및 아연(Zn)등의 미량원소들을 분석한 결과를 요약하면 다음과 같다. 본 연구해역의 전 조사정점에서 위생세균이 다소 높은 농도를 보이는 것은 아마도 조사시기가 하계로써 담수유입에 따른 영향으로 보여진다. 미량금속의 농도는 우리나라 식품위생기준 이내의 양호한 농도분포를 보였으며, 비소(As), 크롬(Cr), 니켈(Ni) 및 납의 경우 시화호 및 시화호 외측해역에서 유의한 농도차이(p<0.05)를 나타내지 않았으나 카드뮴 및 망간의 농도의 경우 시화호내에서 다소 높은 농도를 보였다(p<0.05). 반면에 구리, 수은, 셀렌니움 및 아연 등의 농도는 시화호에서 보다 시화호 외측해역에서 다소 높은 농도를 보였다(p<0.05). 또한 각성분간에 상관관계를 살펴보면 비필수원소중 수은과 카드물의 경우 셀레니움과 좋은 정의 상관성를 보이는 것으로 보아 이들 비필수원소의 셀레니움이 진주담치의 황산화성물질로 작용하는 것으로 보여 진다.

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