• Title/Summary/Keyword: Fastness to Light

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Photo-grafting Dyeing of Wool Fabrics with ${\alpha}$-bromoacrylamide reactive dye (반응성 염료를 이용한 양모직물의 광그라프트 염색)

  • Dong, Yuanyuan;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.31-31
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    • 2011
  • Lanasol dyes containing ${\alpha}$-bromoacrylamide or ${\alpha},{\beta}$-dibromopropionylamide group are used for wool dyeing. They are normally applied to wool under pH 4.5 to 6.5 at $100^{\circ}C$. Although wool fabric can be dyed to obtain deep colour, high light and wet fastness, the dyeing processes need long dyeing time at high temperature, with salt addition, which inevitably causes environmental problems. Grafting is a modification method for textile where monomers are covalently bonded onto the polymer chain. It can be initiated by ozone, ${\gamma}$ rays, electron beams, plasma, corona discharge and UV irradiation. Coloration by UV-induced photografting exhibits several advantages such as fast reaction rate, energy saving, simple equipment, easy exploitation and environmentally friendliness. Also it requires much lower energy compared to the conventional dyeing and less damage to the substrate. In this study, a direct sequential UV-induced photografting onto wool fabrics was discussed. To understand the graft polymerization mechanism further, several characterization methods were used. Moreover, the effects of several principal factors on the graft photopolymerization were investigated. Furthermore, the colorfastness results were compared with conventional dyeing methods.

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A Pre-treatment Process for Natural Dyeing of Wool to Impar t Durable Antimicrobial Efficacy

  • Raja, A.S.M.;Thilagavathi, G.
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.69-75
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    • 2011
  • A pre-treatment process has been developed for natural dyeing of wool by which the dyed materials have been imparted antimicrobial efficacy against both gram-positive and gram-negative bacteria durable up to 20 washes. In this process, wool fabrics were treated with citric acid under oxidizing condition prior to dyeing. The treated fabrics were then dyed with four different types of natural dye powders obtained from leaves of silver oak, wattle, tanner's senna and flame of forest. All the natural dyes produced yellowish brown colour on wool fabrics. The washing and light fastness properties of the fabrics subjected to pre-treatment were one grade higher compared to those of the dyed fabrics without pre-treatment. The pre-treated wool fabrics showed antimicrobial efficacy against both gram-positive bacteria (Staphylococcus aureus) and gram-negative bacteria (Escherichia coli). The fabrics dyed without pre-treatment showed antimicrobial efficacy against gram-positive bacteria (Staphylococcus aureus) only. The durability of antimicrobial efficacy was higher in pre-treated and dyed wool fabrics compared to the dyed fabrics without pre-treatment.

Reactive Dyeing of Photografted para-Aramid Fabrics

  • Kim, Eun-Min;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.3
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    • pp.155-162
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    • 2011
  • para-Aramid has limited dyeability because of its highly crystalline structure and compactness. To improve the dyeability of the para-aramid to reactive dyes of bright color in deep shade, the fabrics were photografted under continuous UV irradiation with dimethylaminopropyl methacrylamide and 4-benzoyl benzoic acid as a monomer and a hydrogen -abstractable photoinitiator respectively. A UV energy of 35J/$cm^2$ and a photoinitiator concentration of ten percent or more with respect to the monomer in the formulation was required for optimal photografting. Grafting yield increased with higher monomer application level. Surface analysis indicated significant alterations in the atomic composition of the photografted fabric surface and the fabric surface was covered with the grafted polymers. While the pristine para-aramid fabrics showed no appreciable dyeability to the ${\alpha}$-bromoacrylamide reactive dyes, the grafted para-aramid fabrics enhanced the dyeability to the reactive dyes substantially. In case of C.I. Reactive Blue 50, a K/S value of 8.7 can be obtained with the grafted para-aramid fabrics with a grafting yield of 2.3 %. Also the color fastness properties of the dyed fabrics was excellent in the conditions of washing, rubbing and light irradiation.

Dyeing of High Strength and High Molecular Weight Polyethylene Fiber Using Super Hydrophobic Fluorescence Dyes (초소수성 형광염료에 의한 고강도/고분자량폴리에틸렌섬유의 염색)

  • Kim, Taekyeong;Park, Jihoon;Lee, Junheon;Kim, Taegun
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.223-230
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    • 2017
  • Three super hydrophobic fluorescence dyes were selected to dye high molecular weight polyethylene fiber and their molar absorptivity, emission spectrum, and quantum yield were measured. From the results of color strength on the fiber, all the three dyes exhibited linear increase according to the dye concentration and Fluoro3 dye showed the highest color strength among them. Emission strength of the fluorescence dyes on the fiber was investigated according to the dye concentrations. The emission was increased with the increase of the dye concentration at relatively low dye concentration and then after showing the maximum emission strength the emission was decreased at higher dye concentrations. The highest emission was obtained in Fluoro2 dye. Color fastness to washing and rubbing was generally good enough, however, especially to light, only Fluoro3 dye exhibited rating 3 acceptable practically and Fluoro1 and 2 was ratings 1 which is unacceptable level.

Design of Natural Dyeing Hanbok-Type Leisurewear Using Elm Bark and Rubia akane Nakai Composite Extracts (느릅나무껍질과 꼭두서니 복합추출물을 이용한 천연염색 한복형 휴식복 디자인)

  • Jang, Hyun-Joo
    • Fashion & Textile Research Journal
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    • v.23 no.2
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    • pp.151-158
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    • 2021
  • The purpose of this study was to develop high-quality naturally dyed leisurewear with images of traditional Korean clothing that keeps a psychologically comfortable and physically pleasant environment at home and in vacation spots. The root bark of elm trees, the atopic skin, is also known to be effective for the relief of rhinitis and atopic diseases as well as stress and insomnia. However, there is insufficient color in the bark for the dyeing of fashion products, so to compensate for the lack of color, for dyeing purposes it was combined with a composite extract called Rubia akane Nakai resulting in a relatively bright red color. Except for the light fastness, all the fastnesses were rated 4 to 5, showing excellent results. Through complex dyeing using elm bark and pods extract the author produced four high-quality vests, one-piece, a gown, and jeogori-pantsuits of silk materials with Korean images that are suitable wear for relaxing comfortably at home and during breaks and which provide a comfortable and physically pleasant experience. The vest was made with the formal style of Bae-ja and Dang-eu, the dress is made of Cheok-lik, and the gown is made of Wonsam. It will be meaningful at a time when the importance of rest is increasing due to the healing clothes worn by busy modern people.

A Study on Dyeability of Cotton Fabrics -Effects of Dyeing on Water Repellent Finished Cotton- (면직물의 염색성에 관한 연구 -발수가공포의 염색효과-)

  • 장지혜
    • Journal of the Korean Home Economics Association
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    • v.35 no.3
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    • pp.115-124
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    • 1997
  • In this study, Water Repellent Finish was carried out before dyeing on cotton fabrics. It was aimed to improve on dyeing properties of cotton fabrics with direct dye. The results obtained were summerized as follows: 1. The K/S value of water repellent finished cotton fabrics increased. This phenomena in water repellent finished cotton fabrics were much more noticiable than unfinished cotton fabrics. 2. The color fastness(light, washing, and rubbing) of water repellent finished cotton-dyed were worse than those of unfinished cotton-dyed with direct dye. △E of water repellent finished cotton fabrics wasn't showed significant difference as compared with that of unfinished cotton fabrics. 3. The water repellency of finished cotton after dyeing got down from 100 to 70. That of finished-cotton before dyeing was 100. 4. Moisture regain, stiffness and weight of finished cotton fabrics were not almost differenciated with unfinished cotton fabrics. Moreover, the tensile strength of finished cotton fabrics was increased compared to that of unfinished cotton fabrics. As conclusion, according to the above results when the cotton fabrics were dyed with direct dye, it was much more effective that water repellent finished cotton fabrics were dyed rather than trational process, that is pre-dyeing after-finishing even if, by low liquor ratio. The physical properties of fabrics were maintained or increased.

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Natural Dyeing of Silk Fabrics with Humulus japonicus Extract (환삼덩굴을 이용한 견직물의 천연염색에 관한 연구)

  • Ha, Young Kab;Lee, Jeong Sook
    • Textile Coloration and Finishing
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    • v.26 no.3
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    • pp.263-271
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    • 2014
  • The purpose of this study is to investigate the dyeability of silk fabrics with Humulus japonicus (Hwansam) extract which is a kind of weeds that grows wild in the suburbs. In the research, the general extract method was conducted with the extract from fresh herb of root-removed Humulus japonicus while we investigated the optimal dyeing conditions and dyeability depending on the changes of the kind of mordants, methods and temperature. The functional properties such as antibacterial activities, deodorization and UV protection were also reviewed. The ideal output, as a result, was shown at 100% of dye concentration, $90^{\circ}C$ of dyeing temperature and 40 minutes of dyeing time while in terms of dye uptake depending on the kind of mordants and methods, it was found that among four mordants of $SnCl_2$, $AlK(SO_4)_2$, $CuSO_4$, and $FeSO_4$ post-mordanting with $FeSO_4$ showed the best result. Color fastness to washing, dry cleaning and rubbing was found strong at grade 4-5 and the grade to light was as good as 3 while to perspiration was good at 4-5 as well. In aspects of functional properties, it showed excellent results of 99% deodorization rate, 98% UV protection rate and 99.9% bacterial reduction against Staphylococcus aureus.

Change of Dyeability and Physical Properties of Modified Wool by Formic Acid, Ultrasonic Wave and Heat Treatment (포름산과 초음파 열처리에 의한 양모의 물성 및 염색성 변화)

  • Choi, Woo-Hyuk;Kim, Mi-Kyung;Kim, Jong-Won;Yoon, Seok-Han;Um, In-Cheol
    • Textile Coloration and Finishing
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    • v.23 no.4
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    • pp.290-297
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    • 2011
  • In this study, the possibility of the practical development of highly sensitive clothing textiles using fibrillated wool fibers were considered by determining the dyeability, the physical and mechanical properties of fibrillated wool fibers treated under strong acid and high temperature ultrasonic wave irradation and they were compared with those of untreated wool fibers. The color strengths of the dyed fibrillated wool fabrics increased by the acid metal complex dyes contrary to the untreated wool fabrics, and color fastness properties to rubbing, light, and dry cleaning were excellent, similar to those of the untreated wool fabrics. The tensile strengths of fibrillated wool fabrics were also kept after the dyeing. Moreover, the Numeri, Fukurami, and THV of the fibrillated wool fabrics were better than those of the untreated wool fabrics.

Natural Dyeing of Fabrics with a Dyebath Extracted from C. Umshiu Mandarin Peel (온주밀감 과피 추출액을 이용한 직물의 천연염색)

  • 임은숙;이혜선
    • Journal of the Korean Society of Costume
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    • v.54 no.6
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    • pp.141-148
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    • 2004
  • This study examines the dyeability of fabrics in relation to dyeing temperature, time, concentration, and the number of repeated dyeings. For this study, at first we extracted natural dyes from the peel of C.umshiu mandarin, which is fast as a dye and considered as recycling agricultural wastes. Additionally, it represents the image of Jeju Island. Then, we dyed cotton, wool, silk and nylon fabrics with the extracted dyes. The findings of this study are as follows. 1) Dyed cotton, wool, silk and nylon fabrics with the extract of C.umshiu mandarin peel are generally yellow. 2) Wool, nylon, silk, and cotton, in this order, are of good dyeability; Wool fabrics have the highest dyeability and cotton fabrics have the lowest. The dyeabilty of cotton fabrics was not improved even after dyeing in different conditions. 3) Colorfastness with washing, rubbing and perspiration are all good, while colorfastness with light is poor. 4) Higher dyeing concentration makes better dyeability. 5) Dyeability is enhanced as the dyeing temperature increases, while the dyeability of silk and nylon is relatively good even at low temperatures. 6) Looking at dyeability according to dyeing time, the longer the dyeing time, the better the dyeablility. Sixty minutes of dyeing time is appropriate to dye fabrics. 7) With an increase in the number of repeated dyeings, increased dyeability is obtaihed.

Utilization of Bamboo Leaves as a New Resource of Natural Green Colorants

  • Shin, Younsook;Cho, Arang;Yoo, Dong Il
    • Textile Coloration and Finishing
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    • v.24 no.4
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    • pp.247-252
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    • 2012
  • The objective of this study was to find an appropriate method and process for protecting the green color in bamboo leaves and subsequent extraction of the green colorants, chlorophyll. Various inorganic salts including cupric sulfate, ferric sulfate, and zinc chloride were employed as green color protectors. Accordingly, the effects of metal salts and treatment conditions on color protection were investigated to find appropriate protector and conditions. And also, the efficacy of bamboo colorants as a natural green dye was evaluated through dyeing and colorfastness tests. Antimicrobial activity of dyed fabrics was measured by shake flask method in terms of bacterial reduction rate using Staphylococcus aureus(ATCC 6538). On the basis of experimental results for stabilizing bamboo leaves colorants, it was confirmed that Cu was the most appropriate metal type considering dye uptake, photostability and light fastness, and its optimum concentration was 0.025%. After the stabilization, the colorants were extracted efficiently at NaOH aqueous solution of 1.00%. It was concluded that bamboo leave has a high potentiality as new resources to produce a natural green dye with antimicrobial functionality.