• Title/Summary/Keyword: Factory wastewater

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Removal of Nitrogen Using by SOD Process in the Industrial Wastewater Containing Fluoride and Nitrogen from the Zirconium Aolly Tubing Production Factory of the Nuclear Industry (원자력산업 지르코늄합금 튜브 생산공장에서 배출되는 불소.질소 함유 폐수의 황산화탈질을 이용한 질소처리)

  • Cho, Nam-Chan;Moon, Jong-Han;Ku, Sang-Hyun;Noh, Jae-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.855-859
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    • 2011
  • The main pollutants from zirconium alloy tubing manufacturing process in nuclear industry are nitrate ($NO_3-N$) and fluoride (F-)Nitric acid, and hydrofluoric acid is used for acid pickling. The process for the removal of nitrate and fluoride is composed of 1st chemical coagulation, SOD (Sulfur Oxidation Denitrification) process using sulfur-oxidizing denitrification, and 2nd chemical coagulation. The characteristic of the wastewater treatment is an application of SOD process. The SOD Process is highly received attention because it is significantly different from existing processes for sulfur denitrification. A JSC (JeonTech-Sulfur- Calcium) Pellet is unification of sulfur and alkalinity material. According to result of SOD process in wastewater treatment plant, the removal efficiency of T-N was over 91% and the average concentration of T-N from influent was 147.55 mg T-N/L and that from effluent was 12.72 mg T-N/L. Therefore, SOD process is a useful to remove nitrogen from inorganic industrial wastewater and a new development of microbial activator was shown to be stable for activation of autotrophic bacteria.

Treatment of Pharmaceutical Wastewaters by Hydrogen Peroxide and Zerovalent Iron

  • Jeon, Byeong-Cheol;Nam, Se-Yong;Kim, Young-Kwon
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.9-14
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    • 2014
  • Fenton reaction with zerovalent iron (ZVI) and $Fe^{2+}$ ions was studied to treat pharmaceutical wastewaters (PhWW) including antibiotics and non-biodegradable organics. Incremental biodegradability was assessed by monitoring biochemical oxygen demand (BOD) changes during Fenton reaction. Original undiluted wastewater samples were used as collected from the pharmaceutical factory. Experiments were carried out to obtain optimal conditions for Fenton reaction under different $H_2O_2$ and ion salts (ZVI and $Fe^{2+}$) concentrations. The optimal ratio and dosage of $H_2O_2$/ZVI were 5 and 25/5 g/L (mass basis), respectively. Also, the optimal ratio and dosage of $H_2O_2/Fe^{2+}$ ions were 5 and 35/7 g/L (mass basis), respectively. Under optimized conditions, the chemical oxygen demand (COD) removal efficiency by ZVI was 23% better than the treatment with $Fe^{2+}$ ion. The reaction time was 45 min for ZVI and shorter than 60 min for $Fe^{2+}$ ion. The COD and total organic carbon (TOC) were decreased, but BOD was increased under the optimal conditions of $H_2O_2$/ZVI = 25/5 g/L, because organic compounds were converted into biodegradable intermediates in the early steps of the reaction. The BOD/TOC ratio was increased, but reverse-wise, the COD/TOC was decreased because of generated intermediates. The biodegradability was increased about 9.8 times (BOD/TOC basis), after treatment with ZVI. The combination of chemical and biological processes seems an interesting combination for treating PhWW.

Analysis of Air-water Temperature Elasticity Taking into Account the Confidence Interval in Major Tributary of Nakdong River (낙동강 주요 지류의 신뢰구간을 고려한 기온-수온 탄성도 분석)

  • Park, Jaebeom;Kal, Byungseok;Kim, Seongmin
    • Journal of Wetlands Research
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    • v.22 no.3
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    • pp.178-186
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    • 2020
  • In this study, the elasticity was calculated and sensitivity analysis was performed using air-water temperature data of the major tributaries of the Nakdong River. We developed a nonparametric elasticity analysis technique capable of estimating the confidence interval for elasticity and verifying the hypothesis, and examined its applicability compared to the existing method using the median value. It is analyzed that the elasticity of winter is low and the elasticity of summer and autumn is high, so that the fluctuation of water temperature and water quality according to the fluctuation of air temperature is large. The spatial elasticity tends to be low in the Geumho River area, which is influenced by artificial factors such as sewage treatment plant effluent, small and medium-sized livestock wastewater, and small-scale factory wastewater. Since the elasticity of major tributaries of the Nakdong River is over weak and is reasonable at a significance level of 5%, it was analyzed that the air-water temperature fluctuation caused by climate changes is large.

Application of a Thermophilic Aerobic Digestion Process to Industrial Waste Activated Sludge Treatment

  • Kim, Young-Kee;Eom, Yong-Suk;Oh, Byung-Keun;Lee, Won-Hong;Choi, Jeong-Woo
    • Journal of Microbiology and Biotechnology
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    • v.11 no.4
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    • pp.570-576
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    • 2001
  • Thermophilic aerobic bacteria were applied in the degradation of industrial waste activated sludge (WAS) on a laboratory scale expreiment. The performance of digestion was estimated by measuring the reduction of total suspended solids (TSS), dissolved organic carbon (DOC), and total organic carbon (TOC). Among three strains of Bacillus stearothermophilus and three strains of Thermus species, B. stearothemophilus ATCC 31197 showed the best overall efficiency level for the degradation of industrial WAS, which was collected from a wastewater treatment plant in an oil refinery factory. Industrial WAS coul be successfully detraded in a batch digestion with ATCC 31197. The stability of the digestion process with ATCC 31197 was successfully verified by semi-continuous (fill-and-draw) digestion experiment. From the results of this study, it was shown that the thermophilic aerobic digestion process with ATCC 31197 could efficiently be applied to the degradation of industrial WAS.

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Evaluation of Fugitive Emission Characteristics of Airborne Volatile Organic Compounds from Different Source Categories (발생원 유형에 따른 공기 중 휘발성 유기화합물의 비산배출 특성 평가)

  • 백성옥;김미현;서영교
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.4
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    • pp.363-376
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    • 2003
  • In this study, the fugitive emission characteristics of airborne volatile organic compounds from different source categories were evaluated with respect to the concentrations measured in the vicinity of the sources. A total of 22 different sources were investigated, including gasoline storage and filling stations, painting spray booth, laundry, printing officer, textile industries, and a number of environmental sanitary facilities such as landfill, wastewater treatment and incineration plants. The target VOCs included 83 individual compounds, which were determined by adsorption sampling and thermal desorption coupled with GC/MS analysis. Overall, the aliphatic compounds appeared to be the most abundant class of compounds in terms of their concentrations, followed by aromatic, and halogenated hydrocarbons. As a single compound, however, toluene was the most abundant one, explaining 11% of the total VOC concentrations as an average of all the dataset. Among source categories, petroleum associated sources such as gasoline storage/filling stations, and laundry factory were identified as the most significant sources of aliphatic hydrocarbons, while aromatic VOCs were dominantly emitted from the sources handling organic solvents, such as painting booth, printing offices, and textile dyeing processes. However. there was no apparent pattern in terms of the contributions of eath group to the total VOCs concentrations in environmental sanitary facilities. It was also found that the activated carbon adsorption tower installed for the VOC emission control in some facilities do not show any effective performances, which may result in the increased VOC levels in the ambient atmosphere.

Feasibility of Recycling Residual Solid from Hydrothermal Treatment of Excess Sludge

  • Kim, Kyoung-Rean;Fujie, Koichi;Fujisawa, Toshiharu
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.112-118
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    • 2008
  • Residual solid in excess sludge treated by hydrothermal reaction was investigated as raw material for its recycling. Treated excess sludge and residual solid were also focused on their content change during hydrothermal reaction. Two kinds of excess sludge, obtained from a local food factory and a municipal wastewater treatment process, were tested under various conditions. Following hydrothermal reaction, depending on the reaction conditions, biodegradable substrates in treated excess sludge appeared to increase. The separated residual solid was a composite composed of organic and inorganic materials. The proportion of carbon varied from 34.0 to 41.6% depending on reaction conditions. Although 1.89% of hazardous materials were detected, SiO2 (Quartz) was a predominant constituent of the residual solid. X-ray diffraction (XRD) experiments revealed that the residual solid was of a partially amorphous state, suggesting that the residual solids could be easily converted to stable and non harmful substances through a stabilization process. Thus, this technology could be successfully used to control excess sludge and its reuse.

A Study on the Estimation of the GHGs Emissions to the Reuse of De-ionized Water Production Process in Semiconductor Factory (반도체 생산용 초순수 제조공정의 농축수 재이용에 따른 온실가스 발생량 평가에 관한 연구)

  • Han, Jong-Min;Chung, Jin-Do;Kim, San
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.518-525
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    • 2018
  • In the 21st century, human beings are becoming increasingly concerned about greenhouse gas emissions as the environment changes due to climate change become serious. The temperature of Korea has risen by approximately $1.5^{\circ}C$ from 1904 to 2000, and the climate is changing gradually to a subtropical climate. As a result, the frequency of floods and droughts increases, so that the water available to humans is decreasing every year, and the cost of using city water is rising every year. The reuse of wastewater that is normally abandoned is inevitable. This study examined the monthly data for 6 months of operation by installing a reuse system of concentrated wastewater (Re R/O System) that is generated during the process of manufacturing de-ionized water (DI-Water System) used in semiconductor processing. As a result of the survey, the city water supply saved approximately $2,767m^3$ per month. The average annual greenhouse gas emissions was $1,329.07kg-CO_2$ per month due to the electricity consumption of the water reuse system. On the other hand, because of the reduction in city water supply, the average monthly average of $918.64kg-CO_2$ was reduced, and the greenhouse gas emissions were increased to $410.43kg-CO_2$ per month. If it improves some processes in the water reuse system, the amount of greenhouse gas emissions can be reduced by an average of $254.41kg-CO_2$ per month.

The Study of Preparation of Block Using Wastewater Sludge of Petrochemical Factory (석유화학공장 폐수슬러지를 이용한 벽돌제조 연구)

  • Hu, Kwan;Lu, Juk-Yong;Wang, Seung-Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.2
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    • pp.66-73
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    • 2003
  • To investigate the availability of solidified wastes as resource, wastewater sludge, waste gypsum and fly ash were mixed and the results with various mixing ratios are as follows. Compressive strength turned out to be increasing as the amount of waste gypsum increases, keeps longer curing inhibition, and higher forming Pressure under the conditions of waste gypsum/sludge ratio 0.31-0.45, and 0.9kg cement as 15% and 1.2kg cement as 20% of total amount. Solidified agent under the fly ash/sludge ratio 0.45, 0.6, compressive strength seemed to be higher than standard one which means solidified wastes with these conditions could be applicable in real life. These results inform that concentrations of the leachate $Cr^{+6}$, Cu, Zn, Cd, Pb solidified matrix, containing low concentration of heavy metal, were cured with/without enough time it still will cause adverse effect on nature environment and application of heavy metal sequester must be needed to reuse industrial wastes from incineration plant solidified matrix. Total cost price, when considering manufacturing capability of the facilities for resourcerizing as 18,000ton was presented 678,664,000 won, as it were, manufacturing cost price was 37,704 won per ton. The results as above has shown that it's possible to use the mixture of waste gypsum/sludge, fly ash/sludge, cement, additions, and solidification matter as substitute of materials like brick, block, interlocking which has proper compressive strength of KS L 5201 and KS F 4004.

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Recovery and Utilization of Proteins and Lipids from the Washing Wastewater in Marine Manufacture by Isoelectric Point Shifting Precipitation Method;4. Utilization of the Recovered Protein Fractions as the Alternative Feed of Fish Meal. (수산가공공장폐액의 등전점이동 응집처리에 의한 유용성분재회수이용;4. 회수단백질의 어분 대체 사료로서의 이용)

  • Kim, Gwang-Woo;Kim, Ga-Hyeon;Ueo, Myung-Hee;Kim, Ok-Seon;Cho, Soon-Yeong
    • Journal of Life Science
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    • v.18 no.6
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    • pp.832-838
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    • 2008
  • Mackerel water-soluble protein fraction produced by washing the mackerel meat were concentrated by isoelectric point shifting precipitation process, and the concentrates were utilized as the alternative feed of fish meal. In the 1st aquaculture diet experiment for Israel common carp, the feed conversion ratio decreased in proportion to the rise in the percentage of the recovered protein containing a residual lipid, which was added to the fish meal. It was supposed that the low feed efficiency was because of lipid oxidation in the recovered protein fraction. In addition, 2nd aquaculture diet experiment for Israel common carp was conducted after removing the oxidized lipid in the recovered protein fish meal. When a portion of the fish meal was substituted by the recovered protein devoid of the residual lipid, the feed conversion ratio increased in proportion to the amount of the substitute being added to the fish meal. Therefore, the recovered protein fraction of the mackerel washing wastewater from mackerel processing factory could be used as the alternative feed of fish meal.

Decolorization Efficiency of Different Dyes by Extract from Spent Mushroom Substrates of Pleurotus eryngii (큰느타리(Pleurotus eryngii)의 수확 후 배지추출물을 이용한 다양한 염료의 탈색효과)

  • Lim, Seon Hwa;Kwak, A Min;Min, Gyeong Jin;Kim, Sang Su;Lee, Sang Yeop;Kang, Hee Wan
    • The Korean Journal of Mycology
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    • v.42 no.3
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    • pp.213-218
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    • 2014
  • Water extract from spent mushroom substrates (SMS) of Pleurotus eryngii was utilized in decolorization of eight synthetic dyes and wastewater from a textile factory. High laccase activity was detected in the extract of P. eryngii (SMSE). The SMSE showed that decolorization rate was 34~93% after 24 h incubation without any mediator on eight dyes including Rit-blue and Rit-red used in fiber dyeing. Dye decolorization rate more than 90% was observed on bromophenol blue and remazol brilliant blue R (RBBR). Dye in textile wastewater was decolorized at room temperature after three days by addition of P. eryngii SMSE. The results suggest that biological decolorization of dyes using the P. eryngii SMSE can be used as environmental friendly materials.