• Title/Summary/Keyword: Face-to-face (F2F)

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Heteroleptic Phosphorescent Iridium(III) Compound with Blue Emission for Potential Application to Organic Light-Emitting Diodes

  • Oh, Sihyun;Jung, Narae;Lee, Jongwon;Kim, Jinho;Park, Ki-Min;Kang, Youngjin
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3590-3594
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    • 2014
  • Blue phosphorescent $(dfpypy)_2Ir(mppy)$, where dfpypy = 2',6'-difluoro-2,3'-bipyridine and mppy = 5-methyl-2-phenylpyridine, has been synthesized by newly developed effective method and its solid state structure and photoluminescent properties are investigated. The glass-transition and decomposition temperature of the compound appear at $160^{\circ}C$ and $360^{\circ}C$, respectively. In a crystal packing structure, there are two kinds of intermolecular interactions such as hydrogen bonding ($C-H{\cdots}F$) and edge-to-face $C-H{\cdots}{\pi}(py)$ interaction. This compound emits bright blue phosphorescence with ${\lambda}_{max}=472nm$ and quantum efficiencies of 0.23 and 0.32 in fluid and the solid state. The emission band of the compound is red-shifted by 40 nm relative to homoleptic congener, $Ir(dfpypy)_3$. The ancillary ligand in $(dfpypy)_2Ir(mppy)$ has been found to significantly destabilize HOMO energy, compared to $Ir(dfpypy)_3$, $(dfpypy)_2Ir(acac)$ and $(dfpypy)_2Ir(dpm)$, without significantly changing LUMO energy.

Effects of the Wire Net Composition on Flexural Properties of Sawdustboard (철강구성(鐵鋼構成)이 톱밥보오드의 휨성질(性質)에 미치는 영향(影響))

  • Lee, Phil-Woo;Suh, Jin-Suk
    • Journal of the Korean Wood Science and Technology
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    • v.13 no.4
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    • pp.67-72
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    • 1985
  • To improve the bending strength of sawdustboard, verious resin contents of 10, 13, 16, and 19% were applied to the thin shell (face layer) composed with wire net or not. The shell effect of sawdust and wire net composition formed with core sawdustboard were evaluated. Forcusing on the effects of wire net composition and noncomposition including a comparison with chipboard and veneer complyboard, bending properties (Modulus of rupture (MOR), Modulus of elasticity (MOE), Stress at proportional limit ($S_{pl}$). Work to maximum load ($W_{ml}$))were analyzed and discussed. 1. In modulus of rutpute, veneer comply was the highest (621.5 kg/$cm^2$), and next decreasing order was wire net composition (159.1 kg/$cm^2$), chipboard (81.75 kg/$cm^2$), and wire net noncomposition (76.21 kg/$cm^2$) as in modulus of elasticity, work to maximum load, except for stress at proportional limit. 2. The highly significant effects were shown in both wire net composition and noncomposition, at the same time wire net composition exceeded two times of noncomposition throughout resin contents in bending properties. Chipboard was similar to the mean or 16% resin content in noncomposirion. 3. Every board in wire net composition above 10% resin content was beyond 100 kg/$cm^2$ in MOR, minimum allowable strength for structural use according to KS F 3104. In conclusion, the feasibility for improving the bending strength of weak sawdustboard by wire net composed shell was offered.

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Compact Dual-Band MIMO Antenna with High Isolation Performance (소형 고 격리도 듀얼 밴드 MIMO 안테나)

  • Yeom, In-Su;Jung, Chang-Won
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.21 no.8
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    • pp.865-871
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    • 2010
  • A compact dual-band(IEEE 802.11b: 2.4~2.5 GHz, 11a: 5.15~5.825 GHz) 2-channel MIMO antenna for PMP applications is presented. The proposed antenna is composed of a planar inverted F-shape antenna(PIFA) operating at 2 GHz band and a loop antenna operating at 5 GHz band. The proposed antenna is orthogonally arranged at the edge of the ground plane for polarization and pattern diversities with excellent isolation characteristics. The two PIFA antennas operating 2 GHz have connecting line($\lambda_g$/4) face to the feed point for high isolation and low correlation at 2 GHz band. The two loop antennas connected each other in the bottom side to improve the isolation at 5 GHz band. The proposed antenna has a sufficient gain in WLAN service band and is compact sized for the portable media player (PMP) applications.

THE CEPHALOMETRIC STUDY OF KOREAN MANDIBULAR ANGLE (한국인 성인 하악각에 대한 두부계측 방사선학적 연구)

  • Park, Jung-Ha;Hwang, Kyung-Gyun;Kim, Yong-Jae;Woo, Soon-Seop;Yoo, Eem-Hak;Shim, Kwang-Sup
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.29 no.4
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    • pp.226-231
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    • 2003
  • The contour of mandibular angle is important for facial esthetics in the oriental population, because the wide and square face is thought to have had an unhappy life. A prominent mandibular angle produces a characteristics quardrangle, coase, and muscular appearance. So, uni- or bi-lateral mandibular angle reduction is usually performed. However, there is little guideline for bi-lateral angle reduction. So, this study was to investigate the pattern of Korean mandibular angle for bi-lateral mandibular angle reduction as guideline. This study was included 66 adult men and women over 19 years old who are having the normal mandibular angle. We measured the posterior border, angle, and inferior border of mandible using cephalometric view. The results of study was as followed : 1. The ratio of posterior mandible was 96.6, 97.3% in male, and 103.0, 106.0% in female. 2. The ratio of mandibular angle(R1-Go/R1-R2) was 120.2% in male, and 117.3% in female. 3. The ratio of inferior mandible(D5, 6, 7, E, F, G/D4) was 97.3, 90.9, 79.5, 65.2, 57.8, 46.9% in male, and 98.5, 91.2, 80.5, 67.6, 59.1, 50.2% in female. The results of this study should be useful to decide accurate amount of reduction.

Influence of Panax ginseng formulation on skin microbiota: A randomized, split face comparative clinical study

  • Hou, Joon Hyuk;Shin, Hyunjung;Shin, Hyeji;Kil, Yechan;Yang, Da Hye;Park, Mi Kyeong;Lee, Wonhee;Seong, Jun Yeup;Lee, Seung Ho;Cho, Hye Sun;Yuk, Soon Hong;Lee, Ki Yong
    • Journal of Ginseng Research
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    • v.46 no.2
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    • pp.296-303
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    • 2022
  • Background: Skin microbiota is important for maintenance of skin homeostasis; however, its disturbance may cause an increase in pathogenic microorganisms. Therefore, we aimed to develop a red ginseng formulation that can selectively promote beneficial bacteria. Methods: The effects of red ginseng formulation on microorganism growth were analyzed by comparing the growth rates of Staphylococcus aureus, S. epidermidis, and Cutibacterium acnes. Various preservatives mixed with red ginseng formulation were evaluated to determine the ideal composition for selective growth promotion of S. epidermidis. Red ginseng formulation with selected preservative was loaded into a biocompatible polymer mixture and applied to the faces of 20 female subjects in the clinical trial to observe changes in the skin microbiome. Results: Red ginseng formulation promoted the growth of S. aureus and S. epidermidis compared to fructooligosaccharide. When 1,2-hexanediol was applied with red ginseng formulation, only S. epidermidis showed selective growth. The analysis of the release rates of ginsenoside-Rg1 and -Re revealed that the exact content of Pluronic F-127 was around 11%. The application of hydrogel resulted in a decrease in C. acnes in all subjects. In subjects with low levels of S. epidermidis, the distribution of S. epidermidis was significantly increased with the application of hydrogel formulation and total microbial species of subjects decreased by 50% during the clinical trial. Conclusion: We confirmed that red ginseng formulation with 1,2-hexanediol can help maintain skin homeostasis through improvement of skin microbiome.

Continuous Positive Airway Pressure during Bronchoalveolar Lavage in Patients with Severe Hypoxemia (심한 저산소혈증 환자에서 기관지폐포세척술 시 안면마스크를 이용한 지속성 기도양압의 유용성)

  • An, Chang Hyeok;Lim, Sung Yong;Suh, Gee Young;Park, Gye Young;Park, Jung Woong;Jeong, Seong Hwan;Lim, Si Young;Oui, Misook;Koh, Won-Jung;Chung, Man Pyo;Kim, Hojoong;Kwon, O Jung
    • Tuberculosis and Respiratory Diseases
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    • v.54 no.1
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    • pp.71-79
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    • 2003
  • Background : A bronchoalveolar lavage(BAL) is useful in diagnosing the etiology of bilateral pulmonary infiltrations, but may worsen the oxygenation and clinical status in severely hypoxemic patients. This study assessed the safety and efficacy of the continuous positive airway pressure(CPAP) using a conventional mechanical ventilator via a face mask as a tool for maintaining the oxygenation level during BAL. Methods : Seven consecutive patients with the bilateral pulmonary infiltrates and severe hypoxemia ($PaO_2/FIO_2$ ratio ${\leq}200$ on oxygen 10 L/min via mask with reservoir bag) were enrolled. The CPAP 5-6 $cmH_2O(F_IO_2\;1.0)$ was delivered through an inflatable face mask using a conventional mechanical ventilator. The CPAP began 10 min before starting the BAL and continued for 30 min after the procedure was completed. A bronchoscope was passed through a T-adapter and advanced through the mouth. BAL was performed using the conventional method. The vital signs, pulse oxymetry values, and arterial blood gases were monitored during the study. Results : (1) Median age was 56 years(male:female=4:3). (2) The baseline $PaO_2$ was $78{\pm}16mmHg$, which increased significantly to $269{\pm}116mmHg$(p=0.018) with CPAP. After the BAL, the $PaO_2$ did not decrease significantly but returned to the baseline level after the CPAP was discontinued. The $SpO_2$ showed a similar trend with the $PaO_2$ and did not decrease to below 90 % during the duration of the study. (3) The $PaCO_2$ increased and the pH decreased significantly after the BAL but returned to the baseline level within 30 min after the BAL. (5) No complications directly related to the BAL procedure were encountered. However, intubation was necessary in 3 patients(43 %) due to the progression of the underlying diseases. Conclusion : In severe hypoxemic patients, CPAP using a face mask and conventional mechanical ventilator during a BAL might allow minimal alterations in oxygenation and prevent subsequent respiratory failure.

Analysis of the Physical Properties of the Conductive Paste according to the Type of Binder Resin and Simulation of Mechanical Properties according to Ag Flake Volume Fraction (바인더 수지 종류에 따른 도전성 페이스트의 물성 분석 및 Ag flake 부피 분율에 따른 기계적 특성 시뮬레이션 연구)

  • Sim, Ji-Hyun;Yun, Hyeon-Seong;Yu, Seong-Hun;Park, Jong-Su;Jeon, Seong-Min;Bae, Jin-Seok
    • Composites Research
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    • v.35 no.2
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    • pp.69-74
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    • 2022
  • In this study, the conductive paste used in a wide range such as wiring in the electronic packaging field, the automobile industry, and electronic products is manufactured under various process conditions due to the simplicity of the process, and then the thermal, mechanical, and electrical characteristics are analyzed and simulation studies are conducted to optimize the process. to establish the conditions of the conductive paste manufacturing process. First, a conductive paste was prepared by setting various types of binder resin, an essential component of the conductive paste, and characteristics such as thermal conductivity, tensile strength, and elongation were analyzed. Among the binder resins, the conductive paste applied with a flexible epoxy material had the best physical properties, and a simulation study was conducted based on the physical property data base of the conductive face. As a result of the simulation, the best physical properties were exhibited when the Ag flake volume fraction was 60%.

The turbulent wake of a square prism with wavy faces

  • Lin, Y.F.;Bai, H.L.;Alam, Md. Mahbub
    • Wind and Structures
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    • v.23 no.2
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    • pp.127-142
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    • 2016
  • Aerodynamic effects, such as drag force and flow-induced vibration (FIV), on civil engineering structures can be minimized by optimally modifying the structure shape. This work investigates the turbulent wake of a square prism with its faces modified into a sinusoidal wave along the spanwise direction using three-dimensional large eddy simulation (LES) and particle image velocimetry (PIV) techniques at Reynolds number $Re_{Dm}$ = 16,500-22,000, based on the nominal width ($D_m$) of the prism and free-stream velocity ($U_{\infty}$). Two arrangements are considered: (i) the top and bottom faces of the prism are shaped into the sinusoidal waves (termed as WSP-A), and (ii) the front and rear faces are modified into the sinusoidal waves (WSP-B). The sinusoidal waves have a wavelength of $6D_m$ and an amplitude of $0.15D_m$. It has been found that the wavy faces lead to more three-dimensional free shear layers in the near wake than the flat faces (smooth square prism). As a result, the roll-up of shear layers is postponed. Furthermore, the near-wake vortical structures exhibit dominant periodic variations along the spanwise direction; the minimum (i.e., saddle) and maximum (i.e., node) cross-sections of the modified prisms have narrow and wide wakes, respectively. The wake recirculation bubble of the modified prism is wider and longer, compared with its smooth counterpart, thus resulting in a significant drag reduction and fluctuating lift suppression (up to 8.7% and 78.2%, respectively, for the case of WSP-A). Multiple dominant frequencies of vortex shedding, which are distinct from that of the smooth prism, are detected in the near wake of the wavy prisms. The present study may shed light on the understanding of the underlying physical mechanisms of FIV control, in terms of passive modification of the bluff-body shape.

The Analysis of MMPI and Clinical Study for Somatization Disorder and Depressive Disorder Patients (우울증성 장애 및 신체형 장애 환자에 대한 MMPI분석과 임상고찰)

  • Choe, Byeong-Man;Jung, In-Chul;Lee, Sang-Ryong;Park, Ji-Un
    • Journal of Oriental Neuropsychiatry
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    • v.13 no.2
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    • pp.41-56
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    • 2002
  • The Analysis of MMPI and Clinical Study was carried out the 28 patients with somatoform disorder and depressive disorder who were treated in Daejeon University Oriental Hospital from 19 June 2001 to 17 April 2002. The results were summarized as follows. 1. The ratio of female was higher, especially in the depressive disorder, the ratio of female was higher and in the age distribution, the 40 aged were higher frequence. 2. In the somatoform disorder, symptoms appeared to be busy in physical symptoms, and they were in descending order the digestive organs system, head and face portion and musculoskeletal system symptoms, in the depressive disorder, appeared to be busy in psychosomatic system symptoms and in the prescription drugs, soyosan(逍遙散), punsimkiyyin(分心氣飮) were used to be busy. 3. In the scales of L, F, K, somatoform disorder showed ${\wedge}$ typed graph, and depressive disorder showed ${\vee}$ typed graph. 4. In the somatoform disorder, scales of Hs, Hy, D, Pa were higher, and in the depressive disorder, scales of Hy, Hs, Pd, D were higher. 5. In the scales of Hs, D, Hy, somatoform disorder showed ${\vee}$ typed graph, and depressive disorder showed/typed graph. 6. the average of T-scores and the ratio over 65 score and 70 score showed common distribution.

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Optimum Monitoring Parameters for the Safety of Mechanical Seals (미캐니컬 씰의 안전운용 감시를 위한 최적 계측인자)

  • Soon-Jae Lim;Man-Yong Choi
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.214-219
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    • 1997
  • The mechanical seals, which are installed in rotating machines like pump and compressor, are generally used as sealing devices in the many fields of industries. The failure of mechanical seals such as leakage, crack, breakage, fast and severe wear, excessive torque, and squeaking results in big problems. To identify abnormal phenomena on mechanical seals and to propose the proper monitoring parameter for the failure of mechanical seals, sliding wear experiments were conducted. Acoustic emission, torque, and temperature were measured during experiments. Optical microstructure was observed for the wear processing after every 10 minute sliding at rotation speed of 1750 rpm and scanning electron microscopy was also observed. Except for the initial part of every experiment, the variation of acoustic emission was well coincided with torque variation during the experiments. This study concludes that acoustic emission and torque are proper monitoring parameters for the failure of mechanical seals. The intensity of acoustic emission signals is measured in root mean square voltage. Temperature of sealing face will be used as a parallel parameter for increasing the reliability of monitoring system.

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