• Title/Summary/Keyword: FUNCTIONAL GROUPS

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Facile Syntheses and Multi-orthofunctionalizations of Tertiary Benzamides

  • Paek, Kyung-Soo;Kim, Kyung-Mo;Kim, You-Seung
    • Bulletin of the Korean Chemical Society
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    • v.14 no.6
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    • pp.732-739
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    • 1993
  • Good yields were usually obtained in Pd(O)-catalyzed Suzuki aryl-aryl coupling reaction, even when both coupling partners had an ortho tertiary benzamide functional group. The direct ortho functionalization of oligomeric tertiary benzamides at Snieckus condition is dependent on the chain length. Tertiary benzamide 1 can be o,o-dilithiated only by metal-halogen exchange of the 2,6-dihalo-compound. Bis-tertiary benzamide 9 can be o,o'-dilithiated with excess(4.1 equivalents) s-butyllithium/TMEDA as the lithiating agent. Tris-tertiary benzamide 21 is hard to o,o"-difunctionalize due to steric interactions among the tertiary benzamide functional groups, and due to steric interactions between these functional groups and others (if present) on the termini of the terphenyl unit.

Investigation of Oxygen Functional Group Movement in Graphene Oxide Devices (그래핀 산화물 소자에서의 산소 작용기 이동 연구)

  • Eun Hee Kee;Mohd Musaib Haidari;Ji Hoon Jeon;Jin Sik Choi;Bae Ho Park
    • Journal of Sensor Science and Technology
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    • v.32 no.2
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    • pp.100-104
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    • 2023
  • In this study, a device was fabricated to check the possibility of a memory device by controlling the oxygen functional groups in graphene oxide formed with a 45-second exposure time. We discovered that graphene oxide can be formed using the ultraviolet (UV) light treatment method with different exposure times. Moreover, Raman spectroscopy measurement revealed that the oxygen functional groups can be moved by controlling the voltage. We further studied the change in the local graphene oxide region, which was found to be related to the modulation of the electrical properties of the device. Therefore, the fabricated graphene oxide device can be used as a wettability switching membrane and graphene-based ion transport device.

A Study on Image of Functional Food and Meal Patterns of Health Behavior (기능성 식품에 대한 인식과 건강에 관여하는 식생활에 관한 연구 -대구지역을 중심으로-)

  • 김미향
    • Journal of the East Asian Society of Dietary Life
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    • v.11 no.2
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    • pp.151-159
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    • 2001
  • This study was conducted to determine the image of functional foods and the meal patterns for health behavior of 242 persons in Daegu area. Anthropometric data showed that female and male were 38, and 204 respectively. The most BMI group was standard group(55.4% )The most eaten functional foods were Lactobicilli goods while the lowest functional foods were Taurine goods. The highest functional food image score on the basis of Likert's 5 scales was 3.89(expensive) and the lowest score was 2.98 (experienced in eating functional food). Accepted food groups were significantly associated with eating rate of protein food and age(p < 0.01),eating rate of cabohydrate foods and sex(p < 0.05), eating rate of mineral foods and monthly average income, eating rate of vitamin foods and sex.

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Thermal Desorption of Propylamine and XPS Analysis on Surface Modified Activated Carbon Fibers (표면 개질된 활성탄소 섬유의 Propylamine 탈착과 XPS 분석)

  • Kim Byeoung-Ku;Yang Burm-Ho
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.1 s.53
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    • pp.59-67
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    • 2005
  • Activated carbon fiber (ACF) was surface modified by nitric acid to improve the adsorption efficiency of the propylamine. The adsorption amount of propylamine of the modified ACF increased $17\%$ more than that of as-received ACF. Desorption of propylamine from the propylamine saturated ACF was occurred in two steps, the first step started arround $50^{\circ}C$ showing the desorption of physically adsorbed propylamine and the second step started at $200^{\circ}C$ showing the decomposition of chemically adsorbed propylamine. Total desorption amount of propylamine from the modified ACF was larger than that of the as-received ACF because of increased functional groups. The oxygen and nitrogen contents on the modified ACF increased by 1.5 and 3 times compared with the as-received ACF. A part of propylamine adsorbed on ACF formed pyridine-like or pyrrolic structures with 2 carbons exposed on the surface of the ACF. It was found that propylamine reacted with strong or weak acidic functional groups such as -COOH or -OH existed on ACF surface.

EFFECTS OF EARLY FUNCTIONAL LOADING ON BONE FORMATION AROUND TITANIUM PLASMA SPRAYED IMZ IMPLANTS IN DOGS (성견에서 Titanium Plasma Sprayed IMZ 임플란트에 가해진 조기 기능하중의 골유착 및 골형성에 미치는 영향)

  • Jeon, Young-Sik;Han, Dong-Hoo
    • The Journal of Korean Academy of Prosthodontics
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    • v.33 no.3
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    • pp.550-568
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    • 1995
  • The purpose of this study was to observe the effects of early functional on bone formation around titanium plsama sprayed IMZ implants. 15 IMZ implants were inserted on the mandibular premolar areaa in 5 mondgrel dogs. The inplants were divided into 4 groups according to it’s loading schedule : Temporary abutments were connected for functional loading 6weeks, 9weeks, and 12weeks after implants installation in group I, II, and III, respectively. Abutments were not connected in the control group. After polyfluorochrome sequential labeling, all animals were sacrificed and bone sections includig implants and the 1st. molar were removed and processed for histologic evaluation. From light and fluorescence microscopic evaluation as well as histomorphometric and EPMA analysis, following results were obtained : 1. Light microscopically, the osteoid tissues were observed much in the compact bone of unloaded group, and cancellous bone formation observed more in early loaded group. 2. Calcification and remodeling of bone took place faster in loaded group, especially in 6 weeks group. 3. Moderate to severe marginal bone resorption was observed in 6 weeks group, mainly on buccal crest. 4. There was no difference in the percentages of bone-to-metal contact among the experimental groups. 5. In quantitative analysis using EPMA, there was no difference in the content of calcium and phosphorus among the experimental groups, regardless of distance.

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Fabrication of Pre-Exfoliated Clay Masterbatch via Exfoliation-Adsorption of Polystyrene Nanobeads

  • Khvan, Svetlana;Kim, Jun-Kyung;Lee, Sang-Soo
    • Macromolecular Research
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    • v.15 no.1
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    • pp.51-58
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    • 2007
  • The approach studied in the present work produced an exfoliated state of clay layers via confinement of the charged nano-sized polystyrene (PS) beads within the gallery of swollen pristine clay. It was demonstrated that adsorption of the polymer nanobeads dramatically promotes expansion of the clay gallery. A comparative study of incorporation was conducted by employing organo-modified clay along with two different colloid polymer systems: electrostatically stabilized PS nanobeads and cationic monomer-grafted PS nanobeads. The mechanism of adsorption of the monomer-grafted polymer beads onto clay via cationic exchange between the alkyl ammonium group of the polymer nanobeads and the interlayer sodium cation of the layered silicate was verified by using several techniques. As distinct from the polymer nanobeads formed using conventional miniemulsion polymerization method, competitive adsorption of stabilizing surfactant molecules was be prevented by grafting the surface functional groups into the polymer chain, thereby supporting the observed effective adsorption of the polymer beads. The presence of surface functional groups that support the establishment of strong polymer-clay interactions was suggested to improve the compatibility of the clay with the polymer matrix and eventually play a crucial role in the performance of the final nanocomposites.

NO gas sensing ability of activated carbon fibers modified by an electron beam for improvement in the surface functional group

  • Park, Mi-Seon;Lee, Sangmin;Jung, Min-Jung;Kim, Hyeong Gi;Lee, Young-Seak
    • Carbon letters
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    • v.20
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    • pp.19-25
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    • 2016
  • Activated carbon fiber (ACF) surfaces are modified using an electron beam under different aqueous solutions to improve the NO gas sensitivity of a gas sensor based on ACFs. The oxygen functional group on the ACF surface is changed, resulting in an increase of the number of non-carbonyl (-C-O-C-) groups from 32.5% for pristine ACFs to 39.53% and 41.75% for ACFs treated with hydrogen peroxide and potassium hydroxide solutions, respectively. We discover that the NO gas sensitivity of the gas sensor fabricated using the modified ACFs as an electrode material is increased, although the specific surface area of the ACFs is decreased because of the recovery of their crystal structure. This is attributed to the static electric interaction between NO gas and the non-carbonyl groups introduced onto the ACF surfaces.

Effects of remedial massage therapy on the pain, grip strength and functional status scale in carpal tunnel syndrome (정형의학적 마사지가 수근관 증후군 환자의 통증, 악력, 기능적 평가의 등급에 미치는 영향)

  • Ma, Sang-Yeol;Gong, Won-Tae;Kang, Young-Suk
    • Journal of the Korean Data and Information Science Society
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    • v.20 no.1
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    • pp.97-107
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    • 2009
  • This study is to examine effects of orthopedic remedial massage therapy on the pain, grip strength and functional status scale in carpal tunnel syndrome. We selected 30 cases of carpal tunnel sydrome, which were evenly divided into two groups: experimental group and control group. We applied the same infrared and ultrasound therapy to both groups. The experimental group had additional treatment of orthopedic remedial massage therapy. For each subject, the pain, grip strength and functional status scale were measured before and after treatment, While both groups showed significant improvements after treatment, more significant effects were found in the experimental group.

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The Effects of Task-Oriented Functional Training on Standing Balance in Stroke Patients (과제 지향적 기능 훈련이 뇌졸중 환자의 균형에 미치는 영향)

  • Kim Jae-wook;Kim Soo-min;Park Rae-joon
    • The Journal of Korean Physical Therapy
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    • v.15 no.4
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    • pp.65-81
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    • 2003
  • The purpose of this study was to investigate the balance of stroke patient appling Task-Oriented Functional training program. Sixteen subjects were recruited from KeiMyung university Dongsan Medical Center inpatient satisfying requirement for this study. They were divided into Task-Oriented Functional training group and Conventional therapy group. They were measured by Sensory organization test and Motor control test items using EquiTest Version 8.0 machine before and after the test. The result of this study were to follow: 1. In Sensory organization test, there were no significant differences in static eguibrium score in both groups(p<.05). 2. In Sensory organization test, there were significant differences in dynamic eguibrium score in both groups(p<.05). 3. In Motor control test, there were significant differences in both groups(p<.05). 4. In exercise group, there were no significant differences in static Sensory organization test(p<.05). 5. In exercise group, there were significant differences in dynamic Sensory organization test(p<.05). 6. In exercise group, there were significant differences in Motor control test(p<.05). 7. In control group, there were no significant differences in static Sensory organization test(p<.05). 8. In control group, there were no significant differences in dynamic Sensory organization test(p<.05). 9. In control group, there were no significant differences in Motor control test(p<.05).

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The Influence of Microcurrent on Pain and Function of Patients with Chronic Back Pain (만성 요통 환자에게 미세전류의 적용이 통증 및 기능에 미치는 영향)

  • Park, Jang-Sung;Jung, Hwa-Su
    • Journal of the Korean Academy of Clinical Electrophysiology
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    • v.8 no.1
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    • pp.1-5
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    • 2010
  • Purpose : This research inquires into the effect of applying microcurrent (MC) according to various frequency levels on the pain and functional recovery of patients with chronic back pain. Methods : Thirty participants with chronic lower back pain disease were divided equally into three experimenta l groups. The MC frequency used in the first experimental group was 0.5Hz, the second experimental group was 50Hz, and the third experimental group was 100Hz for 20 minute sessions. A hot pack and ultrasound were applied to all groups as the general physical therapy. Measurements were taken using the visual analogue scale (VAS), the face pain rating scale (FPRS), and the Oswestry disability index (001). The analysis used the paired t-test in order to compare pretest and posttest results. A one-way ANOVA was performed to make comparisons with regards to frequency levels. Results : VAS, FPRS, and 001 showed significant pain decrease in all groups except for the 001 measurement in the 0.5 Hz group. There were no significant differences according to frequency levels. Conclusion: For chronic pain and functional recovery, a microcurrent produces an effect after treatment. However, results did not show a significant difference in change obtained from differing frequency levels.