• Title/Summary/Keyword: FTIR

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FTIR Spectroscopic Analysis of Structural Changes of Cellulosic Fibres During Papermaking Process

  • Kim, Hyoung-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.2
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    • pp.51-58
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    • 1998
  • Structural changes of cellulosic fibres during the papermaking process were studied by analysis of FTIR spectra collected by the transmission method. The spectra were obtained from a carefully prepared handsheet, using a special infra-red (IR) cell suitable for evacuating the sample. The deconvolution technique was also applied for sharpening the FTIR spectra in the frequency range of the OH and CH stretching bands, which gave detailed information on the structural changes of cellulose. The intensity of some bands was decreased by predrying the sample as a result of the removal of adsorbed moisture. An increase in intensity of some bands in the frequency range of 3700 to $3200cm^{-1}$ was shown at a higher beating level. This increase in intensity was caused by changes in the crystal domain of cellulose resulting from the exposure of the crystalline area on the fibre surface.

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TM polarized photon tunneling in a frustrated total internal reflection structure (Frustrated Total Internal Reflection 구조에서의 TM 편광된 광자의 터널링)

  • Lee, Byoung-Ho;Lee, Wook
    • Korean Journal of Optics and Photonics
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    • v.7 no.2
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    • pp.112-119
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    • 1996
  • TM polarized photon tunneling time and the position where TM photons appear after two-dimensional tunneling in a frustrated total internal reflection (FTIR) structure are calculated. This is done by converting the FTIR tunneling problem of TM photons to an electron tunneling problem with a position-dependent effective mass for a heterostructure potential barrier. Derived results are compared with TE photon cases.

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Vibrational Spectroscopic Studies of Crystallization in Mixed n-Paraffins (진동분광실험을 이용한 n-Paraffin혼합물의 결정화에 관한 연구)

  • 김도균;임현주;최선남;김성수;송기국
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.752-758
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    • 2002
  • FTIR, FT-Raman, and X-ray diffraction techniques were used to determine chain segregations and lamellar structures of the mixed binary n-paraffins with different chain lengths. The results of three different techniques, infrared spectroscopic studies of crystal field splitting, the Raman longitudinal acoustic mode, and the SAXS long period measurements were compared one another to understand the crystallization mechanism of separated or mixed n- paraffin lamellae.

Analysis of Catalytic Reaction Characteristics of NGV Exhaust Gas by FTIR Spectroscopy (FTIR법에 의한 천연가스자동차 배기의 촉매반응특성 분석)

  • Choi, B.C.;Kim, Y.K.;Lim, M.T.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.6
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    • pp.218-225
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    • 1998
  • FTIR spectroscopy, useful technology for simultaneous and continuous measurement of the various components of the automotive exhaust gas, is utilized to investigate catalytic reaction charactristics of methane and a few unregulated exhaust emissions of NGV. Major findings are (1) catalytic reaction characteristics of methane measured in unsteady states of varying temperature are similar to those measured in steady states, (2) about 24 % of NO was oxidized to $NO_2$ as soon as they encounter catalysts, (3) study of formaldehyde suffers from difficulties in measurement due to the proximity in wavenumber of formaldehyde and methane, and requires an analyzer of higher resolution and accuracy than used in this study.

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