• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.232-232
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• 2023

고속도로 및 편의시설 건설로 불투수층의 면적이 증가하여 강우 시 고속도로 및 편의시설에서 발생하는 오염원에 의한 하천의 수질 영향도 커지고 있다. 특히 휴게소에서는 자동차의 급가속, 급감속으로 더욱 많은 분진과 오염물질이 발생할 수 있으며 타이어 마모 입자, 자동차 배기가스, 중금속 및 오일류 등이 휴게소나 도로 지표에 집적되어 있다. 이렇게 발생한 오염물질은 우기에 강우와 함께 불투수면을 침투하지 못하고 배수로를 통해 유출되어 인근 하천의 수생태 및 토양의 주요 오염원으로 작용하고 있다. 이에 따라 고속도로 및 인근 휴게소의 비점오염 저감대책이 필요하며 효율적인 비점오염원 저감을 위해 장기적인 모니터링, 지속적인 자료 수집 및 분석이 필요하다. 본 연구에서는 강원지역 고속도로 및 인근 휴게소에서 강우 시 강우유출수 모니터링을 통해 강우유출수 유량가중평균농도 (Event Mean Concentration) 산정하고 강우유출수 수문곡선 (hydrograph)을 작성하였다. 또한 강우사상에 따른 분석항목별 초기세척효과(First Flush Effects)와 오염부하량을 산정하였다. 추가적으로 차량 기인 입자를 확인하기 위해 μ-FT-IR 현미경 분석 실험을 하였다. 모니터링 장소는 휴게소 및 고속도로 일원이며, 모니터링은 선행무강우일수 2일 이상, 강우량 10mm 이상일 때 실시하였으며 2022년 6월부터 10월까지 총 4회 실시하였다. 모니터링 결과 타이어 및 브레이크 패드 마모와 관련된 중금속인 Zn, Cu, Pb 등의 중금속이 높게 분석되었으며 이러한 중금속의 오염부하량 역시 높게 산정되었다. 강우유출수 수문곡선에서 강우 초기 오염물질의 세척효과가 나타났다. MFFn 산정 결과 강우 30% 구간에서 초기세척효과를 보였다. μ-FT-IR 현미경 분석 결과 PE (Polyethylene)가 가장 많이 검출되었고 PP (Polypropylene), PS (Polystyrene) 순으로 검출되었다. 이러한 강우유출수 모니터링 데이터는 향후 고속도로 휴게소 및 고속도로 주변 오염저감 시설 설치 및 사회적 동참을 위한 타당한 근거 확보를 위한 기초자료로서 제공될 수 있을 것이다.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.04a
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• pp.262-266
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• 2011

본 연구에서는 건축물 내장 재료에 대한 연소독성평가와 독성지수연구로써 FT-IR을 이용한 연소가스분석실험을 하였다. 독성지수를 산정하기 위한 실험의 화재모델로 콘 칼로리미터 화재모델(KS F ISO/TR 9122-4)을 사용하였으며 ISO 19702의 절차에 따라 FT-IR을 이용하여 건축 재료의 연소로부터 발생되는 가스의 분석을 수행하였다. 국제규격에서 제시하고 있는 몇 가지 독성지수 산정법 중 ISO 13344에서 규정하는 방법에 따라 FED 값을 산정하였으며, 30분간 시험동물에 노출 시 대상의 50%가 사망하는 농도인 $LC_{50}$을 기준으로 하여 3가지 재료의 독성지수화를 통해 상대적인 독성 위험도를 평가하였다.

• Analytical Science and Technology
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• v.19 no.2
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• pp.121-130
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• 2006

In this study, silver pre-treated activated carbons are transformed using sulfuric acid. From the results of adsorption, each isotherm shows a distinct knee band, which is characteristic of microporous adsorbents with capillary condensation in micropores. In order to reveal the causes of the differences in adsorption capacity and specific surface area after the samples were washed with various strengths of sulfuric acid, surface morphology and external pore structure were investigated by SEM. X-ray diffraction patterns indicated that Ag-activated carbons show better performance for silver and silver compounds removal by post-treatment with acid. The FT-IR spectra of silver-activated carbon samples show that the acid post-treatment was consequently associated with the removal of silver with an increased surface functional group containing oxygen of the activated carbon. The type and quality of oxygen groups are determined on the method proposed by Boehm. For the chemical composition microanalysis of silver-activated carbons transformed by post-treatment with sulfuric acid, samples were analyzed by EDX.

• Analytical Science and Technology
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• v.20 no.2
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• pp.124-130
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• 2007

In this study, we present the preparation and characterization of oxidized fullerene and fullerene dimer [$C_{120}$]. From the XRD data, other weak peaks with pristine fullerene [$C_{60}$] peaks were observed in the X-ray diffraction patterns for fullerene dimer [$C_{120}$]. SEM micrographs for the fullerene dimer [$C_{120}$] indicated that practically all the surface state was shown the drastic morphology changes and its outer surface is clearly visible and resulted in clogging and frost-like formation. From the MALDI-TOF mass spectra, the differences in the spectra recorded on two kinds of fullerene are due to the oxidation including chemical bonding and bridging between the $C_{60}$ molecules. We also obtained additional information from FT-IR spectra on functional component on the chemically modified surface of oxidized fullerene and fullerene dimer [$C_{120}$].

• Conservation Science in Museum
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• v.13
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• pp.37-44
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• 2012

White crystals on 46 costumes excavated from Shim Su-Ryun(1534 - 1589)'s tomb were examined their characterization and distribution. In 36 of such samples, white crystals with different shape and hardness were found. The formation of crystals did not correlated with a kind and use of textiles. However, crystals were found in the back side than the front of costume, specially around the marks of shrouding dead body. White crystals from 7 textiles were investigated by EPMA, XRD, or FT-IR. The composition of white crystal was analysed by EPMA and the structure characterization of crystals was used by X-ray diffraction. FT-IR spectroscopy was applied to check if non-crystalline compounds were also present. Mg and P were detected as the main element of white crystals and these compounds were identified a struvite and newberyite, the inorganic mineral magnesium ammonium phosphates. Struvite precipitation are influenced by many factors including concentration of Mg²⁺, NH₄⁺, and PO₄^3- ions, pH, and temperatures. It is assumed that magnesium, phosphorous, ammonia, a base material of struvite comes from decomposition product of human body. Tomb covered with lime, a unique triple-structure in Joseon period offering the basic condition, an anaerobe in a coffin, and high magnesium concentration of outer coffin with lime can be inferred as important factor for precipitation of crystals.

• Journal of Conservation Science
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• v.31 no.4
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• pp.499-506
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• 2015

The artifacts of Admiral Yi Sun-sin (Treasure No.326) consist of six items with two long swords, a jade decoration, a belt and two peach-shaped cups. In commemoration of the opening of Chungmugong Yi sun-sin Memorial Museum (April 28, 2011), there were conservation treatments for those artifacts at the beginning of 2011. At that time, from the result of non-destructive surface analysis on pigments in blood-colored grooves of the two long swords, it was presumed to be synthetic resin paints. This study shows the accurate identification on pigments which was presumed as synthetic resin paints and its removal. To identify pigments in blood-colored grooves, the optical microscope, scanning electron microscope, Micro-XRF, XRD and FT-IR were used for the analysis. The results turned out that the thickness of $10{\sim}90{\mu}m$ in a single layer was measured. And major components containing Pb and Cr and lead chromium molybdenum oxide were identified and to identify components of adhesives from the analysis by FT-IR, it turned out to be alkyd resin, which can be presumed that they were recently colored with synthetic paints. The synthetic paints easily react with most of the organic solvents. And it is so easy to handle without the effect on metal that it was removed with acetone. While removing synthetic paints, all of paints on it were collected for identifying whether there is traditional pigment but nothing was identified.

• Journal of Adhesion and Interface
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• v.2 no.2
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• pp.1-10
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• 2001

Silica for Epoxy Molding Compound (EMC) was coated via plasma-polymerization with RF plasma (13.56 MHz) as a function of treatment time, power and pressure. 1,3-diaminopropane, allylamine, pyrrole, 1,2-epoxy-5-hexene, allylmercaptan or allylalcohol were utilized for plasma polymerization coating and adhesion of coated silica was evaluated by measuring flexural strength. CTE and water absorption of EMC were also measured, and fracture surface of flexural specimen was analyzed by SEM in order to elucidate the failure mode. The plasma polymer coated silica was analyzed by FT-IR and reactivity of plasma polymer coating with epoxy resin was evaluated with DSC in order to investigate the adhesion mechanism. The EMC prepared from the silica coated with 1,3-diaminopropane or allylamine exhibited high flexural strength, low CTE, and low water absorption compared with the control sample, and also exhibited 100% cohesive failure mode. These results can be attributed to the chemical reaction between the functional groups in the plasma polymer coating and epoxy resin, and also consistent with the results from FT-IR and DSC analysis.

• Fire Science and Engineering
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• v.25 no.4
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• pp.35-41
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• 2011

Casualties due to toxic smoke products have been reported as major fire damage. There are various tests in order to evaluate toxic smoke from a fire at home and abroad, and KS F 2271 as a test of the gas hazard of building finish materials has been conducted in Korea. The current test of the gas hazard exposes rodent, laboratory rat, to smoke gases to evaluate combustion gas toxicity by measuring acting time of that. this study performed a test of the gas hazard for combustible polymer material, Urethane and rubber flooring, and determined gases with the FT-IR. Quantitative results compared with standard value defined in BS6853 and toxicity index (R) was calculated. Using relative comparison with animal test and the toxicity index, We tried a variety of toxicity evaluation by correlation analysis of two tests.

• Journal of the Korean Wood Science and Technology
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• v.35 no.6
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• pp.152-158
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• 2007

Micromorphological and chemical characteristics of living Castanea spp. and Tamarix spp. attacked by a brown-rot fungus were examined. Micromorphological features of brown-rotted hardwood species were similar to those observed in softwoods such as losses in birefringence under polarized microscopy, preferential degradation of $S_2$ layer and cracks in the $S_3$ layer. Thinning of the secondary cell wall in fibers was also observed, although it did not seem to be the main symptom. FT-IR analysis showed that bands assigned to cellulose and hemicelluloses decreased or disappeared, whereas the bands assigned to lignin increased. X-ray diffraction analysis exhibited the decrease of relative crystallinity, indicating that degradation of hardwood by a brown-rot fungus was in the advanced stages.

• Analytical Science and Technology
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• v.17 no.2
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• pp.173-179
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• 2004

The $BaTiO_3$ powders and thin films were prepared by an alkoxide modified sol-gel process (polymerization-complex route) using ethylene glycol. The stable starting (Ba-Ti)-mixed metal organic sol was made by addition of acetylacetone. The $BaTiO_3$ powders, which had a particle size of 40~77 nm, were crystallized from an amorphous to a tetragonal phase on annealing at 700 and $1100^{\circ}C$ for 1 h. From FT-IR, solid-state $^{13}C$ CP/MAS NMR spectroscopy and X-ray diffractometry, the trace of the Ba-Ti-oxycarbonate phase first appeared at $400^{\circ}C$. Hydrolyzed sol was spin coated on a quartz wafer at 3500 rpm for 60 s and pyrolyzed at $1100^{\circ}C$ for 1 h. After heat treatment, the coated layer became dense and smooth.