• Journal of the Korean Society for Marine Environment & Energy
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• v.10 no.3
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• pp.181-186
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• 2007

Despite of environmental problems(safety hazards), mechanical recycling of FRP boats, which involves shredding and grinding of the scrap FRP in a new product. is one of the simpler and more technically proven methods than incineration or reclamation ones. Because FRP is made up of reinforced fiber glass, it is very difficult to break into pieces. It also occurs secondary problem such as air pollution and unacceptable shredding noise level. The another urgent problem which is a serious barrier to FRP recycling is very limited reusable applications. This study is to propose a new method which is efficient and environment friendly waste FRP regenerating system. And it also have shown the polymer cement and fiber-reinforced concrete applications with the waste FRP.

• Journal of the Korean Society for Marine Environment & Energy
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• v.10 no.3
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• pp.167-172
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• 2007

Since 1990s, these many researchers have been fully involved in developing recycling methods for FRP boats. There are four basic classes of recycling covered in the literature. the first is "Mechanical recycling" which involves shredding and grinding of the scrap FRP in a new product. Despite of the safety hazards, mechanical recycling is one of the simpler and more technically proven methods. Recent researchers should be more interested in these methods. It is fact that most of FRP wastes are depended on incineration or reclamation. Because it Is made up of reinforced fiber glass, it is very difficult to break into pieces. By the disposing of waste FRP this way, it also occurs secondary problem such as air pollution and unacceptable noise. This study is to propose a new method which is efficient and environment friendly waste FRP regenerating.

• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.3
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• pp.207-215
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• 2015

In the last decade, increasing national research fund for recycling the waste FRP (fiber reinforced plastics) ships which has caused environmental problems, improves the technology making concrete-reinforcing fibers out of the waste FRP. Furthermore, the concrete with recycled FRP fiber was tested for the structural performance. Experimental strength tests show that use of recycled FRP powder does not reduce the compressive strength of high strength concrete, and does increase the fire resistance performance of high strength concrete significantly. But, the study in investigating the properties of recycled fiber powder from waste FRP has not been completed because of the absence of the method of separation of mat layer from the waste FRP. This study is to propose a new extracting method of the mat layer from waste FRP, which is the efficient and environment friendly system. and thus it is considered to be the useful recycling method for fire resistance high concrete products or structures.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.1
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• pp.29-34
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• 2009

For several decades, many researchers have been involved in developing recycling methods for FRP boats. There are four basic classes of recycling covered in the literature. Despite of environmental problems(safety hazards), mechanical recycling of FRP boats, which involves shredding and grinding of the scrap FRP, is one of the simpler and more technically proven methods than incineration, reclamation or chemical ones. Because FRP is made up of reinforced fiber glass, it is very difficult to break into pieces. It also leads to secondary problem in recycling process, such as air pollution and unacceptable shredding noise level. Another serious problem of mechanical FRP recycling is very limited reusable applications for the residue. This study is to propose a new and efficient method which is more wide range applications and environment friendly waste FRP regenerating system. New system is added with the cyclone sorting machine for airborne pollutions and modified cutting system for several glass fiber chips sizes. It also has shown the FRP chip fiber-reinforced concrete and fiber-reinforced secondary concrete applications with the waste FRP boat to be more eligible than existing recycling method.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.1
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• pp.46-51
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• 2014

Increasing of waste FRP (fiber reinforced plastics) has caused environmental problems. Recently, the technology of making fibers from waste FRP, which can be used to reinforce the concrete, was developed and the reinforced concretes were tested to study the structural performance. The purpose of this study is to investigate the effect of the powder, obtained together with F-fiber from the waste FRP, on the compressive strength and the fire resistance performance as in the high strength concrete. Strength tests show that the use of recycled FRP powder does not reduce the compressive strength of high strength concrete if the volume fraction of FRP powder is less than 0.7%. Electric furnace test results also show that the use of recycled FRP powder may increase the fire resistance performance of high strength concrete significantly.

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.1
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• pp.50-54
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• 2008

There are several basic classes of recycling methods for FRP boats. The main one is 'Mechanical recycling' which involves shredding and grinding of the scrap FRP in a new product. That is one of the simpler and more technically proven methods. It recently has been reported that FRP can be recycled by separating into layers instead of crushing into powder. Many researchers should be more interested in these mechanical recycling for the eligibility. Nevertheless, because resins is very useful renewable energy, most of waste FRP regenerating methods depend on incineration (reclamation) or thermal recycling (pyrolysis). FRP is made up of laminated glass- fiber (roving cloth layer) which is also very unlikely to break into each layer. If there is an extracting method which is efficient and environment friendly removing glass fiber from waste FRP, it should also solve the another urgent problem. Laminated glass-fiber which is very limited renewable, is a serious barrier to wast FRP boat regenerating. This study is to propose a new extracting method which is efficient and environment friendly waste FRP regenerating system. And it should be applied to renewable energy applications with the waste resins of FRP. Also recycling glass fiber obtained by the separation of the roving layer from waste FRP will be consider to be useful for concrete products or structures.

• Journal of the Korean Society for Marine Environment & Energy
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• v.16 no.1
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• pp.53-59
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• 2013

Since 1990s, the major recycling methods for mechanical recycling of FRP(Fiber Reinforced Plastics)boats has involved shredding and grinding of the scrap FRP in a new recycled product. But still it leads to secondary problem such as air pollution, unacceptable shredding noise level and few limited applications. This study is to propose a newly advanced method which is more efficient and environment friendly waste FRP regenerating system. As extracting FRP layer and making the recycled fiber for recycled-fiber reinforced concrete(RFRC) from waste FRP, the recycling process has some merits in a sense of the recycling energy and the environmental effects. In this study, for those tasks, spectro-chemical differentiation method and coloring water-soluble dye treatment makes the roving layer more distinguishable photophysically. Also that has remarkably reduced safety hazards and energy. Using the mechanical properties of polymers and composite, FRP with the orthotropic and laminated plastic structure has been easily separated in the new extracting system. Also the new method has introduced five kind of separating manuals for the some different compositions of FRP boats. The roving fiber of laminated glass-fiber layer is as good as the polyvinyl fiber which is cost-high commercial fiber to increasing strength of concrete products. The early study has shown the effectiveness of laminated glass-fiber layer which also is chemical-resistant due to the resin coating. These results imply that more efficient and environment friendly recycled glass fiber can be better applied to the fiber reinforced concrete(FRC) substitute and this study also has shown wide concrete applications with RFRC from the waste FRP boat.

• Applied Chemistry for Engineering
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• v.21 no.2
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• pp.217-223
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• 2010

In general, fiber-reinforced plastics (FRP) wastes are simply buried or burned. Landfill brings about a permanent contamination of soil due to the inability of FRP to decompose and incineration causes an issue of generating toxic gases and dusts. There have been several ways to treat the FRP wastes such as landfill, incineration, chemical recycling, material recycling and the utilization of energy from combustion. Most methods excluding material recycling are known to have critical limitations in economic, technical and environmental manners. However it is known that material recycling is most desirable among the methods handling FRP wastes. In this study, to investigate the purpose of feasibility of material recycling, various bulk molding compound (BMC) specimens were prepared with the various contents of unsaturated polyester resin binder (25, 30, 35 wt%) and the various replacement ratios of FRP wastes powder (0, 25, 50, 75, 100 wt%) substituted for filler. To evaluate the physical properties BMC specimens, various tests such as tensile strength, flexural strength, impact strength, hot water resistance and SEM imaging were conducted. As a results, mechanical strengths decreased with an increase of replacement ratio of FRP waste powder and physical properties of BMC specimens were deteriorated in the hot water resistance. The fluidity of BMC with more than 50 wt% of the replacement ratio of FRP wastes powder decreased remarkably, causing a problem in the BMC composite.

• Journal of the Korean Society for Marine Environment & Energy
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• v.13 no.1
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• pp.43-46
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• 2010

As one of the methods for recycling the FRP used for the small and medium-sized waste ships, separation of the roving layer from the mat has some merit in a sense of the recycling energy and the environmental effects. Similar characteristics between the roving and the mat make the mechanically automatic differentiation difficult. They, however, contain different ratio of the resin and the glass and the thickness. In this study photo physical differentiation between the two layers has been made using (1) boiling concentrated sulfuric acid which can dissolve the resin in the FRP layer and (2) hydrogen fluoride(HF) solution which can reacts with $SiO_2$ fragments of the glass. Furthermore coloring the FRP sample with water-soluble dye following the HF treatment makes the roving layer more distinguishable photophysically. The implementation of HF treatment has been successfully tested in this study.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.1
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• pp.55-59
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• 2009

As one of the methods for recycling the FRP from the small and medium waste ships, separation of roving layer from the mat has some merits in a sense of the recycling energy and the environmental effects. Similar characteristics, however, between the roving and the mat even with different ratio of the resin and the glass and the thickness of the roving, much thinner than the mat, make the mechanically automatic differentiation difficult. In this study spectrochemical differentiation between the two layers has been made using (1) boiling concentrated sulfuric acid which can dissolve the resin in the FRP layer, (2) methanol and isopropanol solution saturated with KOH which can dissolve the glass, or (3) hydrogen fluoride(HF) solution which can reacts with $SiO_2$ fragments of the glass. Furthermore coloring water-soluble dye following the HF treatment makes the roving layer more distinguishable photo-physically.