• Title/Summary/Keyword: FFF

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Study of Equivalent Retention among Different Polymer-Solvent Systems is Thermal Field-Flow Fractionation

  • 김원숙;박영훈;문명희;유유경;이대운
    • Bulletin of the Korean Chemical Society
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    • v.19 no.8
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    • pp.868-874
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    • 1998
  • An equivalent retention has been experimentally observed in thermal field-flow fractionation (ThFFF) for different polymer-solvent systems. It is shown that iso-retention between two sets of polymer-solvent systems can be obtained by adjusting the temperature difference (ΔT) according to the difference in the ratio of ordinary diffusion coefficient to thermal diffusion coefficient. This method uses a compensation of field strength (ΔT) in ThFFF at a fixed condition of cold wall temperature. It is applied for the calculation of molecular weight of polymers based on a calibration run of different standards obtained at an adjusted AT. The polymer standards used in this study are polystyrene (PS), polymethylmethacrylate (PMMA), and polytetrahydrofuran (PTHF). Three carrier solvents, tetrahydrofuran (THF), methylethylketone (MEK) and ethylacetate (ETAc) were employed. Though the accuracy in the calculation of molecular weight is dependent on the difference in the slope of log λ vs. log M which is related to Mark-Houwink constant a, it shows reasonable agreement within about 6% of relative error in molecular weight calculation for the polymer-solvent systems having similar a value.

Development of wet-sampler for collection and fractionation of micron-sized particles (마이크로 입자의 습식 수집 및 분획 장치 개발)

  • Eum, Chul-Hun;Kang, Dong-Young;Lee, Seung-Ho
    • Analytical Science and Technology
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    • v.24 no.6
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    • pp.429-434
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    • 2011
  • In this study, a wet-sampler was developed for collection in water and simultaneous fractionation of micron-sized particles (e.g., pigment, airborne, etc.). In this new device, three cylinders (partially filled with water) through which air was forced to pass for sample collection are connected in a series. Particles of different sizes are collected in different cylinders, allowing simultaneous fractionation. An uniqueness of this new device is that it does not use any membrane filter. Microparticles are collected directly in cylinders filled partially with water. Also the particles are simultaneously fractionated within this device while they are being collected. The new device was employed for collection of airborne particles. The collected airborne particles were fractionated by using sedimentation field-flow fractionation, SdFFF), and observed with an optical microscopy (OM) for size and shape analysis. Also AAS and ICP-AES were used for composition analysis of the airborne particles. It is expected that the new device is applicable to collection and analysis of size distribution of various types of microparticles.

A Study of Construction and Efficacy of Thermal Field-Flow Fractionation (열 장 흐름 분획장치의 제작과 효율성에 관한 연구)

  • Dai-Woon Lee;Wook-Hwan Heo;Jeon Sun-Joo;In-Ho Lee
    • Journal of the Korean Chemical Society
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    • v.36 no.3
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    • pp.419-427
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    • 1992
  • The performance of homemade thermal field-flow fractionation (ThFFF) and the optimization for separation are investigated in terms of retention parameters and selectivity using polystyrene standards. The ribbonlike channel was constructed by sandwiching two Mylar spacers between two highly polished copper bars which serve as channel walls. The hot bar was heated by two electrical cartridge heaters and the cold bar had holes through the entire length, allowing tap water as coolant to enter. It has been observed that the retention of polystyrenes increases as the temperature gradient increases. And the retention decreases as the cold wall temperature increases from 20 to $45^{\circ}C$. In comparison with size exclusion chromatography, ThFFF is more selective but has relatively low efficiency. It has been found that the plate height is proportional to the flow velocity and good estimates of polydispersities can be made directly from the ThFFF data.

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A Case Study on the Sustainability for a Stanchion of Recreational Crafts based on the Design for Additive Manufacturing Using a FFF-type 3D Printer (FFF 3D 프린터를 이용한 DfAM 기반 소형선박용 스탠션 지속가능 개발 사례 연구)

  • Lee, Dong-Kun;Park, Bon-Yeong
    • Journal of the Society of Naval Architects of Korea
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    • v.58 no.5
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    • pp.294-302
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    • 2021
  • In this study, the 3D printing technique called design for additive manufacturing (DfAM) that is widely used in various industries was applied to marine leisure ships of equipment. The DfAM for the stanchion for crew safety was applied to the equipment used in an actual recreational craft. As design constraints, the design alternatives were not to exceed the safety and weight of the existing stainless steel material, which were reviewed, and the production of a low-cost FFF-type 3D printing method that can be used even in small shipyards was considered. Until now, additive manufacturing has been used for manufacturing only prototypes owing to its limitations of high manufacturing cost and low strength; however, in this study, it was applied to the mass production process to replace existing products. Thus, a design was developed with low manufacturing cost, adequate performance maintenance, and increased design freedom, and the optimal design was derived via structural analysis comparisons for each design alternative. In addition, a life-cycle assessment based on the ISO 1404X was conducted to develop sustainable products. Through this study, the effectiveness of additive manufacturing was examined for future applications in the shipbuilding industry.

A Study on Superficial Dose of 6MV-FFF in HalcyonTM LINAC: Phantom Study (HalcyonTM 선형가속기 6MV-FFF 에너지의 표재 선량에 대한 고찰: Phantom Study)

  • Choi, Seong Hoon;Um, Ki Cheon;Yoo, Soon Mi;Park, Je Wan;Song, Heung Kwon;Yoon, In Ha
    • The Journal of Korean Society for Radiation Therapy
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    • v.32
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    • pp.31-39
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    • 2020
  • Purpose: The aims of this study were to compare the superficial dose with Optically Stimulated Luminescence Dosimeter(OSLD) measurement and Treatment Planning System(TPS) calculation for 6MV-Flattening Filter Free(FFF) energy using HalcyonTM and TrueBeamTM. Materials and methods: Phantom study was performed using the CT images of human phantom. In the treatment planning system, the Planning Target Volume(PTV) was contoured which is similar to Glottic cancer. Furthermore, Point(M), Point(R), and Point(L) were contoured at the iso-center of head and neck region and 5mm bolus was applied to the body contour. Each treatment plans using 6MV-FFF energy from HalcyonTM and TrueBeamTM with static Intensity Modulated Radiation Therapy(IMRT) and Volumetric Modulated Arc Therapy(VMAT) were established with eclipse. To reproduce the same position as the TPS, OSLDs were placed at the iso-center point and 5mm bolus was applied to compare the error rate after the dose delivery. Result: The results of the study using human phantom are as follows. In case of HalcyonTM, the mean absolute error rates of the point dose using the treatment planning system and the dose measured by OSLD were 1.7%±1.2% for VMAT and 4.0±2.8% for IMRT. Also TrueBeamTM was identified as 2.4±0.4% and 8.6±1.8% respectively for VMAT and IMRT. Conclusion: Through the results of this study, TrueBeamTM confirmed that the average error rate was 2.4 times higher for VMAT and 3.6 times higher for IMRT than HalcyonTM. Therefore, based on the results of this study, If we need a more accurate dose assessment for the superficial dose, It is expected that using HalcyonTM would be better than TrueBeamTM.

Clinical Implications of High Definition Multileaf Collimator (HDMLC) Dosimetric Leaf Gap (DLG) Variations

  • Chang, Kyung Hwan;Ji, Yunseo;Kwak, Jungwon;Kim, Sung Woo;Jeong, Chiyoung;Cho, Byungchul;Park, Jin-hong;Yoon, Sang Min;Ahn, Seung Do;Lee, Sang-wook
    • Progress in Medical Physics
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    • v.27 no.3
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    • pp.111-116
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    • 2016
  • This study is to evaluate the dosimetric impact of dosimetric leaf gap (DLG) and transmission factor (TF) at different measurement depths and field sizes for high definition multileaf collimator (HD MLC). Consequently, its clinical implication on dose calculation of treatment planning system was also investigated for pancreas stereotactic body radiation therapy (SBRT). The TF and DLG were measured at various depths (5, 8, 10, 12, and 15 cm) and field sizes ($6{\times}6$, $8{\times}8$, and $10{\times}10cm^2$) for various energies (6 MV, 6 MV FFF, 10 MV, 10 MV flattening filter free [FFF], and 15 MV). Fifteen pancreatic SBRT cases were enrolled in the study. For each case, the dose distribution was recomputed using a reconfigured beam model of which TF and DLG was the closest to the patient geometry, and then compared to the original plan using the results of dose-volume histograms (DVH). For 10 MV FFF photon beam, its maximum difference between 2 cm and 15 cm was within 0.9% and it is increased by 0.05% from $6{\times}6cm^2$ to $10{\times}10cm^2$ for depth of 15 cm. For 10 MV FFF photon beam, the difference in DLG between the depth of 5 cm and 15 cm is within 0.005 cm for all field sizes and its maximum difference between field size of $6{\times}6cm^2$ and $10{\times}10cm^2$ is 0.0025 cm at depth of 8 cm. TF and DLG values were dependent on the depth and field size. However, the dosimetric difference between the original and recomputed doses were found to be within an acceptable range (<0.5%). In conclusion, current beam modeling using single TF and DLG values is enough for accurate dose calculation.

A study of Curved Dosimeter for Flattening Filter Free Beam Quality Assurance Evaluation using Curved Dosimeter in Radiotherapy (Flattening Filter Free Beam의 정도관리를 위한 곡면선량계 가능성 연구)

  • Han, Moojae;Shin, Yohan;Jung, Jaehoon;Heo, Seunguk;Kim, Kyotae;Heo, Yeji;Cho, Heunglae;Park, Sungkwang
    • Journal of the Korean Society of Radiology
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    • v.13 no.1
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    • pp.119-124
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    • 2019
  • Radiation therapy using flattening filter free beam can prevent beam attenuation caused by flattening filter and can improve treatment efficiency. However, accurate dose control is not established for nonuniform iso dose distributions. In this study, curved dosimeter based on photoconductive material $HgI_2$ was fabricated and its reproducibility and linearity were evaluated at 6 MV photon energy to verify its performance. In order to show the usefulness of the curved measurement, the signals measured on the flat substrate and the curved substrate were compared in the flattening filter free beam using the acrylic filter. As a result, the reproducibility of the unit cell dosimeter was evaluated as SE 0.613%, and the linearity was evaluated as R-sq 0.9999. The usability evaluation of the array curve dosimeter demonstrated its usefulness by indicating a curvature error rate of 11.073%p and a reduced error rate.

Development of a 3D Printing Open-market System for Copyright Protection and Remote 3D Printing (3D프린터용 설계데이터의 저작권보호와 원격출력을 지원하는 오픈 마켓 시스템 개발)

  • Kim, Sung Gyun;Yoo, Woosik
    • Journal of Korean Institute of Industrial Engineers
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    • v.41 no.3
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    • pp.253-258
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    • 2015
  • The 3D printing is any of various processes for making a three dimensional object of almost any shape from a 3D model. Recently, a rapidly expanding hobbyist and home-use market has become established with the inauguration of the open-source RepRap and Fab@Home projects. However, this causes problems regarding copyright protection and usage of illegal 3D data. In this paper, we developed a 3D printing open-market system, which guarantees copyright protection using the remote 3D printing without direct distribution of 3D design data. Because most of the home-use 3D printers are FFF (Fused Filament Fabrication) based on NC code system, open-market system uses FFF 3D printers. Also, open-market system inspects the uploaded 3D model data, so the system can prevent distribution of illegal model data such as weapons, etc.

Blind Direct Decision Feedback Equalization using Prediction Error Filters (예측 오류 필터를 이용한 블라인드 결정 궤환 등화기 추정 기법)

  • 유화선;홍대식
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.28 no.3C
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    • pp.279-285
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    • 2003
  • In this paper we propose a blind decision feedback equalizer (DFE) that is characterized by the fact that it does not require channel estimation. Because the output of the optimized multistep prediction error filter (PEF) can be represented as a product of the channel partial impulse response and the transmitted sequence, a backward multistep PEF can be used as the blind DFE feedforward filter (FFF). The corresponding feedback filter (FBF) is obtained from the symbol -rate partial channel impulse response. The proposed algorithm has several advantages over existing blind channel estimation techniques, including stable performance without the necessity of exact channel order estimation.

Study on the Improvement of Efficiency in Dehydration Process of LNG Liquefaction Plant Using Molecular Sieve (분자체를 이용한 LNG 액화 플랜트 탈수 공정의 효율성 향상에 관한 연구)

  • JONGHWA PARK;DONSANG YU;DAEMYEONG CHO
    • Journal of Hydrogen and New Energy
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    • v.35 no.1
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    • pp.105-113
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    • 2024
  • The natural gas dehydration process plays a central role in liquefying LNG. This study proposes two natural gas dehydration process systems applicable to liquefied natural gas (LNG) liquefaction plants, and compares and analyzes energy optimization measures through simulation. The fuel gas from feed stream (FFF) case, which requires additional equipment for gas circulation, disadvantages are design capacity and increased energy. On the other hand, the end flash gas (EFG) case has advantages such as low initial investment costs and no need for compressors, but has downsides such as increased power energy and the use of gas with different components. According to the process simulation results, the required energy is 33.22 MW for the FFF case and 32.86 MW for the EFG case, confirming 1.1% energy savings per unit time in the EFG case. Therefore, in terms of design pressure, capacity, device configuration, and required energy, the EFG case is relatively advantageous. However, further research is needed on the impact of changes in the composition of regenerated gas on the liquefaction process and the fuel gas system.