• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.463-471
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• 2011

A novel $N_2O_2$ Schiff base ligand, N,N'-bis(4-methoxysalicylidene)phenylendiamine(4-$CH_3O$-Salphen), has been synthesized. It has been revealed that the compound is very useful for the spectrophotometric quantification of Fe(II) and Fe(III) ions in aqueous solutions, such as mineral water, hot spring water, sea water, and waste water. The optimum conditions for the quantitative analysis are the followings; [4-$CH_3O$-Salphen]=$4.0{\times}10^{-4}\;M$, DMF/$H_2O$=70/30(v/v), pH=3.4~3.8, T= at $55^{\circ}C$, and prereaction time=1.0 hr. The sample of single valence state was prepared by the preliminary oxidation or reduction using $H_2O_2$ ($5.0{\times}10^{-4}\;M$) and $NH_2OH{\cdot}HCl$ ($5.0{\times}10^{-4}\;M$). The quantitative analyses of Fe(II) and Fe(III) ion were performed by measuring the absorbance at 434 nm and 456 nm, respectively. The estimated mean values agreed well with the standard values within the range of 2.00~6.90%. The limit of detection was 27.9 ng/mL for Fe(II) and 55.8 ng/mL for Fe(III).

• Transactions of Materials Processing
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• v.9 no.3
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• pp.293-303
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• 2000

Recent developments of Fe technology make it possible to apply CAD/CAE/CAM techniques successfully to the stamping die design among the automotive parts industries. Those successful applications are greatly attributable to the development of commercial S/W. Up to now most commercial S/W for the analysis of sheet metal forming is based on the dynamic explicit algorithm. The main characteristics of dynamic explicit algorithm is that there is no convergence problem if the time increment is taken less than the stability limit. The stability of the analysis is guaranteed in the commercial code, since the adequate time increment is computed from the so called "Courant Condition". However excess computing time is often pointed out in the dynamic explicit analysis according to the characteristics of process parameters taken. In the study, various parameters that may affect the stability and the method how to improve computational efficiency of analysis have been investigated.estigated.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.35 no.10
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• pp.1329-1335
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• 2011

On the basis of detailed 3D finite-element (FE) limit analyses, the plastic limit load solutions for pipes with slanted circumferential through-wall cracks (TWCs) subjected to axial tension, global bending, and internal pressure are reported. The FE model and analysis procedure employed in the present numerical study were validated by comparing the present FE results with existing solutions for plastic limit loads of pipes with idealized TWCs. For the quantification of the effect of slanted crack on plastic limit load, slant correction factors for calculating the plastic limit loads of pipes with slanted TWCs from pipes with idealized TWCs are newly proposed from extensive 3D FE calculations. These slant-correction factors are presented in tabulated form for practical ranges of geometry and for each set of loading conditions.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.31 no.3 s.258
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• pp.322-330
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• 2007

This paper quantifies the effect of a bend angle of a pipe bend on plastic loads, via small strain and large strain FE limit analyses using elastic-perfectly plastic materials. To consider the effect of the attached straight pipe, two limiting cases are considered. One case corresponds to the pipe bend without the attached straight pipe, and the other to that with a sufficiently long attached straight pipe. For the former case, the FE results suggest that the limit load is not affected by the bend angle for both in-plane bending and internal pressure. For the latter case, however, the bend angle affects plastic loads. An interesting finding is that the plastic load smoothly changes from the limit load of the straight pipe when the bend angle approaches zero to the plastic load of the $90^{\circ}$ pipe bend when the bend angle approaches 90 degree. Based on such observations, closed-form plastic load solutions are proposed for the pipe bend with an arbitrary bend angle under in-plane bending and internal pressure.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.299-304
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• 2008

This paper presents plastic limit loads of piping branch junctions with local wall thinning under combined pressure and in-plane bending, based on systematic three-dimensional finite element limit analyses using elastic-perfectly plastic materials. An ideal branch junction without weld or reinforcement around the intersection is considered with two locations of wall thinning; one in the run pipe, and the other in the branch pipe. Based on FE results, effects of thinning geometries on plastic limit moments are quantified and simple approximations of plastic limit loads are proposed.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.22 no.6
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• pp.549-555
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• 2009

Based on three-dimensional(3-D) finite element limit analyses, this paper provides limit and TES (Twice-Plastic Load) loads for mitred pipe bends under bending and pressure. The plastic limit loads are determined from FE limit analyses based on elastic-perfectly-plastic materials using the small and large geometry change option. A wide range of parameters related to the mitred bend geometry is considered. Based on the finite element results, closed-form approximations of plastic limit and TES plastic load solutions for mitred pipe bends under bending are proposed.

• Nuclear Engineering and Technology
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• v.54 no.6
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• pp.2188-2197
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• 2022

To ensure the safety margin of a reactor pressure vessel (RPV) under normal operating conditions, it is regulated through the pressure-temperature (P-T) limit curve. The stress intensity factor (SIF) obtained by the internal pressure and thermal load should be obtained through crack analysis of the nozzle corner crack in advance to generate the P-T limit curve for the nozzle. In the ASME code Section XI, Appendix G, the SIF via the internal pressure for the nozzle corner crack is expressed as a function of the cooling or heating rate, and the wall thickness, however, the SIF via the thermal load is presented as a polynomial format based on the stress linearization analysis results. Inevitably, the SIF can only be obtained through finite element (FE) analysis. In this paper, simple prediction equations of the SIF via the thermal load under, cool-down and heat-up conditions are presented. For the Korean standard nuclear power plant, three geometric variables were set and 72 cases of RPV models were made, and then the heat transfer analysis and thermal stress analysis were performed sequentially. Based on the FE results, simple engineering solutions predicting the value of thermal SIF under cool-down and heat-up conditions are suggested.

• Transactions of Materials Processing
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• v.8 no.5
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• pp.482-490
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• 1999

7000 series Al alloy with good mechanical properties has been focused with tendency to reduce the components weight of aircraft and automobile. However, it is difficult to manufacture a sound extruded product because of segregation, grain growth, casting defect, surface defect, decreasing extrudability and so on. The objective of this study is to manufacture a new 7000 al alloy more than the extrudability of A7N01 and A7003 through controlling the weight (%) Mg, Zn, Si. Hot extrusion experiments on the axisymmetric rod are performed in 500℃ and also performed analysis of the same process using unmerical analysis method, a coupled rigid-thermoviscoplastic finite element method. Extrusion limit diagram was obtained for the developed alloy by FE-simulation in order to define the relationship of extrusion speed and initial billet temperature.

• Proceedings of the KSME Conference
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• 2007.05a
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• pp.1766-1771
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• 2007

This paper presents plastic limit loads and approximate J-integral estimates for circumferential part-through surface crack at the interface between elbows and pipes. Based on finite element limit analyses using elastic-perfectly plastic materials, plastic limit moments under in-plane bending are obtained and it is found that they are similar those for circumferential part-through surface cracks in the center of elbow. Based on present FE results, closed-form limit load solutions are proposed. Welds are not explicitly considered and all materials are assumed to be homogeneous. And the method to estimate the elastic-plastic J-integral for circumferential part-through surface cracks at the interface between elbows and straight pipes is proposed based on the reference stress approach, which was compared with corresponding solutions for straight pipes.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.16 no.1
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• pp.43-52
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• 2003

The present study is to investigate the ultimate behavior and limit state design of 2-I) R/C structures, with the changing of crack direction, and the yielding of the reinforcing steel bars, and Is to introduce an algorithm for the limit state design and analysis of 2-D R/C structures, directly from the finite element model. For the design of reinforcement in concrete the limit state design equation is incorporated into finite element algorithm to be based on the pointwise elemental ultimate behavior. It is also introduced a simplified nonlinear analysis algorithm for stress-strain relationship of R/C plane stress problem considering the cracking and its rotation in concrete and the yielding of the reinforcing steel bar. The algorithm is incorporated into the nonlinear finite element analysis. The analysis model is compared with the experimental model of R/C shear wall. In a simple design example for a shear wall, the required reinforcement ratios in each finite element is obtained from the limit state design equations.