• Journal of the Korean Chemical Society
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• v.37 no.6
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• pp.599-603
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• 1993

Crystal structure of bis(1,2-diaminopropane)palladium(II) bis(oxalato)palladate(II) has been determined by X-ray crystallography. Crystal data: $Pd_2C_{10}H_{10}N_{4}O_{8}$, $M_W$ = 573.09, orthorhombic, space group $P_{ccn}$ (No = 56), a = 16.178(5), b = 16.381(6), c = 6.685(2)$\{AA}$, V = 1771.6 $\{AA}^3$, $M_W$W = 573.09, $D_c$ = 2.014 g${\cdot}c\;m^{-3}$, Z = 4, T = 294K, F(000) = 1056.0 and $\mu$ = 20.466 c$m^{-1}$. The intensity data were collected with $Mo-K\alpha$ radiation (${\lambda}$ = 0.7107 $\AA)$ on an automatic four-circle diffractometer with a graphite monochromater. The structure was solved by Patterson method and refined by full matrix least-squares methods using Pivot weights. The final R and S values were R = 0.065, $R_W = 0.059, R_{all}$ = 0.065 and S = 4.315 for 605 observed reflections. Both cation and anion complexes are essentially planar and have dihedral angle of $18(l)^{\circ}$ between thier planes. In the crystal structure, they do not have the Magnus's salt type mixed stacks; instead, the complex anions form regular stacks along the c-axis with the M-M bond length of $3.343(5)\AA$ and their stacks are surrounded by the complex cations through hydrogen bonds with the nitrogen-oxygen distances of 2.94(3) and $3.31(4)\AA.$

• Journal of the Korean Institute of Landscape Architecture
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• v.40 no.4
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• pp.114-126
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• 2012

The purpose of this study is to find ways of the view evaluation of biotope classification before development by selecting an area, which is as large as about $10.0km^2$ around Non Gong Up, Auk Po Myun, Dalsung Gun, Daugu where the large project has been planned, as a subject of this study. The results of this study are as follows. Because of the classification of biotope, there are 23 kinds of types that are subdivided into 140 types. Three surveys for selecting the assessment indicators were performed. The first survey analyzed the importance of 22 selected assessment indicators based on the evaluation of an existing literature review and on the spot research. The second survey performed factor analysis and reclassified the value indicators. The third survey computed additive values of the selected assessment indicators. It used a method of standardizing the average importance of indicators by making their sum equal by 10. Theses additive values were then multiplied by each grade of indicators in order to make a final evaluation. The number of assessment indicators finally selected through the survey of asking specialist is vitality elements, visual obstructs elements etc 19. According to the result of evaluation of 1st, 1 grade spaces which especially valuable is analyzed that 7 spaces, 2 grade spaces for 4, 3 grade spaces for 5, 4 grade space for 2, 5 grade space for 5. Because of the evaluation of 2st, 1 grade spaces which especially valuable(1a, 1b) is analyzed that 15 spaces, 2 grade spaces which valuable is analyzed that 28 space. As the evaluation of site suitability model of this study couldn't have high applicability to other similar area because of having only one site as a subject, it is needed to do synthesize and standardization of various examples to have higher objectivity later.

• The Korean Journal of Air & Space Law and Policy
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• v.7
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• pp.177-203
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• 1995

In den letzten Jahren h ufen sich $F\ddot{a}llen$, in denen Luftpostsendungen gestohlen worden oder sonst abhanden gekommen sind. Zumeist handeltes sich urn Sendungen mit hohem Wert, oft genug urn Sendungen, die erhebliche Geldsummen oder gar Diamanten enthalten. Da nach den luftpostrechtlichen Vorschriften nur recht geringf gige $Betr\ddot{a}ge$ von der Post erstattet werden, liegt der Gedanke nahe, den Luftfrachtf hrer in Anspruch zu nehmen. Bei der $Luftpostbef\ddot{o}rderung$ liegt ein klassisches $Dreiecksverh\ddot{a}ltnis$ vor. Folgende Rechtsbeziehungen sind zu unterscheiden : (1) $Verh\ddot{a}ltnis$ zwischen dem Absender und der Post, (2) $Verh\ddot{a}ltnis$ zwischen Post und $Luftfrachtf\ddot{u}hrer$, (3) $Verh\ddot{a}ltnis$ zwischen $Gesch\ddot{a}digtern$ und $Luftfrachtf\ddot{u}hrer$, wobei der $Gesch\ddot{a}digte$ der Absender, $Empf\ddot{a}nger$ oder dinglich Berechtigte sein kann. Gegenstand der Untersuchung ist dieses zuletzt genannte $Rechtsverh\ddot{a}ltnis$. Angesichts der praktischen Bedeutung der hiermit in Zusammenhang stehenden Fragen, angesichts aber auch der Tatsache, $da{\beta}$ die auf erste Sicht umfangreiche (in - und) $ausl\ddot{a}ndische$ Literatur zuni Luftpostrecht wenig $aussagekr\ddot{a}ftig$ ist, erscheint eine genauere Untersuchung ist folgender: $Zun\ddot{a}chst$ wird die Rechtslage nach dem Warschauer Abkommen, insbesondere die Bestimmung des Art.2 Abs.2 WA, untersucht. $Ber\ddot{u}cksichtigt$ weren sodann die $\ddot{A}nderungen$ der genannten Bestimmung im Haag 1955 und Montreal 1975. Sodann wird die bislang vorliegende internationale Rechtsprechung behandelt. Dem $schlie{\beta}t$ sich die Diskussion des hier $ma{\beta}$- geblichen 52 LuftVG an. Besonderes Gewicht wird hierbei auf die Einbettung des Lufttransportrechts in das allgemeine Transportrecht gelegt. Es erscheint an der Zeit, die Vereinzelung der einzelnen Transportrechtsgebiete zu durchbrechen. Es wird sich zeigen, $da{\beta}$ aus dieser $Ber\ddot{u}cksichtigung$ anderer Transportrechtsgebiete sich eine sachgerechte $L\ddot{o}sung$ entwicklen Das Warschauer Abkommen befa t sich in seinem Art.2 Abs.2 $ausdr\ddot{u}cklich$ mit der Bef rderung von Luftpost. Die $urspr\ddot{u}ngliche$ Fassung von Warschau ist im Haag 1955 $ge\ddot{a}ndert$ worden. Eine weitere $\ddot{A}nderung$ ist in Montreal 1975 beschlossen worden.

• Proceedings of the KSAR Conference
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• 2001.03a
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• pp.22-22
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• 2001

To produce reconstituted rabbit embryos with fetal fibroblasts, the present study was evaluated the efficiencies of the different fusion and activation conditions as assessments of subsequent development and chromosome in the embryos. New Zealand White rabbits were used throughout the study. Fetal fibroblasts collected from 22-d of fetuses were cultured in DMEM ＋ 10% FBS in 5% $CO_2$ in air. The culture was maintained for 10 passages. In every passage half of cell suspension were kept In frozen. From rabbits treated with FSH in 30% PVP solution and hCG, oocytes were surgically collected from oviducts at 14 h post-hCG injection and stripped off their cumulus cells by re-pipetting in a 300 IU hyaluronidase solution. Oocytes with an extruded first polar body and dense cytoplasm were enucleated by micromanipulation in Ham's F-10 medium＋7.5 g/$m\ell$ cytochalasin B. Euncleation was confirmed under a fluorescence microscope after staining with 5 g/$m\ell$ bisbenzimide for 2 min. Each enucleated oocyte was injected with a fetal fibroblast into a perivitelline space. Reconstructed eggs were compared fusion rates either at 2.0 ㎸/cm or 1.6 ㎸/cm(60 sec, double pulses). After fusion, all eggs were activated with the combination of 5 M ionomycin (5 min) and 10 g/$m\ell$ cycloheximide (CHX, 3h), and cultured in CRlaa medium and transferred into TCM199＋10% FBS on day 3. Although there was not significantly differ in fusion rate between treatments (60%, 2.0 ㎸/cm vs. 79.4%, 1.6 ㎸/cm), none of them in the eggs fused with 2.0 ㎸/cm developed to blastocyst. In comparison of development and chromosome status between different activation treatments (Group 1; 5 M ionomycin/10 g/$m\ell$ CHX, Group 2; 5 M ionomycin/5 g/$m\ell$ CHX ＋ 2 mM DMAP after fusion with 1.6 ㎸/cm), there were not differ in cleavage and development rates (67.3% and 28.9% in Group 1; 67% and 33% in Group 2). All out of 8 embryos evaluated in Group 1 appeared a normal diploid chromosome sets and mean number of cells (Mean SEM) on day 4.5 of culture was 141.5 23.15 (n=8). It can be concluded that the use of cycloheximide has not happened in chromosome abnormalities, and fetal fibroblasts can be used for cloning in rabbit.

• Journal of Chest Surgery
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• v.40 no.6 s.275
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• pp.420-427
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• 2007

Background: Postpneumonectomy empyema (PPE) due to bronchopleural fistula (BPF) can be a surgical challenge for surgeons. We analyzed the follow-up outcomes after performing omentopexy and thoracoplasty for the treatment of PPE with BPF after pneumonectomy. Material and Mehod: Between December 1991 and January 2006, 9 patients underwent BPF closure using an omental pedicled flap for the treatment of PPE with BPF after pneumonectomy. There were 7 males and 2 females (mean age: $45.9{\pm}9$ years). The patients were followed up for a mean of 58 months (median: 28 months, range: $6{\sim}169$). When we performed omentopexy, the surgical procedures for empyema were thoracoplasy for 8 patients and the Clagett procedure for 1 patient. Thoracoplasty was performed for the latter patient due to recurrence of empyema, Result: For the 8 patients who were treated by omentopexy and thoracoplasty, there was 1 operation-related death due to sepsis. During follow up, 1 patient, who was treated by omentopexy and a Clagett procedure, died of acute hepatitis 40 months postoperatively. The early mortality was 11.1% (8/9). Of the 8 patients, including the 1 late death patient, successful closure of the BPF were achieved in all patients (8/9) and the empyema was cured in 7 patients (7/8). Conclusion: The BPF closure using an omental pedicled flap was an effective method for treating PPE with BPF due to 75-destroyed lung, and thoracoplasty with simultaneous omentopexy was effective and safe for removing dead space if the patient was young and in a good general condition.

• Journal of Korean Society of Forest Science
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• v.108 no.2
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• pp.216-223
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• 2019

This study was conducted to measure the changes in the geological and soil properties following slow-moving landslide events in Yangbuk-myun and Gyungju-si, Gyeongsangbuk-do, South Korea. The geological characteristics of the study site comprised black shale in the Gyeongsang nodal group formed in the Cretaceous period and quartz feldspar carcinoma in the east side with conglomerate in the Yeonil group formed in the Quaternary period. The study site exhibited the geologic characteristics of a slow-moving landslide with severely weathered rocks. The maximum collapsing depth of the slow-moving landslide was 12.0 m with colluvial deposits. The strike and joint aspects in the slope areas of the slow-moving landslides were $N46^{\circ}E$ in lower slope and $N62^{\circ}E$ in upper slope, respectively. Soil hardness of ${\leq}20cm$ deep was not measured because of the completely disturbed soil resulting from soil creeping. Soil from 25 to 90 cm deep was 1.4-4.7 times softer in the slow-moving landslide areas than in the undisturbed or natural forests. Soil bulk density was $1.24-1.29g/cm^3$ in land creep areas. Soil bulk in both areas was 1.6 times denser than that in the natural forest. The soil pore space was 51.5-53.3% in the land creep areas. The values are 1.3-1.4 times lower than those within the natural forest. Black shale areas showed the lowest coefficient of permeability (8.75 E-06 cm/s) and mesopore ratio (pF 2.7: 9.8%) compared with those resulting from other study areas.

• Tunnel and Underground Space
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• v.17 no.2 s.67
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• pp.128-138
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• 2007

At low in-situ stress, the continuity and distribution of natural fractures in rock mass predominantly control the failure processes. However at high in-situ stress, the failure process are affected and eventually dominated by stress-induced fractures preferentially growing parallel to the excavation boundary. This fracturing is often observed in brittle type of failure such as slabbing or spatting. Recent studies on the stress- or excavation-induced damage of rock revealed its importance especially in a highly stressed regime. In order to evaluate the brittle failure around a deep underground opening, physical model experiments were carried out. For the experiments a new tue triaxial testing system was made. According to visual observation and acoustic emission detection, brittle failure grades were classified under three categories. The test results indicate that where higher horizontal stress, acting perpendicular $(S_{H2})$ and parallel $(S_{H1})$ to the axis of the tunnel respectively, were applied, the failure grade at a constant vertical stress level (Sy) was lowered. The failure initiation stress was also increased with the increasing $S_{H1}\;and\;S_{H2}$. From the multi-variable regression on failure initiation stress and true triaxial stress conditions, $f(S_v,\;S_{H1},\;S_{H2})$ was proposed.

• Korean Institute of Interior Design Journal
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• v.17 no.1
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• pp.3-10
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• 2008

This study is concerned with the process of development and architectural characteristics of secular stained glass in the 20th century. Stained glass had been architectural art from the origin. But it had declined since the Renaissance era, and began to revive in the early 20th century. Stained glass work is very flourish in Korea today, but it is still treated as simple decoration or 2-dimensional mosaic. Architect and interior designer even have little understanding of architectural character of stained glass. In order to recover the architectural nature of stained glass, I have considered the process of development of secular stained glass in the 20th century, and analysed the works of Frank Lloyd Wright, the postwar German artists, Georg Meistermann, Ludwig Schaffrath, Johannes Schreiter, and English artist, Brian Clarke. Major findings of the study are as followings : First, stained glass has come to life again from the secular glass painting decoration in the end of the 19th century, through Art-Nouveau, De Stil, Bauhaus in the beginning of the 20th century, and L'Art $Sacr\acute{e}$. Second, Frank Lloyd Wright, the postwar German artists and Brian Clarke have established the architectural concept and potentiality of the modem stained glass in the secular field. Third, They have done by coming back to the basic creative method by traditional lead-came technique in spite of the development of various materials and techniques. Forth, stained glass fundamentally has architectural characteristics as the characters of Space, Time, Place, Context, and they have showed the new possibility of stained glass by recovery of these characters.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.19 no.2
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• pp.67-73
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• 2013

This study investigated the quality changes of Samgyetang during storage, resulting from various degassing methods used at the packaging stage. Three different samples were prepared, one without any treatment (CON), a second with reduced head space volume by squeezing the pouch (RHS), and a third by flushing with nitrogen gas (NGF). These were retorted at $120^{\circ}C$ for 65 min under the F-value of approx. 8.0, and stored at $25^{\circ}C$ for 9 months. The oxygen ratio in the head space and the dissolved oxygen content of NGF samples tended to be lower than those of other samples over the storage period. Compared to the CON, the acid values of NGF and RHS samples were lower than the CON from month 3 and 6 (p<0.05). During storage, volatile basic nitrogen values of NGF and RHS samples increased slowly compared to the CON. To delay quality deterioration and extend the shelf-life of Samgyetang products, the reduction of oxygen content in the head space of the retort pouch (preferably by flushing with nitrogen gas) is recommended, even though no significant differences in sensory evaluation were observed among the samples during 9 months of storage (p>0.05).

• Toxicological Research
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• v.21 no.2
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• pp.141-150
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• 2005

1,3-Dichloro-2-propanol (1,3-DCP) is known as chloride chemicals and causes severe hepatotoxic agent. The Ito cells and Kupffer's cells of the liver in the 5 old F344 Rats were exposed to 1,3-DCP gas chamber for 6 hours/ a day, 5 days/ a week, and 13 weeks, in the 0, 5, 20, 80 ppm, respectively. After then the body weights, liver weights, and relative liver weight to body weight were measured, and the hepatic tissues were prepared by the routine and Immunostain method, and observed by the LM, and EM. In the results, there were severe body weight decrease (p<0.05) in the 80 ppm of the male and female rats. The relative liver weights to the body weight were increased relate with exposed 1,3-DCP concentration (P<0.001). Inflammatory cells, infiltration was observed at the perivascular area in the 20 ppm exposed group, and bilirubin pigment infiltration, bile duct hyperplasia, inflammation hepatocytic necrosis, fibrosis were observed in the 80 ppm exposure group. In the 80 ppm exposure group, disarrangement of the endothelial cells, erythrocytes and hepatic cell fragment in the Disse space and numerous migration macrophages were observed in the necrotic area by EM observation. In the immunostained hepatic tissues positive stained ED1 cells were extremely increased (P<0.05) in central vein area, but ED2 was weakly positive immunostained in the 80 ppm exposed group. Immunostained desmin was observed in the Ito cell. It was no difference in the low and medium exposed group but it was typical increase in the necrotic area. In conclusion, These results suggest that NOAEL of 1,3-DCP may be 5 ppm in rats and the Immunostained of desmin, ED1 and ED2 positive cells activated in the inflammatory liver were related to the exposure volume and density. The increase of the Ito cells were related to the severe phagocytosis of the Kupffer's cells.