• 제목/요약/키워드: F.E.M analysis

검색결과 568건 처리시간 0.028초

Synthesis of Nucleophilic Adducts of Thiols (Ⅰ). Addition of Cysteine to $\beta$-Nitrostyrene Derivatives

  • Kim, Tae-Rin;Choi, Sung-Yong
    • Bulletin of the Korean Chemical Society
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    • 제2권4호
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    • pp.125-129
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    • 1981
  • The addition reactions of cysteine without blocking amino and carboxyl groups to substituted and unsubstituted ${\beta}$-nitro-styrene derivatives were investigated. ${\beta}$-Nitrostyrene(1a), p-methyl-${\beta}$-nitrostyrene(1b), 3,4,5-trimethoxy-$[\beta}$ -nitrostyrene(1c), $[\varpi}$-3,4-methylenedioxy-${\beta}$ -nitrostyrene(1d), o-, m- and p-chloro-${\beta}$ -nitrostyrene (1e, 1f, 1g) and o-, m- and p-methoxy-${\beta}$-nitrostyrene (1h, 1i, 1j) easily undergo addition reactions with cysteine to form S-(2-nitro-1-phenylethyl)-L-cysteine(3a), S-[2-nitro-1-(p-methyl)phenyl-ethyl]-L-cysteine(3b), S-[2-nitro-1-(3',4',5'-trimethoxy) phenylethyl]-L-cysteine(3c), S-[2-nitro-1-($[\vatpi}$ -3',4'-methylenedioxy)phenylethyl]-L-cysteine(3d), S-[2-nitro-1-(o-chloro)phenylethyl]-L-cysteine(3e), S-[2-nitro-1-(m-chloro)-phenylethyl]-L-cysteine(3f), S-[2-nitro-1-(p-chloro)phenylethyl]-L-cysteine(3g), S-[2-nitro-1-(o-methoxy)phenylethyl]-L-cysteine(3h), S-[2-nitro-1-(m-methoxy)phenylethyl]-L-cysteine(3i) and S-[2-nitro-1-(p-methoxy)phenylethyl]-L-cysteine(3j), respectively. The structure of adducts were confirmed by means of UV-spectrum, IR-spectrum, molecular weight measurement and elemental analysis. The various factors effecting the yield of cysteine adducts to ${\beta}$-nitrostyrene derivatives were also studied.

The Use of Pistachio Pollen for the Production of Nanostructured Porous Nickel Oxide

  • Atalay, F.E.;Yigit, E.;Biber, Z.S.;Kaya, H.
    • Nano
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    • 제13권12호
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    • pp.1850143.1-1850143.9
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    • 2018
  • Natural biotemplates - such as bacteria, fungi and viruses - are used in nanostructured metal oxide production. The pollen can be found abundantly in nature, and their microcapsules can be easily isolated from the pollen by chemical treatments. To date, pollen microcapsules are mostly used as drug carriers and catalytic agent templates. In the present study, nanoporous-structured nickel oxide is produced using Pistachio pollen microcapsules. The raw pollen, chemically treated pollen and metal-coated pollen were characterized using scanning electron microscopy, Brunauer-Emmett-Teller (BET) surface area analysis, thermogravimetric analysis (TGA), differential thermal analysis (DTA) and X-ray diffraction (XRD) techniques. The natural Pistachio pollen which were procured from Gaziantep, Turkey, are spherical, with a diameter of approximately $23{\mu}m$. The maximum surface area obtained for nickel oxide-coated microcapsules is $228.82m^2/g$. This result shows that Pistachio pollen are an excellent candidate for the production of porous nanostructured materials for supercapacitor electrodes.

히이트 파이프용 열교환기의 에너지 회수효과 해석 해법 (An Analytical Method on the Effective Energy Recovery for Heat Exchanger with Heat Pipes)

  • 장영석;서해성;이영수;전철호
    • 태양에너지
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    • 제9권2호
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    • pp.31-41
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    • 1989
  • The purpose of this research is to study the utility of prediction program like a F.E.M. analysis for energy recovery of heat exchanger with heat pipe which uses arbitrary groove wick. The program is based on the utility by the experimental and applytical method of the single heat pipe. It is also expanded and applied in the prediction program of the heat exchanger. The results are as follows; 1) The effective thermal conductivity of the groove wick with arbitrary shape is counted by the thermal resistance change. 2) The more the number of rows, the more the effect energy recovery changing by the number of rows, the bigger the free velocity, the smaller the effect of energy recovery. 3) The effect of energy recovery increases according to the value of the rate of mass flow (Me/Mc) and also number of rows. 4) The comparison between calculated and data shows good agreement within 2.5% error, therefore the F.E.M. analysis of the study is useful to predict the performance of heat pipe-heat exchanger.

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냉간단조용 금형의 변형모드에 따른 탄성변형량의 측정 및 유한요소 해석 (Measurement and FEM Analysis of Elastic Deformation According to the Forging Stages in Cold Forging Die)

  • 이대근;이영선;이정환
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2002년도 춘계학술대회 논문집
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    • pp.112-116
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    • 2002
  • In cold forging, the elastic behavior of the die has a direct influence on the accuracy of the forging part. And the die dimension is continuously changed during the loading, unloading, and ejecting stage. In this paper, we evaluated the elastic deflections of cold forging die during loading, unloading, and ejecting stage. Uni-axial strain gauges are used to measure elastic strain of die during each forging stage. Strain gauges are attached on the surface of die. A commercial F.E.M code, DEFORM-2D$\^$TM/ is used to predict elastic strain of die. Two method of F.E.M. analysis are used to compare with measured and calculated elastic strain. One is to regard the die as rigid body over forging cycle. And then, the die sass is analyzed by loading the die with pressure from the forging part. The other is to regard the die as elastic body from forging cycle. The elastic strain of die is calculated and the die is elastically deformed at each strop. The calculated results under the elastic die assumption are well agreed with experimental data using strain gauges.

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S여대생(女大生)의 구강보건 실태조사 (A STUDY ON THE DENTAL HEALTH STATUS OF A COLLEGE GIRL STUDENTS)

  • 김정식
    • Restorative Dentistry and Endodontics
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    • 제6권1호
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    • pp.123-132
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    • 1980
  • The author conducted a dental survey of a college girl students and compared with that of E college students 10 years ago which based on the same criteria. The items of this survey included the prevalence of dental caries, DMFT and the kinds of restored material. All college students 1,414 were examined in May 1978, with the recommended criteria and method of W.H.O.. Among them, the data of 1,393 were analyzed for this study. The following results were obtained: 1. The average number of present teeth were 28.97${\pm}$1.64. 2. The prevalence of dental caries was 84.92% and D.M.F. index was 15.51. Average D.M.F. teeth were 4.49${\pm}$3.69. 3. The average number of decayed (D) teeth were 2.09${\pm}$2.16. 4.30% of the present decayed teeth was secondary decay, and 2.44% of the decayed teeth was indicated for extraction. 4. The average number of missing(M) teeth were 0.32${\pm}$0.79. It included 8.56% of root fragements. 5. Average number of filled(F) teeth were 2.09${\pm}$3.17. F-ratio of this group was 46.45%. The analysis revealed 50.88% of amalgam alloy, 31.41% of gold inlays, and 1.20%, the least among the filling materials, silicate cement or composite resin. 6. While the prosthodontic treatment, such as crown and bridge has reduced than that of 10 years ago, the fillings and inlays as the conservative means has increased.

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Streptomyces coelicolor (Muller)의 과산화수소 대응 반응에 관련된 단백질 양상의 분석 (Profile Analysis of Proteins Related with Hydrogen Peroxide Response in Strep-tomyces coelicolor (Muller))

  • 정혜정;노정혜
    • 미생물학회지
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    • 제31권2호
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    • pp.166-174
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    • 1993
  • Streptomyces coelicolor (Muller) 의 세포에 $100 \mu$M 의 과산화수소를 1시간 동안 처리하여 과산화수소 스트레스중에 생성되는 단백질을 L-[$^{35}S$] methionine 을 이용하여 순간 표지하였다. 단백질을 추출하여 2차원 겔 전기영동으로 분석한 결과 지수 성장기의 세포가 가지는 총세포 단백질 중 약 100개의 단백질의 합성이 과산화수소에 의해 증가되는 것을 관찰하였다. 이들을 Pin(peroxide inducible) 단백질이라고 명명하고 과상화수소 처리 후 발현이 증가되는 시간에 따라 세 그룹으로 나누었다. 약 60 개의 Pin 단백질은 과산화수소 처리후 20분 이내에 발현이 증가하여 1시간동안 지속적으로 다량 합성되었다. 정체 성장기의 세포에서는 62개의 단백질의 합성이 과산화수소에 의해 증가되었으며, 이 중 21 개의 단백질은 지수성장기의 Pin 단백질과 일치하였다. 과산화수소에 대한 저항성이 증가한 세가지 돌연변이체의 단백질을 지수 성장기에서 추출하여 2 차원 겔 전기영동으로 분석한 결과, 각각의 경우 15, 17, 15개의 Pin 단백질을 야생형보다 항상적으로 다량합성하는 것을 관찰하였다. 이 pin 단백질 중 9개 (D74.7 a, E76.0c, E23.3, F50.7, F47.2a, F25.5, G39.6b, G24.0, H39.6a) 는 두가지 돌연변이체 모두에게 증가되었다. 따라서 이 단백질들은 S. coelicolor 가 과산화수소 스트레스에 대응하는데 있어 중요한 역할을 담당한다고 추정된다.

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Mutation Detection of E6 and LCR Genes from HPV 16 Associated with Carcinogenesis

  • Mosmann, Jessica P.;Monetti, Marina S.;Frutos, Maria C.;Kiguen, Ana X.;Venezuela, Raul F.;Cuffini, Cecilia G.
    • Asian Pacific Journal of Cancer Prevention
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    • 제16권3호
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    • pp.1151-1157
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    • 2015
  • Human papillomavirus (HPV) is responsible for one of the most frequent sexually transmitted infections. The first phylogenetic analysis was based on a LCR region fragment. Nowadays, 4 variants are known: African (Af-1, Af-2), Asian-American (AA) and European (E). However the existence of sub-lineages of the European variant havs been proposed, specific mutations in the E6 and LCR sequences being possibly related to persistent viral infections. The aim of this study was a phylogenetic study of HPV16 sequences of endocervical samples from C${\acute{o}}$rdoba, in order to detect the circulating lineages and analyze the presence of mutations that could be correlated with malignant disease. The phylogenetic analysis determined that 86% of the samples belonged to the E variant, 7% to AF-1 and the remaining 7% to AF-2. The most frequent mutation in LCR sequences was G7521A, in 80% of the analyzed samples; it affects the binding site of a transcription factor that could contribute to carcinogenesis. In the E6 sequences, the most common mutation was T350G (L83V), detected in 67% of the samples, associated with increased risk of persistent infection. The high detection rate of the European lineage correlated with patterns of human migration. This study emphasizes the importance of recognizing circulating lineages, as well as the detection of mutations associated with high-grade neoplastic lesions that could be correlated to the development of carcinogenic lesions.

선점법과 유한요소법을 사용한 단순지지된 등변사다리꼴 직교이방성판의 좌굴해석 (Buckling Analysis of Simply Supported Isosceles Trapezoidal Orthotropic Plate Using Collocation and Finite Element Method)

  • 이병권;채수하;윤순종
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 추계학술발표대회 논문집
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    • pp.13-16
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    • 2001
  • This paper presents the results of an elastic buckling analysis of isosceles trapezoidal orthotropic plate. In this study, all edges of plate are assumed to be simply supported and the difference of the applied loads are assumed to be taken out by shear of constant intensity along the sloping sides. For the buckling analysis, collocation method is employed. Finite element analysis is also conducted and the results are compared with theoretical ones.

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불소화된 $YBa_2Cu_3O_{7-y}$ 초전도체의 구조적, 전기적 성질에 관한 연구 (A study on the structural and electric properties of fluorinated $YBa_2Cu_3O_{7-y}$)

  • 김재욱;김채옥
    • E2M - 전기 전자와 첨단 소재
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    • 제9권4호
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    • pp.404-409
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    • 1996
  • The structural and electric properties of $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$(x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) have been investigated by using XRD(X-ray diffraction), TMA(thennomechanical analysis), NMR(nuclear magnetic resonance) analysis and four probe method. $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$ samples were prepared by conventional solid-state reaction method using $Y_{2}$O$_{3}$, BaCO$_{3}$, CuO and YbF$_{3}$ power. TMA and high temperature XRD results shows that orthorhombic to tetragonal phase transition occurs in the unfluorinated 1-2-3 sample while the phase change is not observed in the fluorinated 1-2-3 samples. Superconducting transition temperature(T$_{c}$) increases with increasing YbF$_{3}$ content ; T$_{c}$, of the sample reaching maximum of 102K for x=0.3, and then decreases with further increasing YbF$_{3}$ content. The structural analysis and T$_{c}$ results shows that the fluorine doping stabilize the orthorhombic phase, together with the increase in T$_{c}$.}$ c/.TEX> c/.

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