• Title/Summary/Keyword: F.E.M analysis

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Synthesis of Nucleophilic Adducts of Thiols (Ⅰ). Addition of Cysteine to $\beta$-Nitrostyrene Derivatives

  • Kim, Tae-Rin;Choi, Sung-Yong
    • Bulletin of the Korean Chemical Society
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    • v.2 no.4
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    • pp.125-129
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    • 1981
  • The addition reactions of cysteine without blocking amino and carboxyl groups to substituted and unsubstituted ${\beta}$-nitro-styrene derivatives were investigated. ${\beta}$-Nitrostyrene(1a), p-methyl-${\beta}$-nitrostyrene(1b), 3,4,5-trimethoxy-$[\beta}$ -nitrostyrene(1c), $[\varpi}$-3,4-methylenedioxy-${\beta}$ -nitrostyrene(1d), o-, m- and p-chloro-${\beta}$ -nitrostyrene (1e, 1f, 1g) and o-, m- and p-methoxy-${\beta}$-nitrostyrene (1h, 1i, 1j) easily undergo addition reactions with cysteine to form S-(2-nitro-1-phenylethyl)-L-cysteine(3a), S-[2-nitro-1-(p-methyl)phenyl-ethyl]-L-cysteine(3b), S-[2-nitro-1-(3',4',5'-trimethoxy) phenylethyl]-L-cysteine(3c), S-[2-nitro-1-($[\vatpi}$ -3',4'-methylenedioxy)phenylethyl]-L-cysteine(3d), S-[2-nitro-1-(o-chloro)phenylethyl]-L-cysteine(3e), S-[2-nitro-1-(m-chloro)-phenylethyl]-L-cysteine(3f), S-[2-nitro-1-(p-chloro)phenylethyl]-L-cysteine(3g), S-[2-nitro-1-(o-methoxy)phenylethyl]-L-cysteine(3h), S-[2-nitro-1-(m-methoxy)phenylethyl]-L-cysteine(3i) and S-[2-nitro-1-(p-methoxy)phenylethyl]-L-cysteine(3j), respectively. The structure of adducts were confirmed by means of UV-spectrum, IR-spectrum, molecular weight measurement and elemental analysis. The various factors effecting the yield of cysteine adducts to ${\beta}$-nitrostyrene derivatives were also studied.

The Use of Pistachio Pollen for the Production of Nanostructured Porous Nickel Oxide

  • Atalay, F.E.;Yigit, E.;Biber, Z.S.;Kaya, H.
    • Nano
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    • v.13 no.12
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    • pp.1850143.1-1850143.9
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    • 2018
  • Natural biotemplates - such as bacteria, fungi and viruses - are used in nanostructured metal oxide production. The pollen can be found abundantly in nature, and their microcapsules can be easily isolated from the pollen by chemical treatments. To date, pollen microcapsules are mostly used as drug carriers and catalytic agent templates. In the present study, nanoporous-structured nickel oxide is produced using Pistachio pollen microcapsules. The raw pollen, chemically treated pollen and metal-coated pollen were characterized using scanning electron microscopy, Brunauer-Emmett-Teller (BET) surface area analysis, thermogravimetric analysis (TGA), differential thermal analysis (DTA) and X-ray diffraction (XRD) techniques. The natural Pistachio pollen which were procured from Gaziantep, Turkey, are spherical, with a diameter of approximately $23{\mu}m$. The maximum surface area obtained for nickel oxide-coated microcapsules is $228.82m^2/g$. This result shows that Pistachio pollen are an excellent candidate for the production of porous nanostructured materials for supercapacitor electrodes.

An Analytical Method on the Effective Energy Recovery for Heat Exchanger with Heat Pipes (히이트 파이프용 열교환기의 에너지 회수효과 해석 해법)

  • Jang, Yeong-Suk;Seo, Hae-Sung;Lee, Young-Soo;Jun, Chul-Ho
    • Solar Energy
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    • v.9 no.2
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    • pp.31-41
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    • 1989
  • The purpose of this research is to study the utility of prediction program like a F.E.M. analysis for energy recovery of heat exchanger with heat pipe which uses arbitrary groove wick. The program is based on the utility by the experimental and applytical method of the single heat pipe. It is also expanded and applied in the prediction program of the heat exchanger. The results are as follows; 1) The effective thermal conductivity of the groove wick with arbitrary shape is counted by the thermal resistance change. 2) The more the number of rows, the more the effect energy recovery changing by the number of rows, the bigger the free velocity, the smaller the effect of energy recovery. 3) The effect of energy recovery increases according to the value of the rate of mass flow (Me/Mc) and also number of rows. 4) The comparison between calculated and data shows good agreement within 2.5% error, therefore the F.E.M. analysis of the study is useful to predict the performance of heat pipe-heat exchanger.

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Measurement and FEM Analysis of Elastic Deformation According to the Forging Stages in Cold Forging Die (냉간단조용 금형의 변형모드에 따른 탄성변형량의 측정 및 유한요소 해석)

  • 이대근;이영선;이정환
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.05a
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    • pp.112-116
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    • 2002
  • In cold forging, the elastic behavior of the die has a direct influence on the accuracy of the forging part. And the die dimension is continuously changed during the loading, unloading, and ejecting stage. In this paper, we evaluated the elastic deflections of cold forging die during loading, unloading, and ejecting stage. Uni-axial strain gauges are used to measure elastic strain of die during each forging stage. Strain gauges are attached on the surface of die. A commercial F.E.M code, DEFORM-2D$\^$TM/ is used to predict elastic strain of die. Two method of F.E.M. analysis are used to compare with measured and calculated elastic strain. One is to regard the die as rigid body over forging cycle. And then, the die sass is analyzed by loading the die with pressure from the forging part. The other is to regard the die as elastic body from forging cycle. The elastic strain of die is calculated and the die is elastically deformed at each strop. The calculated results under the elastic die assumption are well agreed with experimental data using strain gauges.

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A STUDY ON THE DENTAL HEALTH STATUS OF A COLLEGE GIRL STUDENTS (S여대생(女大生)의 구강보건 실태조사)

  • Kim, Jung-Sik
    • Restorative Dentistry and Endodontics
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    • v.6 no.1
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    • pp.123-132
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    • 1980
  • The author conducted a dental survey of a college girl students and compared with that of E college students 10 years ago which based on the same criteria. The items of this survey included the prevalence of dental caries, DMFT and the kinds of restored material. All college students 1,414 were examined in May 1978, with the recommended criteria and method of W.H.O.. Among them, the data of 1,393 were analyzed for this study. The following results were obtained: 1. The average number of present teeth were 28.97${\pm}$1.64. 2. The prevalence of dental caries was 84.92% and D.M.F. index was 15.51. Average D.M.F. teeth were 4.49${\pm}$3.69. 3. The average number of decayed (D) teeth were 2.09${\pm}$2.16. 4.30% of the present decayed teeth was secondary decay, and 2.44% of the decayed teeth was indicated for extraction. 4. The average number of missing(M) teeth were 0.32${\pm}$0.79. It included 8.56% of root fragements. 5. Average number of filled(F) teeth were 2.09${\pm}$3.17. F-ratio of this group was 46.45%. The analysis revealed 50.88% of amalgam alloy, 31.41% of gold inlays, and 1.20%, the least among the filling materials, silicate cement or composite resin. 6. While the prosthodontic treatment, such as crown and bridge has reduced than that of 10 years ago, the fillings and inlays as the conservative means has increased.

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Profile Analysis of Proteins Related with Hydrogen Peroxide Response in Strep-tomyces coelicolor (Muller) (Streptomyces coelicolor (Muller)의 과산화수소 대응 반응에 관련된 단백질 양상의 분석)

  • 정혜정;노정혜
    • Korean Journal of Microbiology
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    • v.31 no.2
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    • pp.166-174
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    • 1993
  • Streptomyces coeUc%r (Muller) cells were treated with $100 \mu$M hydrogen peroxide for I hour and proteins synthesized during hydrogen peroxide stress were labeled with L-[$^{35}S$]-methionine. Total cellular proteins were extracted and analyzed by two-dimensional polyacrylamide gel electrophoresis. In exponential growth phase, synthesis of about 100 proteins was increased by hydrogen peroxide treatment. These proteins were named as Pin (£eroxide-inducib]e) proteins and classified into 4 subgroups according to their induction time after hydrogen peroxide treatment. About 60 of them were found to be induced within 20 minutes and maintained throughout I hour of treatment. In stationary growth phase. synthesis of 62 proteins was increased by hydrogen peroxide and 21 of them were the same Pins found in exponential growth phase. Proteins from the mutants which are resistant to hydrogen peroxide were obtained in exponential growth phase and compared with those from the wild type on two-dimensional gel. The three mutants, N7, N9. and N24, were found to have higher constitutive leve]s of ]5, 17, and 15 Pin proteins respectively, than the wild type. 9 of these Pin proteins (D74.7a, E76.0c, E23.3. F50.7, F47.2a. F25.5, G39.6b, G24.0, H39.6a) increased in two of the three mutants and 3 proteins (F39.7, H6I.7. 120.8) increased in all of the three mutants. These proteins might play important roles in the response of S. coelic%r to hydrogen peroxide.

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Mutation Detection of E6 and LCR Genes from HPV 16 Associated with Carcinogenesis

  • Mosmann, Jessica P.;Monetti, Marina S.;Frutos, Maria C.;Kiguen, Ana X.;Venezuela, Raul F.;Cuffini, Cecilia G.
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.3
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    • pp.1151-1157
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    • 2015
  • Human papillomavirus (HPV) is responsible for one of the most frequent sexually transmitted infections. The first phylogenetic analysis was based on a LCR region fragment. Nowadays, 4 variants are known: African (Af-1, Af-2), Asian-American (AA) and European (E). However the existence of sub-lineages of the European variant havs been proposed, specific mutations in the E6 and LCR sequences being possibly related to persistent viral infections. The aim of this study was a phylogenetic study of HPV16 sequences of endocervical samples from C${\acute{o}}$rdoba, in order to detect the circulating lineages and analyze the presence of mutations that could be correlated with malignant disease. The phylogenetic analysis determined that 86% of the samples belonged to the E variant, 7% to AF-1 and the remaining 7% to AF-2. The most frequent mutation in LCR sequences was G7521A, in 80% of the analyzed samples; it affects the binding site of a transcription factor that could contribute to carcinogenesis. In the E6 sequences, the most common mutation was T350G (L83V), detected in 67% of the samples, associated with increased risk of persistent infection. The high detection rate of the European lineage correlated with patterns of human migration. This study emphasizes the importance of recognizing circulating lineages, as well as the detection of mutations associated with high-grade neoplastic lesions that could be correlated to the development of carcinogenic lesions.

Buckling Analysis of Simply Supported Isosceles Trapezoidal Orthotropic Plate Using Collocation and Finite Element Method (선점법과 유한요소법을 사용한 단순지지된 등변사다리꼴 직교이방성판의 좌굴해석)

  • 이병권;채수하;윤순종
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.10a
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    • pp.13-16
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    • 2001
  • This paper presents the results of an elastic buckling analysis of isosceles trapezoidal orthotropic plate. In this study, all edges of plate are assumed to be simply supported and the difference of the applied loads are assumed to be taken out by shear of constant intensity along the sloping sides. For the buckling analysis, collocation method is employed. Finite element analysis is also conducted and the results are compared with theoretical ones.

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A study on the structural and electric properties of fluorinated $YBa_2Cu_3O_{7-y}$ (불소화된 $YBa_2Cu_3O_{7-y}$ 초전도체의 구조적, 전기적 성질에 관한 연구)

  • 김재욱;김채옥
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.404-409
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    • 1996
  • The structural and electric properties of $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$(x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) have been investigated by using XRD(X-ray diffraction), TMA(thennomechanical analysis), NMR(nuclear magnetic resonance) analysis and four probe method. $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$ samples were prepared by conventional solid-state reaction method using $Y_{2}$O$_{3}$, BaCO$_{3}$, CuO and YbF$_{3}$ power. TMA and high temperature XRD results shows that orthorhombic to tetragonal phase transition occurs in the unfluorinated 1-2-3 sample while the phase change is not observed in the fluorinated 1-2-3 samples. Superconducting transition temperature(T$_{c}$) increases with increasing YbF$_{3}$ content ; T$_{c}$, of the sample reaching maximum of 102K for x=0.3, and then decreases with further increasing YbF$_{3}$ content. The structural analysis and T$_{c}$ results shows that the fluorine doping stabilize the orthorhombic phase, together with the increase in T$_{c}$.}$ c/.TEX> c/.

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