• Proceedings of the KIEE Conference
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• 2005.11a
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• pp.21-23
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• 2005

The electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient $ND_L$ in $C_{3}F_{8}-Ar$ mixture gases were measured by Double shutter drift tube and calculated by multi-term approximation of the Boltzmann equation over the wide E/N range from 0.03 to 100 Td. And an inelastic collision cross sections for $C_{3}F_{8}$ molecular gas were redetermined for quantitative characteristic analysis.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2005.11a
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• pp.341-345
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• 2005

This paper is for the combustion characteristics of gas generator which drive 1.5MW-class turbo pump and runs in fuel-rich combustion regime with LOx/kerosene as propellant. The outline of development procedure of real scale high pressure gas generator is introduced and the relation between O/F ratio and outlet temperature and the molecular weight and specific heat ratio of combustion gas are described. The relation between O/F ratio and temperature is newly obtained at higher pressure and the molecular weight and specific heat ratio is modified and their validity is confirmed by the mass relation equation.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.12
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• pp.1016-1020
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• 2002

Ru thin films were etched using CF/$_4$O$_2$ plasma in an ICP (inductively coupled plasma etching) system. The maximum etch rate of Ru thin films was 168 nm/min at a CF$_4$/O$_2$ gas mixing ratio of 10 %. The selectivity of SiO$_2$ over Ru was 1.3. From the OES (optical emission spectroscopy) analysis, the optical emission intensity of the O radical had a maximum value at 10% CF$_4$ gas concentration and drcrease with further addition of CF4 gas, but etch slope was enhanced. From XPS (x-ray photoelectron spectroscopy) analysis, the surface of the etched Ru thin film in CF$_4$/O$_2$ chemistry shows Ru-F bonds by the chemical reaction of Ru and F. RuF$_{x}$ compounds were suggested as a surface passivation layer that reduces the chemical reactions between Ru and O radicals. From a FE-SEM (field emission scanning electron microscope) micrograph, we had an almost perpendicular taper angle of 89$^{\circ}$.>.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.33 no.2
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• pp.92-97
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• 2005

A series of combustion test was done to verify the optimization result of a gas generator for a 10 ton thrust liquid rocket engine. An injector element is F-O-F impinging type injector and the test was conducted with kerosene/LOX propellants. Test results of combustion temperature and pressure show a very good agreement with optimal design result and verify that the design method was properly established. And turbulence ring revealed its effectiveness in enhancing combustion gas mixing and temperature difference in the radial direction showed only less than 15K. Also turbulence ring induced only 3.2% pressure loss in the combustion chamber, which is far less than conventional level observed in a gas turbine engine. Axial temperature distribution also shows that turbulence ring could effectively reduce about 10% or more in gas generator length if its location is properly selected.

• Journal of the Korean Institute of Gas
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• v.2 no.1
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• pp.7-13
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• 1998

In this study, for the safety performance of LNG storage tank, the fracture toughness in X-grooved weld HAZ(heat-affected zone) of $9\%$ Ni steel was evaluated qualitatively and quantitatively, and the relation with the change in microstructure was analyzed. The toughness assessment was peformed through the modified CTOD test proposed for thick weldment with X-groove. Additionally, microstructures of HAZ were evaluated by OM, SEM and XRD. From the results, HAZ toughness of SMA(shielded metal arc)-welded $9\%$ Ni steel decreased as the evaluated region approached the fusion line. The decrease in toughness was apparently caused by the increase in the fraction of coarse-grained zone within HAZ. On the other hand, toughness drop with decreasing test temperature in F.L.(fusion line) ${\~}$F.L.+3mm was larger than that in F.L.+5mm${\~}$F.L.+7mm region due to the fact that in the former regions, retained austenite had poor stability.

• Journal of the Korean Society of Safety
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• v.17 no.2
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• pp.112-117
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• 2002

The effects of shield gas on the structure of methane-air nonpremixed counterflow flames were numerically investigated. The near extinction flame of a low global strain rate 20 $s^{-1}$ of 19% methane diluted by 81% nitrogen by volume and undiluted air was computed. The flame shape, centerline temperature and axial velocity profiles were compared for different velocity of the shield gas and with and without the shield gas. The effects of the velocity of the shield gas were negligible for $V_{S}/V_{F}{\leq}2$ in normal gravity. Under normal gravity conditions, the flame shape and its position with the shield gas were different from those of the flame without the shield gas, whereas no discernible effects of the shield gas along the centerline were observed in zero gravity.

• Journal of the Korean institute of surface engineering
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• v.34 no.5
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• pp.403-408
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• 2001

In this work, the cyclic perfluorinated ether (c-C$_4$F$_{8}$O) with very high destructive removal efficiency (DRE) than other alternative gases, such as $C_3$F$_{8}$, c-C$_4$F$_{8}$ and NF$_3$ was used as an alternative process chemical. The plasma cleaning of silicon nitride using gas mixtures of c-C$_4$F$_{8}$O/O$_2$ and c-C$_4$F$_{8}$O/O$_2$+ $N_2$ was investigated in order to evaluate the effects of adding $N_2$ to c-C$_4$F$_{8}$O/O$_2$ on the global warming effects. Under optimum condition, the emitted net perfluorocompounds (PFCs) during cleaning of silicon nitride were quantified and then the effects of additive $N_2$ by obtaining the destructive removal efficiency (DRE) and the million metric tons of carbon equivalent (MMT-CE) were calculated. DRE and MMTCE were obtained by evaluating the volumetric emission using. Fourier transform-infrared spectroscopy (FT-IR). During the cleaning using c-C$_4$F$_{8}$O/O$_2$+$N_2$, DRE values as high as (equation omitted) 98% were obtained and MMTCE values were reduced by as high as 70% compared to the case of $C_2$F$_{6}$O$_2$. Recombination characteristics were indirectly investigated by combining the measurements of species in the chamber using optical emission spectroscopy (OES), before and after the cleaning, in order to understand any correlation between plasma and emission characteristics as well as cleaning rate of silicon nitride.silicon nitride.

• Asian-Australasian Journal of Animal Sciences
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• v.19 no.11
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• pp.1649-1657
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• 2006

In order to find an alternative source of inoculum to caecal content for studying the fermentation activity of rabbit hindgut, caecal content and faeces of 25 hybrid Hyla rabbits were used as inocula for an in vitro gas production trial. About 1 g of three substrates (dehydrated alfalfa meal, dehydrated beet pulp, barley) was weighed, in quadruplicate per inoculum, in 120 ml bottles; 75 ml of anaerobic medium and 4 ml of reducing solution were added and bottles were placed at $39^{\circ}C$. Caecal content and faeces were diluted respectively 1:2 (CI) and 1:8 (FI) with anaerobic medium and were introduced in the respective bottles (10 ml). Gas production was recorded 20 times at 2-24 h intervals throughout fermentation (96 h). The fermentation characteristics (i.e. degraded organic matter, OMd; potential gas production, A; fermentation rate, Rmax; time at which it is reached, Tmax; pH, volatile fatty acid, VFA) were studied by inoculum and feedstuffs. The feedstuffs, according to their chemical composition, showed very different fermentation characteristics. In particular, OMd, A and Rmax allowed feedstuff classification as follows: barley>beet pulp>alfalfa. The inocula differ (p<0.05) in Tmax, were higher for CI (15.53 vs. 11.96 h) and in VFA production. In particular, CI produced higher levels of acetate (38.9 vs. 33.4 mM/g OM incubated, p<0.01) and isobutyrate (0.72 vs. 0.42, p<0.01) but less propionate (7.1 vs. 10.3, p<0.01) and butyrate (11.3 vs. 14.0, p<0.01). However, the trend of gas production, similar for the inocula according to the fermented substrate, and the good regression equation to estimate some caecal fermentation parameters from faeces suggest that, after standardisation, the faeces could be used as an alternative inoculum for gas tests in rabbit.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.10
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• pp.804-808
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• 1998

The inductively coupled plasma(ICP) etching of platinum with BCl$_3$/Cl$_2$ gas chemistry has been studied. X-ray photoelectron spectroscopy (XPS) was used to investigate the chemical binding states of the etched surface. The plasma characteristics was extracted from optical emission spectroscopy (OES) and a single Langmuir probe. In this case of Pt etching using BCl$_3$/Cl$_2$ gas chemistries, the result of OES and Langmuir probe showed the increase of Cl radicals and ion current densities in the plasmas with increasing Cl$_2$ gas ratio. At the same time, XPS results indicated that the intensities of Pt 4f decreased with increasing Cl$_2$ gas ratio. The decrease of Pt 4f intensities implies the increase of residue layer thickness on the etched Pt surface.

• Journal of the Korean Ceramic Society
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• v.33 no.3
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• pp.299-306
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• 1996

We invesgated the fesibility of thin films deposition by pyrolysis of metalorganic precursors using chemical beam deposition (CBD) process. We attempted to understand the effects of deposition variables such as substrate temperature operating pressure effusion cell temperature and H2 partial pressure on the properties of MgF2 grown by CBD. Mg(tfac)2 was used as a precursor. MgF2 thin films were always grown in an amorphous state and crystallized bypost-annealing. he higher the substrate temperature and the lower the operating pressure the less the impurities I the deposited MgF2 thin films. H2 gas has to be supplied for the pyrolitic reaction of Mg(tfac)2 decomposition. MgF2 films annealed in H2 have lower C impurity than those annealed in O2. But their crysatllinity was independent of annealing atmosphere. The optimum conditions for the prepara-tion of MgF2 films by CBD process were as following : The substrate temperature 55$0^{\circ}C$ the operating pressure 10-4 torr; effusion cell temperature 21$0^{\circ}C$ the percentage of H2 100% Post-annealing in H2 gas was required to remove residual carbon and to form MgF2 crystalline phase.