• Title/Summary/Keyword: F-gas

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A Study on Greenhouse Gas Inventories for Regional Governments (A Case Study of Jeonbuk Province) (지자체 온실가스 인벤토리 구축연구 - 전라북도 사례)

  • Jang, Nam-Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.7
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    • pp.565-572
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    • 2009
  • Greenhouse gas(GHG) inventories and basic strategies for Jeonbuk regional government were established to reduce greenhouse gas emissions. The method to construct GHG inventories of Jeonbuk followed the 'Revised IPCC 1996 Guidelines'which was used for the 'Third National Communication of the Republic of Korea under UNFCCC'. Korean government could use primary energy consumption for the energy industries section in the national GHG inventories. However, regional governments should use secondary energy consumption (included electricity consumption) for the energy industries section for their GHG inventories because they could not control the emission of energy transformation section. In the result of Jeonbuk GHG inventories in 2006, carbon dioxide($CO_2$) emissions from fuel combustion covered 87.1% of total emissions. Methane($CH_4$), carbon dioxide($CO_2$) from other sections, nitrous oxide($N_2O$) and F-gas(HFCs, PFCs, $SF_6$) accounted for 8.1, 2.2, 1.6 and 1.0% of total emissions, respectively. The sectional emission decreased in the order of the energy(88.0%), agriculture(7.6%), waste(2.3%) and industrial processes(2.1%) section. The energy industries section that contained electricity consumption was the most dominant emission source in the energy section. F-gas consumption, rice cultivation and waste incineration were main emission sources in the industrial processes, agriculture and waste section, respectively. In this study, basic directions of each section were established by the results of Jeonbuk GHG inventories in 2006.

Effect of LiF and BaF2 Addition on Synthesis of AlN Powder (AlN 분말합성에 있어서 LiF와 BaF$_2$ 첨가효과)

  • 최병현;이창송;신태수;이종민
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.647-653
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    • 1991
  • In order to synthesize fine AlN powder by the direct nitridation of Aluminum metal power added LiF and BaF2 as additives was heated at 150$0^{\circ}C$ for 3 hrs. in nitrogen gas with flow rate of 20 mι/sec. Additives are promoted the nitridation by prevented the aggromerate of powders when 3% LiF and 2% BaF2 were added to Al metal powder. Rate of nitridation was about 100% and average size of AlN powders were very fine such as 0.3 ${\mu}{\textrm}{m}$. Specific surface area of synthesized AlN powder was 3.95$m^2$/g and also O2 and N2 contents were 2.595% and 33.25%, respectively.

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Electrical Properties of ZnO:Al Transparent Conducting Thin Films for Film-Typed Dye Sensitized Solar Cell

  • Kwak, Dong-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.11
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    • pp.36-43
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    • 2008
  • In this parer aluminium-doped zinc oxide(ZnO:Al) conducting layer was deposited on polyethylene terephthalate(PET) substrate by r. f. magnetron sputtering method. The effects of gas pressure and r. f. sputtering power on the structural and electrical properties of ZnO:Al thin film were investigated experimentally. Especially the effect of position of PET substrate on the electrical properties of the film was studied and fixed to improve the electrical properties and also to increase the deposition rate. The results show that the structural and electrical properties of ZnO:Al thin film were strongly influenced by the gas pressure and sputtering power. The minimum resistivity of $1.1{\times}10^{-3}[{\Omega}-cm]$ was obtained at 5[mTorr] of gas pressure, and 18D[W] of sputtering power. The deposition rate of ZnO:Al film at 5[mTorr] of gas pressure was 248[nm/min]. and is higher by around 3 times compared to that at 25[mTorr].

Comparison of Partial Discharge Characteristics in SF6 Gas Under AC and DC

  • Jo, Hyang-Eun;Wang, Guoming;Kim, Sun-Jae;Kil, Gyung-Suk
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.6
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    • pp.323-327
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    • 2015
  • In this paper, parameters related with partial discharge (PD) were analyzed in SF6 gas under AC and DC voltages. Three electrode systems (protrusion on conductor, protrusion on enclosure, and free particle) were fabricated to simulate PD defects in a gas-insulated switchgear (GIS). All electrode systems were filled with SF6 gas at 0.5 MPa. PD pulses were detected using an oscilloscope and a data acquisition (DAQ) based on IEC 60270. To analyze the PD characteristics under AC and DC voltages, parameters such as discharge inception voltage (DIV), discharge extinction voltage (DEV), pulse magnitude, repetition rate, and T-F map were compared. From the experimental results, PD was revealed to have different characteristics under AC and DC, and these results may be useful for diagnosis of power facilities operated under HVDC.

Repetitive operation characteristics of 500 Hz class excimer laser (500 Hz급 엑시머레이저의 반복동작특성)

  • 박홍진;이주희
    • Korean Journal of Optics and Photonics
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    • v.7 no.3
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    • pp.232-237
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    • 1996
  • A 500 Hz repetition rate excimer laser was developed as light source for pollution lidar. In this paper, the high repetitive output characteristics, the gas flow loop structure, and CR(clearing ratio) characteristics were investigated. Our laser system was constructed compact structure with a streamline gas flow loop and UV preionization. The real gas volume of laser is 10 liter. At 500 Hz repetitive operation, we have obtained average power of 53 watt with KrF laser gas. The variation of laser output, CR, and active volume are $\pm$6.7%, 2.3, and 2.0(H)$\times$1.2(W)$\times$56(L)=134 ㎤, respectively. Laser output power is declined to half at 3$\times$$10^6$ shots.

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Etching Reaction of $UO_2\;with\;CF_4/O_2$ Mixture Gas Plasma

  • Kim, Yongsoo;Jinyoung Min;Kikwang Bae;Myungseung Yang
    • Nuclear Engineering and Technology
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    • v.31 no.2
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    • pp.133-138
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    • 1999
  • Research on the etching reaction of UO$_2$ with CF$_4$/O$_2$gas mixture plasma is carried out. The reaction rates are investigated as a function of CF$_4$/O$_2$ ratio, plasma power, and substrate temperature. It is found that there exists an optimum CF$_4$/O$_2$ ratio around 4:1 at all temperatures up to 37$0^{\circ}C$ and surface analysis using XPS X-ray Photoelectron Spectroscopy) confirms the result. Peak rate at the optimum gas composition increases with increasing temperature. Highest rate obtained in this study leaches 1050 monolayers/min. at 37$0^{\circ}C$ under r. f. power of 150 W, which is equivalent to about 0.5${\mu}{\textrm}{m}$/min. The rate also increases with increasing r. f. power, thus, higher power and higher substrate temperature will undoubtedly raise the etching reaction rate much further. This reaction seems to be an activated process, whose activation energy will be derived in the following experiments.

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Analysis of Trifluoroacetyl group in PVA-polyvinyltrifluoroacetate Copolymer by the Pyrolysis Gas Chromatography (열분해 기체크로마토그래피를 이용한 PVA-polyvinyltrifluoroacetate 공중합체중의 trifluoroacetyl 기의 정량)

  • Chae, Hee-Ju;Jo, Seong-Mu;Lyu, Hark-Soo;Nakajima, Toshinari
    • Journal of the Korean Chemical Society
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    • v.31 no.3
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    • pp.287-291
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    • 1987
  • The composite mole fraction of monomers in PVA-PVFAc copolymer could be calculated from the analysis of trifluoroacetyl group by the pyrolysis gas chromatography without breaking of C-F bonds in polymer. A linearity between trifluoroacetyl peak areas in pyrogram and sample weights was obtained within the range below 3mg. The data of trifluoroacetyl contents derived from gas chromatogram of copolymers with various D.S. were in good agreement with results by the Specific Ionmeter.

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Effect of Oxygen Partial Pressure on the Structural, Optical and Electrical Properties of Sputter-deposited Vanadium Oxide Thin Films (스퍼터링으로 증착된 바나듐 산화막의 구조적, 광학적, 전기적 특성에 미치는 산소 분압의 효과)

  • 최복길;최창규;권광호;김성진;이규대
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.12
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    • pp.1008-1015
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    • 2001
  • Thin films of vanadium oxide(VO$\_$x/) have been deposited by r.f. magnetron sputtering from V$_2$O$\_$5/ target in gas mixture of argon and oxygen. The oxygen/(oxygen+argon) partial pressure ratio is changed from 0% to 8%. Crystal structure, chemical composition, bonding, optical and electrical properties of films sputter-deposited under different oxygen gas pressures are characterized through XPS, AES, RBS, FTIR, optical absorption and electrical conductivity measurements. V$_2$O$\_$5/ and lower oxides co-exist in sputter-deposited films and as the oxygen partial pressure is increased the films become more stoichiometric V$_2$O$\_$5/. The increase of O/V ratio with increasing oxygen gas pressure is attributed to the partial filling of oxygen vacancies through diffusion. It is observed that the oxygen atoms located on the V-O plane of V$_2$O$\_$5/ layer participate more readily in the oxidation process. With increasing oxygen gas pressure indirect and direct optical band gaps are increased, but thermal activation energies are decreased.

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Determination of Free Radicals in Mainstream Cigarette Smoke by Electron Spin Resonance (전자스핀공명에 의한 담배연기 중 자유라디칼 측정)

  • Lee, Jeong-Min;Lee, John-Tae;Park, Jin-Won;Hwang, Keun-Joong
    • Journal of the Korean Society of Tobacco Science
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    • v.29 no.2
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    • pp.146-151
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    • 2007
  • Gas phase and particulate phase radicals in mainstream cigarette smoke were determined Electron Spin Resonance(ESR) spectroscopy. The free radicals in particulate phase have been investigated by benzene extract of Cambridge Filter Pad containing the smoke condensate. Spin trapping method in conjunction with ESR was used to investigate free radicals in the gas phase of cigarette smoke. Several analytical experiments were conducted in order to determine the optimal conditions for maximum signal intensities and reproducibility of results. All the tests were optimized and normalized using the University of Kentucky 2R4F reference cigarette. The optimal conditions were 0.6 mL for analysis volume of ESR, $4{\sim}5\;mL$ for collection volume of spin-adducts, and PBN for quantification of free radicals in gas phase. The radical levels of Kentucky 2R4F cigarettes were found $2.18{\times}10^{14}\;spins/cig.$ and $2.10{\times}10^{15}\;spins/cig.$ in gas phase.

Analysis of the Fatty Acid Composition of Cow's Milk Fat by Gas Liquid Chromatogrohy with Temperature Programming (Gas Liguid Chromatography에 의한 우유의 지방산 조성에 관한 연구)

  • Shin, Jong-Choul;Lee, Jung-Keun;Yoo, Young-Jin;Park, Ke-In
    • Korean Journal of Food Science and Technology
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    • v.4 no.3
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    • pp.213-223
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    • 1972
  • This paper chose the methods of methylesterification of the use of methoxide, the mixture solution of methanol-benzen-sulfuric acid in transesterification of the fat in cow's milk and modified powder milk and separated by gas liquid chromatography with F.F.A.P., D.E.G.A. as liquid phase. Quantitative analysis of the fatty acid of milk fat in cow's milk and modified powder milk was determined by gas liquid chromatography using the method of temperature programming which should be used to obtain satisfactory separation of short chain fatty acid on the chromatogram. It was found that the fatty acid composition of cow's milk and modified powder milk are all the major fatty acid of milk fat obtained by GLC analysis. Main components was found to be from butyric acid to arachidonic acid showing Fig. 3, 4, 5 and Table 4, 5, 6, 7, 8, 9.

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