• 제목/요약/키워드: External Carbon

검색결과 422건 처리시간 0.024초

Kinetic Studies on Physical and Chemical Activation of Phenolic Resin Chars

  • Agarwal, Damyanti;Lal, Darshan;Tripathi, V.S.;Mathur, G.N.
    • Carbon letters
    • /
    • 제4권3호
    • /
    • pp.126-132
    • /
    • 2003
  • Granular Activated Carbon (GAC) has been proven to be an excellent material for many industrial applications. A systematic study has been carried out of the kinetics of physical as well as chemical activation of phenolic resin chars. Physical activation was carried out using $CO_2$ and chemical activation using KOH as activating agent. There are number of factors which influence the rate of activation. The activation temperature and residence time at HTT varied in the range $550{\sim}1000^{\circ}C$ and $\frac{1}{2}{\sim}8$ hrs respectively. Kinetic studies show that the rate of chemical activation is 10 times faster than physical activation even at much lower temperature. Above study show that the chemical activation process is suitable to prepare granular activated carbon with very high surface area i.e.$ 2895\;m^2/g$ in short duration of time i.e. 1 to 2 hrs at lower temperature i.e. $750^{\circ}C$ from phenolic resins.

  • PDF

Electrostatic Beneficiation of Coal Fly Ash Utilizing Triboelectric Charging with Subsequent Electrostatic Separation

  • Lee, Jae-Keun;Kim, Seong-Chan
    • Journal of Mechanical Science and Technology
    • /
    • 제15권6호
    • /
    • pp.804-812
    • /
    • 2001
  • A triboelectrostatic separation system for removing unburned carbon from coal fly ash is designed and evaluated. Fly ash from a coal-fired power plant is used as an accepted additive in concrete where it adds strength, sulfate resistance and reduced cost, provided acceptable levels of unburned carbon are maintained. Unfortunately, unburned carbon in coal fly ash absorbs some of other additives and reduces the concrete strength. This paper describes to investigate dry triboelectrostatic process to separate unburned carbon from coal fly ash and utilize it into economically valuable products. The laboratory-scale triboelectrostatic separation system consists of a particle feeding system, a tribocharger, a separation chamber, and collection systems. Particles of unburned carbon and fly ash can be imparted positive and negative surface charges, respectively, with a copper tribocharger due to differences in the work function values of the particles and the tribocharger, and can be separated by passing them through an external electric field. Results showed that fly ash recovery was strongly dependent on the electric field strength and the particle size. 70wt% of fly ash containing 6.5wt% of carbon contents could be recovered at carbon contents below 3%. The triboelectrostatic separation system showed a potential to be an effective method for removing unburned carbon from coal fly ash.

  • PDF

막결합 연속회분식 반응기를 이용한 농촌마을 하수의 고도처리 (Membrane-Coupled Sequencing Batch Reactor System for the Advanced Treatment of Rural Village Sewage)

  • 김승건;이호원
    • 멤브레인
    • /
    • 제24권1호
    • /
    • pp.20-30
    • /
    • 2014
  • C/N 비가 낮은 농촌마을 하수의 고도처리를 위하여 $0.4{\mu}m$의 세공크기를 갖고 있는 평막이 침지된 연속회분식 반응기를 사용하였다. 분말활성탄의 투입, 폭기량 및 유입 유기물 농도가 처리효율과 여과 성능에 미치는 영향을 조사하였다. 54일 이내의 조업 초기에서는 C/N 비가 증가할수록 COD, T-N 및 T-P의 제거율과 MLSS 농도는 증가하였다. 조업 89일 후의 COD, T-N 및 T-P의 제거율은 각각 97.1%, 75.0% 및 48.3%이었다. 막여과에 의해 처리수에서 SS는 검출되지 않았으며, T-P의 제거율이 낮게 나온 이유는 과잉의 슬러지를 배출하지 않았기 때문이다. 분말활성탄을 투여한 경우 조업이 진행됨에 따라 분말활성탄의 혼합강도와 충돌빈도가 증가하여 슬러지의 입자크기가 감소하였으며, 이로 인해 분말활성탄을 투여하지 않은 경우에 비해 TMP 상승이 크게 나타났다.

API-581에 의한 정량적 위험기반검사에서 스테인리스강의 외부부식에 의한 사고발생 가능성 해석 (- Analysis of Likelihood of Failure for the External Corrosion of Stainless Steel through the Quantitative Risk Based Inspection Using API-581 -)

  • 이헌창;김환주;김태옥
    • 대한안전경영과학회지
    • /
    • 제6권3호
    • /
    • pp.99-107
    • /
    • 2004
  • Likelihood of failure (LOF) for the external corrosion of stainless steel, which affect to a risk of facilities, was analyzed quantitatively through the risk based inspection using API-581 BRD. We found that the technical module subfactor (TMSF) decreased as the inspection number increased and it increased as the inspection effectiveness and the used year increased, and that the TMSF showed high value for the case of the marine/cooling tower drift area as a corrosion driver, In this condition, the LOF for the external corrosion of stainless steel had lower than that for the carbon and low alloy steels

미생물 연료 전지의 반응조 형상에 따른 전기 생산효율 비교 (Comparison of Electricity Generation Efficiencies depending on the Reactor Configurations in Microbial Fuel Cells)

  • 이윤희;어성욱
    • 한국물환경학회지
    • /
    • 제26권4호
    • /
    • pp.681-686
    • /
    • 2010
  • Two different MFC designs were evaluated in batch mode: single compartment combined membrane-electrodes (SCME) design and twin-compartment brush-type anode electrodes (TBE) design (single chamber with two air cathodes and brush anodes at each side of the reactor). In SCME MFC, carbon anode and cathode electrodes were assembled with a proton exchange membrane (PEM). TBE MFC was consisted of brush-type anode and carbon cloth cathode electrodes without the PEM. A brush-type anode was fabricated with carbon fibers and was placed close to the cathode electrode to reduce the internal resistance. Substrates used in this study were glucose, leachate from cattle manure, or sucrose at different concentrations with phosphate buffer solution (PBS) of 200 mM to increase the conductivity thereby reduce the internal resistance. Hydrogen generating bacteria (HGB) were only inoculated in TBE MFC. The peak power densities ($P_{peak}$) produced from the SCME systems fed with glucose and leachate were 18.8 and $28.7mW/m^2$ at external loads of 1000 ohms, respectively. And the $P_{peak}$ produced from TBE MFC were 40.1 and $18.3mW/m^2$ at sucrose concentration of 5 g/L and external loads of 470 ohms, with a mediator (2-hydroxy-1, 4-naphthoquinone) and without the mediator, respectively. The maximum power density ($P_{max}$) produced from mediator present TBE MFC was $115.3mW/m^2$ at 47 ohms of an external resistor.

GPS-X 시뮬레이션을 이용한 2단탈질 공정에서 외부탄소원 적용성 평가 (Evaluation of External Carbon Source on the 2 Stage Denitrification Process by Simulation of GPS-X)

  • 정창화;심유섭;김태형;박철휘
    • 상하수도학회지
    • /
    • 제18권1호
    • /
    • pp.37-48
    • /
    • 2004
  • The purpose of this study was to evaluate adaptability of external carbon source using GPS-X program in pilot plant composed with 2-stage denitrification process. The result from analysis of pilot plant operation and GPS-X simulation showed that effluent concentration could be simulated similarly by modifying operation conditions, such as DO concentration, C/N ratio and other calibrated parameter. In order to satisfy the standard of the effluent water quality on T-N of 20mg/L, it required approximately 3.1 of C/N ratio and 50% of nitrogen removal efficiency when influent T-N is 36.9mg/L. To maintain the stable water quality of the receiving water, the effluent T-N concentration should be less than 10-15mg/L and the appropriate C/N ratio to remove nitrogen was 4.27-6.82. The analysis of sensitivity to kinetic coefficient and reaction constant showed that $Y_H$ and ${\mu}_{mAUT}$ were most sensitive to nitrate and ammonia nitrogen, relatively and sensitivity coefficient of their were 1.32, 1.98. It was concluded that as $Y_H$ decreased and ${\mu}_{mAUT}$ increased, the reaction rates of denitrification and nitrification increased and the removal efficiencies of $NO_3{^-}-N$ and $NH_4{^+}-N$ improved.

탄소섬유 보강판 전용 정착장치를 이용한 외부 프리스트레싱 보강공법 사례연구 (Case study on the external prestressing method strengthened carbon fiber reinforced plates.)

  • 정원용;임공묵
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2003년도 봄 학술발표회 논문집
    • /
    • pp.1003-1006
    • /
    • 2003
  • In recent years, FRP plates have been studied for flexural reinforcement of RC structures due to easy installation and good Quality control. This study presents experimental field test results for the effectiveness of flexural reinforcement of the RC slab using external prestressing with thin CFRP strips made by the pultrusion process. It was demonstrated that flexural strength was considerably increased with relatively easy installation when compared to the other methods used for the composite reinforcement.

  • PDF

이산화탄소 농도에 따른 촉진 탄산화 결과의 신뢰도 평가 (Reliability Evaluation of Accelerated Carbonation Results According to Carbon Dioxide Concentration)

  • 박동천
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2022년도 봄 학술논문 발표대회
    • /
    • pp.166-167
    • /
    • 2022
  • The International Energy Agency(IEA) recommends that intergovernmental agreements reduce CO2 emissions by 2050 to about 50% in 2005 in its report. To realize these demands, it is suggested to actively utilize energy efficiency improvement technology, renewable energy, nuclear power, carbon dioxide capture & storage technology (CCS). In the field of building materials and cement, mineral carbonization technology is widely used. Inorganic by-products applicable to greenhouse gas storage include waste concrete, slag, coal ash, and gypsum. If the Mineral Carbonation Act is used, it is expected that about 12 million tons of greenhouse gases can be immobilized every year. Greenhouse gas immobilization using cement hydrate can be immobilized by injecting carbon dioxide into the hydrated products C-S-H, and Ca(OH)2. In the case of immobilization through concrete carbonization, a carbon dioxide promotion test is used, which is often different from the actual carbon dioxide carbonization reaction. If the external carbon dioxide concentration is abnormally higher than the reality, it is thought that it will be different from the actual reaction. In this study, the carbonation phenomenon according to the concentration and identification of the carbon dioxide reaction mechanism of cement hydrate was to be considered.

  • PDF

Development of Capacitive-type Pressure Mapping Sensor using Printing Technology

  • Lee, Young-Tae
    • 센서학회지
    • /
    • 제26권1호
    • /
    • pp.24-27
    • /
    • 2017
  • In this study, I developed a simple and low cost process-printing a silver, carbon, dielectric, adhesive layer on PET films using screen printing technology and bonding the two films face-to-face-to fabricate a low price capacitive pressure-mapping sensor. Both electrodes forming the pressure measuring capacitor are arranged between the two PET films similar to a sandwich. Therefore, the sensor has the advantage of minimizing the influence of external noise. In this study, a $10{\times}10$ capacitance-type pressure-mapping sensor was fabricated and its characteristics were analyzed.