• 한국세라믹학회지
• /
• 제17권3호
• /
• pp.133-140
• /
• 1980

Nonohmic properties of ZnO ceramics with various small amounts of additives were studied in relation to sintering temperature and additive content. The kinds of additives used were basic additives ($Bi_2O_3$, $BaCO_3$, $MnCO_3$, $Cr_2O_3$) and $KNO_3$ Especially this study has focused on the effects of $KNO_3$ in ZnO ceramics with basic additives. SEM studies indicated that microstructures of ZnO, $KNO_3$ and basic additives showed homogenuous grain size in comparison to ZnO and basic additives compounds. The nonohmic exponent ($\alpha$) in ZnO, $KNO_3$ and basic additives component were measured as high as 40.

• 한국재료학회지
• /
• 제16권7호
• /
• pp.416-421
• /
• 2006

The varistor properties of ZPCCL-based ceramics were investigated at different $La_2O_3$ contents in the range of $0{\sim}2.0$ mol%. As $La_2O_3$ content increased, the ceramic density greatly increased in the range of $4.71{\sim}5.77\;g/cm^3$ and the varistor voltage greatly decreased in the range of $503.5{\sim}9.4$ V. The varistor with 0.5 mol% $La_2O_3$ exhibited good nonlinearity, in which the nonlinear exponent is 81.6 and the leakage current is 0.2 ${\mu}A$. Furthermore, the varistors exhibited the high electrical stability, with $%{\Delta}V_{1mA}=-1.1%,%{\Delta}{\alpha}=-3.7%$, and $%{\Delta}I_L=+100%$ for DC accelerated aging stress condition of 0.95 $V_{1mA}/150^{\circ}C/24$ h.

• 한국자기학회지
• /
• 제5권5호
• /
• pp.511-514
• /
• 1995

The crystallization kinetics of $Fe_{73.5}Si_{13.5}B_{9}Cu_{1}Nb_{3}$ amorphous alloy has been investigated using differential scanning calorimetry (DSC). The crystallization process had two stages, i.e. precipitation of the $\alpha$-Fe(Si) solid solution and the tetragonal borides. The isothermal transformation data of the amorphous alloy has been fitted successfully to the generalized Johnson-Mehl-Avrami equation. The mean time exponent, n, obtained is close to 2.5. The value of n=2.5 may be interpreted as being due to a diffusion-controlled transformation process with a constant nucleation rate, one likely transformation mode for the crystallization of metallic amorphous alloys. The activation energy of the overall crystallization process deduced from the time to 50% crystallization are about 81 kcal/mole. The value is of the same order as those estimated from viscous flow.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
• /
• pp.625-628
• /
• 2002

The electrical properties of the praseodymium-based ZnO varistor ceramics, which are composed of Zn-Pr-Co-Cr-Dy oxides were investigated with $Dy_2O_3$ amount. The average grain size of varistor ceramics was greatly decreased from 18.2 to 4.6 pm with increasing $Dy_2O_3$ amount. The calculated nonlinear exponent$({\alpha})$ in varistor ceramics without $DY_2O_3$ was only 4.9, whereas the a value of the varistors with $DY_2O_3$ was abruptly increased in the range of 48.8 to 58.6. In particular, the maximum value of a was obtained by doping of 1.0 mol% $DY_2O_3$, reaching 58.6. The measured leakage current$(I_l)$ value in varistors without $DY_2O_3$ was $85.45{\mu}A$, whereas the $I_{\ell}$ value of the varistors with $DY_2O_3$ was very abruptly decreased in the range of 1.10 to $0.12{\mu}A$. In particular, the minimum value of $I_{\ell}$ was obtained by doping of 0.5 mol% $DY_2O_3$, reaching $0.12{\mu}A$. The tan $\delta$ varied in V-shape, with minimum 2.28% at 0.5 mol% $DY_2O_3$. The donor concentration and the density of interface states were decreased in the range of $(4.66{\sim}0.25){\times}10^{18}cm^3$ and $(5.70{\sim}1.39){\times}10^{12}/cm^2$, respectively, as $DY_2O_3$ amount is increased.

• 생물정신의학
• /
• 제16권2호
• /
• pp.69-75
• /
• 2009

Objectives : The detrended fluctuation analysis is one of the nonlinear methods for the investigation of biological time series. It quantifies the fractal scaling properties and is known to be useful in the evaluation of long-range correlations in time series. The heart rate variability(HRV) of obstructive sleep apnea syndrome (OSAS) patients during nighttime was analyzed by detrended fluctuation analysis to assess its relationship with the severity of the symptoms. Methods : Fifty nine untreated male OSAS patients with moderate to severe symptoms(mean age=45.4${\pm}$11.7 years, apnea-hypopnea index, AHI${\geq}$15) underwent nocturnal polysomnography. Moderate(AHI=15-30, N=22) and severe(AHI>30, N=37) OSAS patients were compared for the indices derived from detrended fluctuation analysis and frequency domain analysis of HRV. Results : In the detrended fluctuation analysis, the alpha values were 0.75${\pm}$0.11 and 0.82${\pm}$0.07 for the severe and the moderate OSAS groups respectively. The difference was significant(p<.01). The alpha value had negative correlation with AHI(r=-.425, p=.001). Negative correlation coefficients were also found in the relationships between the alpha values and very low frequency(VLF)(r=-.425, p=.001), low frequency(LF)(r=-.633, p= <.001) and the LF/HF ratio(r=-.305, p=.019) respectively. LF/HF ratio(p=.005) was higher in the severe OSAS group compared to that of the moderate OSAS group. Conclusion : In this study, the detrended fluctuation analysis showed the significant difference between the two OSAS groups classified according to their severity of symptoms. The scaling exponent showed the negative correlation with AHI and indicies of frequency domain analysis. This result suggests that detrended fluctuation analysis can be helpful to estimate the severity of OSAS.

• Bulletin of the Korean Chemical Society
• /
• 제19권6호
• /
• pp.661-666
• /
• 1998

Active reaction sites and electrochemical O2 reduction kinetics on La_{1-x}Sr_xMnO_{3+{\delta}} (x=0.1-0.4)/YSZ (yttria-stabilized zirconia) electrodes are investigated in the temperature range of 700-900 ℃ at $Po_2=10^{-3}$-0.21 atm. Results of the steady-state polarization measurements, which are formulated into the Butler-Volmer formalism to extract transfer coefficient values, lead us to conclude that the two-electron charge transfer step to atomically adsorbed oxygen is rate-limiting. The same conclusion is drawn from the $Po_2$-dependent ac impedance measurements, where the exponent m in the relationship of $I_o$ (exchange current density) ∝ $P_{o_{2}}^m$ is analyzed. Chemical analysis is performed on the quenched Mn perovskites to estimate their oxygen stoichiometry factors (δ) at the operating temperature (700-900 ℃). Here, the observed δ turns out to become smaller as both the Sr-doping contents (x) and the measured temperature increase. A comparison between the 8 values and cathodic activity of Mn perovskites reveals that the cathodic transfer coefficients $({\alpha}_c)$ for oxygen reduction reaction are inversely proportional to δ whereas the anodic ones $({\alpha}_a)$ show the opposite trend, reflecting that the surface oxygen vacancies on Mn perovskites actively participate in the $O_2$ reduction reaction. Among the samples of x= 0.1-0.4, the manganite with x=0.4 exhibits the smallest 8 value (even negative), and consistently this electrode shows the highest ${\alpha}_c$ and the best cathodic activity for the oxygen reduction reaction.

• 암석학회지
• /
• 제26권1호
• /
• pp.45-54
• /
• 2017

미세균열의 길이와 간격의 분포를 이용하여 쥬라기 거창화강암에서 발달하는 결의 특성을 분석하였다. 상기 길이와 간격에 대한 분포상은 박편의 확대사진(${\times}6.7$)에서 도출하였다. 일차적으로, 여섯 방향의 결에 대한 길이 및 간격-누적빈도 도표를 미세균열의 길이의 밀도가 증가하는 순(($H2{\rightarrow}R1$)으로 배열하였다. 상기 두 종류의 도표의 결합을 통하여 다양한 파라미터를 추출하였다. 3개 채석면 및 3개 결을 대변하는 판별요소들은 파라미터의 값 사이의 상호 대비를 통하여 획득하였다. 이 연구의 분석 결과를 요약하면 다음과 같다. 여섯 방향의 결에 대한 평가는 간격(${\alpha}$, ${\lambda}_S$) 및 길이(${\beta}$, ${\lambda}_L$)와 관련된 두 지수 직선 사이의 (1) 교차각(${\alpha}-{\beta}$) 및 (2) 지수차(${\lambda}_S-{\lambda}_L$)과 같은 파라미터를 이용하여 수행하였다. 파라미터(1 및 2)의 값은 H(3번 결, (H1 + H2)/2) < G(2번 결, (G1 + G2)/2) < R(1번 결, (R1 + R2)/2)의 순서이다. 반면에 3개 면에 대한 상기 2개 파라미터의 값은 R < G < H의 순서이다. 한편, 두 지수 직선 사이의 수렴방향을 도출하였다. 상기 방향은 선 ol을 중심으로 하여 선 os'의 배치에 따른다. 선 ol이 좌측의 상부 영역 그리고 선 os'가 우측의 하부영역에 위치하는 경우, 상기 두 지수 직선은 Y축의 방향으로 수렴한다(R-유형). 반면에, 선 ol 및 선 os'의 배열순이 역전되었을 때에는 상기 두 선은 X축의 방향으로 수렴한다(H-유형). 특히, 두 수직선의 배열에 의하여 교차각(${\alpha}-{\beta}$)의 양(+) 혹은 음(-)의 값이 결정된다. 이러한 유형의 상관성 분석은 결의 상대적인 강도 평가 및 3개 채석면의 판별에 유용하다.

• 한국토양비료학회지
• /
• 제28권3호
• /
• pp.218-226
• /
• 1995

복숭아 묘목으로 부터 채취한 근권 및 그 주변 토양을 이용하여 $NH_4-K$와 $NH_4-Ca$ 치환 현상을 조사하였으며 이 결과를 토양중 암모니움 등 양이온의 이동과 분포의 모델화에 적용할 수 있는 치환식을 찾고자 했다. 토양시료를 $NH_4Cl$, KCl과 $CaCl_2$ 용액으로 평형에 도달시킨 후 $Sr(NO_3)_2$ 용액으로 추출하여 평형상태에서의 치환태 양이온 조성을 구하였다. Vanselow, Gapon 그리고 kerr의 식은 $NH_4-K$와 $NH_4-Ca$ 치환 현상을 적절히 기술할 수 없었으나 치환태 양이온 농도에 임의의 지수를 갖는 다음과 같은 경험식이 매우 적절한 것으로 나타났다. ${\frac{\alpha_i^m}{a_j^n}}=K{\frac{(iX)^{mPi}}{(jX)^{nPj}}}$ 이 식에서 ${\alpha}i$와 ${\alpha}j$는 원자가가 m과 n인 양이온 i 및 j의 용액 중 activity이며(iX)와 (jX)는 치환태양이온 i와 j의 농도이다. 치환태 양이온의 농도 단위로는 몰 분율 또는 당량 분율을 사용할 수 있다. 임의상수 $P_i$와 $P_j$ 그리고 분배상수 K는 이 식의 대수형을 이용하여 다중 회귀 방법으로 구할 수 있다.

• 동력기계공학회지
• /
• 제4권1호
• /
• pp.81-87
• /
• 2000

In this study, CT specimens were prepared from ASTM SA516 Gr. 70 which was used for pressure vessel plates for room and low temperature service. And we got the following characteristics from fatigue crack growth test carried out in the environment of room and low temperature at $25^{\circ}C,\;-60^{\circ}C,\;-80^{\circ}C\;and\;-100^{\circ}C$ and in the range of stress ratio of 0.05 by means of opening mode displacement. At the constant stress ratio, the threshold stress intensity factor range ${\Delta}K_{th}$ in the early stage of fatigue crack growth (Region I) and stress intensity factor range ${\Delta}K$ in the stable of fatigue crack growth (Region II) was increased in proportion to descend temperature. It assumed that the fatigue resistance characteristics and fracture strength at low temperature is considerable higher than that of room temperature in the early stage and stable of fatigue crack growth region. The straight line slope relation of logarithm $d{\alpha}/dN\;-{\Delta}K$ in Region II, that is, the fatigue crack growth exponent m increased with descending temperature at the constant stress ratio. It assumed that the fatigue crack growth rate $d{\alpha}/dN$ is rapid in proportion to descend temperature in Region II and the cryogenic-brittleness greatly affect a material with decreasing temperature.

• 정보보호학회논문지
• /
• 제27권6호
• /
• pp.1295-1305
• /
• 2017

국내 블록암호표준(안)으로는 SEED암호가 있다. 이 암호는 한국정보보호진흥원(KISA)이 1998년 10월에 초안을 설계하고 같은 해 12월에 공개검증과정을 거쳐 안전성과 성능이 개선된 최종 수정안을 발표하였다. DES와는 달리 128비트 블록암호로서 여러 과정을 거쳐 2005년에 국제표준으로 확정되었다. DES와 같은 페이스텔 구조를 가진 블록암호로서 다만 입력비트블록이 DES의 두 배인 128비트로 늘어났다는 것이다. 본 논문에서는 첫째, SEED 암호의 일반적인 알고리즘을 소개하고 F-함수에서 적용되는 열쇠 값의 생성원리를 수학적으로 분석해 보았다. 둘째, S-함수의 8비트 입력 값에 대응되는 원시원소 ${\alpha}$ 의 멱승 값을 계산하는 표를 도출해 보았으며 마지막으로 G-함수 내에 설계되어져 있는 S-함수의 계산 원리를 수학적인 방법으로 새로운 정리와 예제를 통해 분석해 보는 것으로 한정하였다. 이러한 과정을 통하여 현재 알려져 있는 SEED암호의 취약점을 보완할 수 있는 새로운 암호체계를 개발하는데 필요한 아이디어와 이론적인 근거를 제공하는 데 어느 정도 도움이 되고자 한다.