• Title/Summary/Keyword: Expanded Uncertainty

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Measurement of Cortisol in Human Serum by Isotope Dilution Liquid Chromatography/Mass Spectrometry and a Comparison through a Proficiency Testing

  • Lee, Hwa-Shim;Shin, Hye-Sun;Park, Sang-Ryoul;Park, Chang-Joon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1149-1154
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    • 2010
  • Liquid chromatography/mass spectrometry using isotope dilution method has been established as a primary method for the measurement of cortisol in human serum. Verification of this method was accomplished by the participation in Consultative Committee for Amount of Substance-Metrology in Chemistry (CCQM) pilot study. Two levels of cortisol certified reference materials were prepared and certified by the established method. They were used as sample materials for the proficiency testing. The expanded uncertainty in the measurement of cortisol in human serum was approximately 1.2% at 95% confidence level. The results of the proficiency testing showed a good precision among the participants, but some bias to the certified values. This means that commercial field laboratories should keep traceability chain to SI unit through available reference measurement procedures and/or available reference materials.

Analysis of Trace Impurities in The Bulk $H_2$ and He Gases by a Cold Concentration Method (저온 농축법에 의한 수소와 헬륨 중의 미량가스 분석)

  • Lee, Taeck Hong;Park, Doo Seon;Son, Moo Ryong
    • Journal of the Korean Chemical Society
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    • v.42 no.5
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    • pp.526-530
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    • 1998
  • Analysis of trace impurities in the gases has been very important with the development of semi-conductor related industry. Particularly, the contamination of the gas handling systems in a semi-conductor plant by the air has been a trouble to the manufacturers. Thus, the analysis of the air components in the system has been a task to the analysts. In this study, we report the analysis data with a expanded uncertainty for the trace impurities of nitrogen and argon in the bulk helium and hydrogen. All data show a good correspondence, exhibiting reliable statistical error ranges.

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A study of how Supply Chain companies correspond to water risk resulted from climate change (기후변화에 따른 기업 공급체인의 물 리스크 대응 실태 조사)

  • Park, Jiyoung;Park, Seogha;Lim, Byungsun;Kim, Chesoong
    • Journal of the Korea Safety Management & Science
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    • v.17 no.1
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    • pp.149-168
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    • 2015
  • It is expected that the temperature in Pyeongyang will be similar to that ($16.6^{\circ}C$) in Seogwipo in the late 21st century, and most of South Korea will enter the subtropical climate due to climate change. Change in the precipitation pattern like the range of fluctuation caused by climate change will lead to expanded uncertainty in securing reliable water supply, along with a serious impact on demands for living and industrial water due to change in the volume and period of river outflow. As industrial water for production activities is estimated based on the contract quantity, it is difficult to apply rationalization of water usage and incentives in water recycling. Therefore many companies are making efforts in complying with the effluent standard while spending few resources on such rationalization and recycling. This study researched water risk management over 115 Korean companies by 28 questions in 4 categories. Through the research, this study aims to understand water risk management levels and seek response plans.

Optical Disk Drive Servo System Using Dual Disturbance Observer

  • Lee, Sang-Han;Jeong, Dong-Seul;Chung, Chung-Choo
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.2087-2092
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    • 2005
  • Using disturbance observer (DOB) is effective in enhancing the performance of dynamic system in the presence of disturbances. Recently the definition of disturbance has been expanded to modeling uncertainty including parameter variation, internal disturbance. Various structures of DOB have been proposed to improve sensitivity of system for better disturbance rejection performance. However in the case of improvement of sensitivity function, it tends to bring poor transient response due to cross-coupling and phase lag. Furthermore it could be very sensitive to measurement noise due to increased peak of complementary sensitivity function. In this paper, a dual disturbance observer (Dual-DOB) is proposed to reduce the effect of such cross-coupling. It is possible for us to improve the sensitivity function with additional external DOB with hardly affecting complementary sensitivity function. Thus it is able to have robustness against measurement noise. Since we are able to design DOBs of internal and external loop independently, we could prevent transient response quality from degrading while improving the sensitivity function. The proposed Dual-DOB is applied to a commercial optical disk drive tracking servo system. The experimental result shows that the Dual-DOB is an effective method in rejecting the disturbance as well as improving the tracking performance.

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Absolute Evaluation Method to Obtain Ratio Error and Phase Displacement of Current Transformers (전류변성기의 비오차와 위상오차의 절대 평가 기술)

  • Kim, Yoon-Hyoung;Jung, Jae-Kap;Han, Sang-Gil;Koo, Kyung-Wan;Han, Sang-Ok
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.57 no.2
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    • pp.153-159
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    • 2008
  • We have developed an absolute evaluation method to obtain the ratio error and phase displacement of a current transformer (CT) without any precise standard CT by measuring four parameters in a CT equivalent circuit. The excitation admittance in the CT equivalent circuit can be obtained by employing standard resistors with negligible reactive component. The secondary leakage impedance in the CT equivalent circuit can be measured using a universal impedance bridge. The method was applied to CTs under test with the wide current ratios in the range of 5 A / 5 A - 5,000 A / 5 A and 5 A / 1 A - 5,000 A / 1 A. The ratio error and phase displacement of the CT under test obtained in this study are consistent with those measured at the national institute in Canada using the same CT under test within an expanded uncertainty (k = 2) in the overall current ratios.

Development of AC magnetic field standard system and analysis of the international key comparison (교류 자기장 표준장치 개발 및 국제비교 결과 분석)

  • Park, Po-Gyu;Kim, Young-Gyun;Kim, Wan-Seop;Kim, Mun-Seok
    • Proceedings of the KIEE Conference
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    • 2009.04b
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    • pp.3-5
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    • 2009
  • 교류 자기장의 정밀측정, 자기장 측정기의교정 및 관련 시험 등 을 지원하기 위해 교류자기장 표준장치를 개발하였다. 주파수에 따른 확장분확도(expanded uncertainty, 2 $\sigma$)는 1 MBz 이하에서 0.16 %, 1 kHz $\sim$ 5 kHz 에서 0.26 %, 5 kHz $\sim$ 20 kHz에서 0.44 % 이었다. 측정결과에 대한 국제적 신뢰성 및 상호인증을 확보하기 위하여 핵심측정표준 국제비교(international key comparison)에 참여하였으며, 또한 측정능력, 교정 및 시험방법 등에 대한 국제적 전문가로부터 평가(peer review)를 수감하였다. 따라서 한국표준과학연구원 (KRISS)에서 교정 및 측정한 결과에 대해서는 국제적 상호인증을 받을 수 있다.

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Development of primary reference gas mixtures of 18 volatile organic compounds in hazardous air pollutants (5 nmol/mol level) and their analytical methods

  • Kang, Ji Hwan;Kim, Yong Doo;Lee, Jinhong;Lee, Sangil
    • Analytical Science and Technology
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    • v.34 no.5
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    • pp.202-211
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    • 2021
  • Volatile organic compounds (VOCs) in hazardous air pollutants (HAPs) have been regulated by the Air Pollution Control Act (1978) and their atmospheric concentrations have been monitored in 39 monitor sites in Korea. However, measurement standards of volatile organic compounds (VOCs) in HAPs at ambient levels have not been established in Korea. Primary reference gas mixtures (measurement standards) at ambient levels are required for accurately monitoring atmospheric VOCs in HAPs and managing their emissions. In this study, primary reference gas mixtures (PRMs) at 5 nmol/mol were developed in order to establish primary national standards of VOCs in HAPs at ambient levels. Primary reference gas mixtures (PRMs) were prepared in pressurized aluminum cylinders with special internal surface treatment using gravimetric method. Analytical methods using gas chromatography-flame ionization detector (GC-FID) coupled with a cryogenic preconcentrator were also developed to verify the consistency of gravimetrically prepared HAP VOCs PRMs. Three different columns installed in the GC-FID were evaluated and compared for the retention times and separation of eighteen target components in a chromatogram. Results show that the HAP VOCs PRMs at 5 nmol/mol were consistent within a relative expanded uncertainty (k=2) of less than 3 % except acrylonitrile (less than 6 %) and the 18 VOCs were stable for 1 year within their associated uncertainties.

Risk-based Operational Planning and Scheduling Model for an Emergency Medical Center (응급의료센터를 위한 위험기반 운영계획 모델)

  • Lee, Mi Lim;Lee, Jinpyo;Park, Minjae
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.42 no.2
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    • pp.9-17
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    • 2019
  • In order to deal with high uncertainty and variability in emergency medical centers, many researchers have developed various models for their operational planning and scheduling. However, most of the models just provide static plans without any risk measures as their results, and thus the users often lose the opportunity to analyze how much risk the patients have, whether the plan is still implementable or how the plan should be changed when an unexpected event happens. In this study, we construct a simulation model combined with a risk-based planning and scheduling module designed by Simio LLC. In addition to static schedules, it provides possibility of treatment delay for each patient as a risk measure, and updates the schedule to avoid the risk when it is needed. By using the simulation model, the users can experiment various scenarios in operations quickly, and also can make a decision not based on their past experience or intuition but based on scientific estimation of risks even in urgent situations. An example of such an operational decision making process is demonstrated for a real mid-size emergency medical center located in Seoul, Republic of Korea. The model is designed for temporal short-term planning especially, but it can be expanded for long-term planning also with some appropriate adjustments.

The Economic Cooperation Potential of East Asia's RCEP Agreement

  • Armstrong, Shiro;Drysdale, Peter
    • East Asian Economic Review
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    • v.26 no.1
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    • pp.3-25
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    • 2022
  • East Asia's Regional Comprehensive Economic Partnership (RCEP) came into force in 2022 as the world's largest free trade agreement. RCEP was concluded, signed and brought into force in the face of major international uncertainty and is a significant boost to the global trading system. RCEP brings Australia, China, Japan, South Korea and New Zealand into the same agreement with the ten member ASEAN group at its centre. It keeps markets open and updates trade and investment rules in East Asia, a major centre of global economic activity, at a time of rising protectionism when the WTO itself is under threat. The agreement builds on ASEAN's free trade agreements and strengthens ASEAN centrality. One of the pillars of RCEP is an economic cooperation agenda which has its antecedents in ASEAN's approach to bringing along its least developed members and builds on the experience of capacity building in APEC and technical cooperation under the ASEAN Australia-New Zealand Free Trade Agreement. There is an opportunity to create a framework that facilitates deeper economic cooperation that involves experience-sharing, extending RCEP's rules and membership at the same time as strengthening political cooperation. The paper suggests some areas that might be best suited to cooperation - that is confidence and trust building instead of or before negotiation - and discusses how non-members may be engaged and the membership expanded. Options such as multilateralising provisions and becoming a platform for policy convergence and coordinating unilateral reforms are canvassed.

Deep neural network for prediction of time-history seismic response of bridges

  • An, Hyojoon;Lee, Jong-Han
    • Structural Engineering and Mechanics
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    • v.83 no.3
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    • pp.401-413
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    • 2022
  • The collapse of civil infrastructure due to natural disasters results in financial losses and many casualties. In particular, the recent increase in earthquake activities has highlighted on the importance of assessing the seismic performance and predicting the seismic risk of a structure. However, the nonlinear behavior of a structure and the uncertainty in ground motion complicate the accurate seismic response prediction of a structure. Artificial intelligence can overcome these limitations to reasonably predict the nonlinear behavior of structures. In this study, a deep learning-based algorithm was developed to estimate the time-history seismic response of bridge structures. The proposed deep neural network was trained using structural and ground motion parameters. The performance of the seismic response prediction algorithm showed the similar phase and magnitude to those of the time-history analysis in a single-degree-of-freedom system that exhibits nonlinear behavior as a main structural element. Then, the proposed algorithm was expanded to predict the seismic response and fragility prediction of a bridge system. The proposed deep neural network reasonably predicted the nonlinear seismic behavior of piers and bearings for approximately 93% and 87% of the test dataset, respectively. The results of the study also demonstrated that the proposed algorithm can be utilized to assess the seismic fragility of bridge components and system.