• Journal of Photoscience
• /
• v.2 no.2
• /
• pp.73-76
• /
• 1995

The photohydration of 1-(m-nitrophenyl)-5, 5-dimethyl-1, 3-hexadiyne (m-NDHD) affords allenyl ketone compound (1) via triplet excited state which is converted into $\beta$-dicarbonyl compound (2) through thermal hydration. The allenyl ketone is formed by the synchronous addition of water with protonation at C$_1$ indicating that m-NDHD has the reverse polarization and greater electron withdrawing effect in the triplet excited state in comparison with p-NDHD.

• Journal of Photoscience
• /
• v.9 no.2
• /
• pp.359-361
• /
• 2002

A green mutant of Rhodobacter sphaeroides 60I was acquired by chemical induction. The blue-shifted of the carotenoid absorption was found in the Light-harvesting complex II (LH2) of the mutant. With the excitation at different wavelength, we observed that the evolution of excited-state dynamics in LH2 of Rhodobacter sphaeroides 60I. The dynamical traces demonstrate a dominant absorption followed concomitantly by an ultrafast transmission increase and decay with 818nm excitation.

• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.35-36
• /
• 2006

Excited-state intramolecular proton transfer (ESIPT) is a phototautomerization occurring in the excited states of the molecules possessing a cyclic intramolecular or solvent-bridged hydrogen bond. Recently, we have developed novel ESIPT chromophores, molecules, dendrimers and polymers which show very high fluorescence quantum efficiency combined with the characteristic features of optical switching, fluorescence patterining, lasing, and electroluminescence. Broad overview of these topics will be given in this talk.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.2
• /
• pp.465-469
• /
• 2013

Proton transfer reaction is one of the most fundamental processes in chemistry and life science. Excited state intramolecular proton transfer (ESIPT) has been studied as a model system of the proton transfer, since it can be conveniently initiated by light. We report ESIPT reaction dynamic of 1-hydroxy-anthraquione (1-HAQ) in solution by highly time-resolved fluorescence. ESIPT time of 1-HAQ is determined to be $45{\pm}10$ fs directly from decay of the reactant fluorescence and rise of the product fluorescence. High time resolution allows observation of the coherent vibrational wave packet motion in the excited state of the reaction product tautomer. The coherently excited vibrational mode involves large displacement of the atoms, which shortens the distance between the proton donor and the acceptor. With the theoretical analysis, we propose that the ESIPT of 1-HAQ proceeds barrierlessly with assistance of the skeletal vibration, which in turn becomes excited coherently by the ESIPT reaction.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.9
• /
• pp.1241-1242
• /
• 2003

• Bulletin of the Korean Chemical Society
• /
• v.32 no.spc8
• /
• pp.3090-3093
• /
• 2011

Curcumin is a natural product with antioxidant, anti-inflammatory, antiviral and antifungal functions. As it is known that the excited state intramolecular hydrogen transfer of curcumin are related to its medicinal antioxidant mechanism, we investigated its excited state dynamics by using femtosecond transient absorption spectroscopy in an effort to understand the molecule's therapeutic effect in terms of its photophysics and photochemistry. We found that stronger intermolecular hydrogen bonding with solvents weakens the intramolecular hydrogen bonding and decelerates the dynamical process of the enolic hydrogen. Exceptions are found in methanol and ethylene glycol due to their nature as simultaneous hydrogen bonding donor-acceptor and high viscosity solvent, respectively.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.4 no.1
• /
• pp.93-101
• /
• 2000

In a gas-turbine engine, fan blades in flow path are confronted with many kinds of loading. The study of the excited force by the wake of struts has proposed and the possibility of fatigue failure about rotating fan blades by the excited force at the steady state is evaluated. Equations of the excited force of wakes has been derived at the steady state and the maximum pressure distributions measured at the transient state are proposed. Dynamic characteristics and the fatigue strength of fan blades by experimental test were obtained. To evaluate HCF(High Cycle Fatigue) damage of fan blades, FEM analysis was performed with a steady state harmonic response, which was followed by high cycle fatigue damage factor from goodman diagram.

• Bulletin of the Korean Chemical Society
• /
• v.17 no.8
• /
• pp.745-749
• /
• 1996

Fluorescence from the electronically excited thiophosgene (Cl2CS) in its first excited singlet state (S1) is efficiently quenched by collision. Rates of the collision-induced electronic relaxation were obtained for various vibrational levels in the S1 state by measuring the fluorescence lifetimes. We found that the relaxation process is strongly energy-dependent; the rate consistently increases by a factor of ~40 with the increase of vibrational energy from 0 to 1450 cm-1. Collision-induced intersystem crossing from the S1 to the first triplet state (T1) is attributed to the major process responsible for the electronic relaxation.

• Bulletin of the Korean Chemical Society
• /
• v.16 no.11
• /
• pp.1043-1045
• /
• 1995

The overtone of the ν2 vibrational mode in Cr(CO)6 are observed for the first time in cyclohexane and methanol at both the 266 and 213 nm excitations. The appearance of the overtones due to the displacement of the electronic excited state with respect to the ground state along the ν2 vibrational mode is interpreted in terms of wavepacket concept and molecular orbital (MO) theory. Our Raman results suggest a new interpretation for the excited state potential.

• Transactions on Electrical and Electronic Materials
• /
• v.18 no.5
• /
• pp.265-272
• /
• 2017

This paper presents the dynamic modeling, analysis, and control of an AC/DC/AC-assisted, self-excited induction generator connected to the grid. The dynamic model includes wind turbine models with pitch control, gear boxes, self-excited induction generators, excitation capacitance, inductive load models, controlled six-pulse rectifiers, and novel state-space models of a grid-connected inverter. The system has been simulated to verify its capabilities of buildup voltage, stator flux response, stator phase current, electromagnetic torque, and magnetizing inductance variation during both the dynamic and steady states with a variable-speed prime mover. The complete setup of the above dynamic models was simulated using MATLAB/SIMULINK.