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Fluorescence Properties of Size Fractions of Dissolved Organic Matter Originated From Different Sources (생성 기원에 따른 용존 자연유기물질 분자량별 형광특성 비교)

  • Hur, Jin;Park, Min-Hye
    • Journal of Korean Society on Water Environment
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    • v.23 no.4
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    • pp.482-489
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    • 2007
  • Fluorescence properties and carbohydrate content were investigated using ultrafiltrated size fractions of dissolved organic matters (DOM) originated from different sources. The materials included a treated sewage, an algal organic matter, and a soil leachate, all of which are major constituents of dissolved organic matter in a typical urban river. Four different size fractions were separated from the three sources of each DOM. The size distribution demonstrated that a higher molecular weight fraction was more present in soil leachate compared to two other source DOMs. A higher content of carbohydrates was observed in the following order - algal DOM > treated sewage > soil leachate. A wide range of specific UV absorbance was observed from size fractions of a single source DOM, indicating that aromatic carbon structures are heterogeneously distributed within one source of DOM. The structural heterogeneity was the most pronounced for the soil leachate. The fluorescence index ($F_{450}/F_{500}$) of the treated sewage was similar to that (2.0) typically obtained from autochthonous DOM, suggesting that the treated sewage exhibited autochthonous organic matter-like properties. No protein-like fluorescence intensities were observed for all of the soil leachate size fractions whereas they were observed with two other source DOMs. Based upon the fluorescence peak ratios from fluorescence excitation-emission matrix (EEM), two discrimination indices could be suggested to distinguish three different source DOMs. It is expected that the suggested discrimination indices will be useful to predict the sources of DOM in a typical urban river affected by treated sewage.

Effect of the Crystalline Phase of Al2O3 Nanoparticle on the Luminescence Properties of YAGG:Ce3+ Phosphor under Vacuum UV Excitation (진공자외선 여기에 의한 YAGG:Ce3+ 형광체의 광발광 특성에 미치는 Al2O3 나노입자 원료의 결정상의 영향)

  • Wu, Mi-Hye;Choi, Sung-Ho;Jung, Ha-Kyun
    • Korean Journal of Materials Research
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    • v.22 no.4
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    • pp.195-201
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    • 2012
  • $Ce^{3+}$-doped yttrium aluminum gallium garnet (YAGG:$Ce^{3+}$), which is a green-emitting phosphor, was synthesized by solid state reaction using ${\alpha}$-phase or ${\gamma}$-phase of nano-sized $Al_2O_3$ as the Al source. The processing conditions and the chemical composition of phosphor for the maximum emission intensity were optimized on the basis of emission intensity under vacuum UV excitation. The optimum heating temperature for phosphor preparation was $1550^{\circ}C$. Photoluminescence properties of the synthesized phosphor were investigated in detail. From the excitation and emission spectra, it was confirmed that the YAGG:$Ce^{3+}$ phosphors effectively absorb the vacuum UV of 120-200 nm and emit green light positioned around 530 nm. The crystalline phase of the alumina nanoparticles affected the particle size and the luminescence property of the synthesized phosphors. Nano-sized ${\gamma}-Al_2O_3$ was more effective for the achievement of higher emission intensity than was nano-sized ${\alpha}-Al_2O_3$. This discrepancy is considered to be because the diffusion of $Al^{3+}$ into $Y_2O_3$ lattice is dependent on the crystalline phase of $Al_2O_3$, which affects the phase transformation of YAGG:$Ce^{3+}$ phosphors. The optimum chemical composition, having the maximum emission intensity, was $(Y_{2.98}Ce_{0.02})(Al_{2.8}Ga_{1.8})O_{11.4}$ prepared with ${\gamma}-Al_2O_3$. On the other hand, the decay time of the YAGG:$Ce^{3+}$ phosphors, irrespective of the crystalline phase of the nano-sized alumina source, was below 1 ms due to the allowed $5d{\rightarrow}4f$ transition of the $Ce^{3+}$ activator.

Excitation Response Estimation of Polar Class Vessel Propulsion Shafting System (대빙 등급 선박 추진 시스템의 기진 응답 평가)

  • Barro, Ronald D.;Lee, Don-Chool
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.21 no.12
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    • pp.1166-1176
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    • 2011
  • The prospect in opening the arctic trade transportation route on a year-round basis offers vast opportunity of exploring untapped resources and shortened navigational routes. In addition, the environment's remoteness and lack of technical experiences remains a big challenge for the maritime industry. With this, engine designers and makers are continually investigating, specifically optimizing propulsion shafting system design, to meet the environmental and technical challenges of the region. The International Association of Classification Society, specifically machinery requirements for polar class ships(IACS UR13), embodies the propulsion shafting design requirements for ice class vessels. However, the necessity to upgrade the various features of the unified rules in meeting current polar requirements is acknowledged by IACS and other classification societies. For the polar class propulsion shafting system, it is perceived that the main source of excitation will be the propeller - ice load interaction. The milling - and the impact load, in addition to the load cases interpreted by IACS, contribute greatly to the overall characteristic of the system and due considerations are given during the propulsion design stage. This paper will expound on the excitation load estimation factors affecting the dynamic response of the different propulsion shafting system design. It is anticipated that detailed understanding of these factors will have a significant role during propulsion shafting design in the future.

Voice personality transformation using an orthogonal vector space conversion (직교 벡터 공간 변환을 이용한 음성 개성 변환)

  • Lee, Ki-Seung;Park, Kun-Jong;Youn, Dae-Hee
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.33B no.1
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    • pp.96-107
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    • 1996
  • A voice personality transformation algorithm using orthogonal vector space conversion is proposed in this paper. Voice personality transformation is the process of changing one person's acoustic features (source) to those of another person (target). In this paper, personality transformation is achieved by changing the LPC cepstrum coefficients, excitation spectrum and pitch contour. An orthogonal vector space conversion technique is proposed to transform the LPC cepstrum coefficients. The LPC cepstrum transformation is implemented by principle component decomposition by applying the Karhunen-Loeve transformation and minimum mean-square error coordinate transformation(MSECT). Additionally, we propose a pitch contour modification method to transform the prosodic characteristics of any speaker. To do this, reference pitch patterns for source and target speaker are firstly built up, and speaker's one. The experimental results show the effectiveness of the proposed algorithm in both subjective and objective evaluations.

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New Strategy for Eliminating Zero-sequence Circulating Current between Parallel Operating Three-level NPC Voltage Source Inverters

  • Li, Kai;Dong, Zhenhua;Wang, Xiaodong;Peng, Chao;Deng, Fujin;Guerrero, Josep;Vasquez, Juan
    • Journal of Power Electronics
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    • v.18 no.1
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    • pp.70-80
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    • 2018
  • A novel strategy based on a zero common mode voltage pulse-width modulation (ZCMV-PWM) technique and zero-sequence circulating current (ZSCC) feedback control is proposed in this study to eliminate ZSCCs between three-level neutral point clamped (NPC) voltage source inverters, with common AC and DC buses, that are operating in parallel. First, an equivalent model of ZSCC in a three-phase three-level NPC inverter paralleled system is developed. Second, on the basis of the analysis of the excitation source of ZSCCs, i.e., the difference in common mode voltages (CMVs) between paralleled inverters, the ZCMV-PWM method is presented to reduce CMVs, and a simple electric circuit is adopted to control ZSCCs and neutral point potential. Finally, simulation and experiment are conducted to illustrate effectiveness of the proposed strategy. Results show that ZSCCs between paralleled inverters can be eliminated effectively under steady and dynamic states. Moreover, the proposed strategy exhibits the advantage of not requiring carrier synchronization. It can be utilized in inverters with different types of filter.

Inspection of Ceramic Coatings Using Nanoindentation and Frequency Domain Photoacoustic Microscopy

  • Steen, T.L.;Basu, S.N.;Sarin, V.K.;Murray, T.W.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.26 no.6
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    • pp.390-402
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    • 2006
  • The elastic properties and thickness of mullite environmental barrier coatings grown through chemical vapor deposition (CVD) on silicon carbide substrates were measured using frequency domain photoacoustic microscopy. In this technique, extremely narrow bandwidth surface acoustic waves are generated with an amplitude modulated laser source. A photorefractive crystal based interferometer is used to detect the resulting surface displacement. The complex displacement field is mapped as a function of source-to-receiver distance in order to extract the wavelength of the surface acoustic wave at a given excitation frequency, and the phase velocity is determined. The coatings tested exhibited spatial variations in thickness and mechanical properties. The measured surface wave dispersion curves were used to extract an effective value for the elastic modulus and the coating thickness. Nanoindentation was used to validate the measurements of the effective elastic modulus. The average elastic modulus measured through the coating thickness using nanoindentation is compared to the effective modulus found using the photoacoustic system. Optical microscopy is used to validate the thickness measurements. The results indicate that the photoacoustic microscopy technique can be used to estimate the effective elastic properties in coatings exhibiting spatial inhomogeneities, potentially providing valuable feedback for the optimization of the CVD growth process.

Analysis and Evaluation of Impact Sound Insulation of Concrete Floor Structures in Response to Characteristics of Heavy-weight Impact Sources (중량충격원에 따른 콘크리트 바닥판의 차음특성 분석 및 평가에 관한 연구)

  • Yoo, Seung-Yup;Yeon, Jun-Oh;Jeon, Jin-Yong
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.10
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    • pp.1062-1068
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    • 2009
  • In this study, the impact force levels of bang machine and impact ball were measured, then the heavy-weight impact sounds generated by the bang machine and impact ball were investigated. It was found that the heavy-weight impact sources generated through modal excitation, and the impact force of the impact ball was similar to that of real impact source. The heavy-weight impact sounds were also measured in the real apartments with different slab thickness and floor structures. The results showed that the floor impact sound levels in terms of $L_{iFmax,AW}$, generated by impact ball sounds were reduced by using the resilient isolators. The frequency characteristics of heavy-weight impact sounds at 125 and 250 Hz were consistent with the characteristics of impact force spectrum. However, the difference between the impact sounds and the impact forces were found at 63 and 500 Hz due to the resonance of the floor structure and flanking noise, respectively.

An innovative vibration barrier by intermittent geofoam - A numerical study

  • Majumder, Mainak;Ghosh, Priyanka;Sathiyamoorthy, Rajesh
    • Geomechanics and Engineering
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    • v.13 no.2
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    • pp.269-284
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    • 2017
  • A new technique is proposed to obtain more effective screening efficiency against the ground vibration using intermittent geofoam (IF) in-filled trench. The numerical analysis is performed by employing two-dimensional finite element method under dynamic condition. Vertically oscillated strip foundation is considered as the vibration source. In presence of the ground vibration, the vertical displacements at different locations (pick-up points) along the ground surface are captured to determine the amplitude reduction factor (ARF), which helps to assess the efficiency of the vibration screening technique. The efficiency of IF over continuous geofoam (CF) in-filled vibration barriers is assessed by varying the geofoam density, the location of trench and the frequency of excitation. The results from this study indicate that a significant reduction in ARF can be achieved by using intermittent geofoam as compared to continuous geofoam. Further, it is noticed that the efficiency of IF increases with an increase in the frequency of the vibrating source. These encouraging results put forward the potential of utilising intermittent geofoam as a vibration screening material.

Charicteristics of HF 10-cm Type Grid Ion Source for Inert and Chemically Reactive Gases.

  • Chol, W.K;Koh, S.K;Jang, H.G;Jung, H.J;Kondranin, S.G.;Kralkina, E.A.;Bougrov, G.E.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1996.02a
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    • pp.102-102
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    • 1996
  • This paper represents a new type low power High Frequency technological ion source (HF TIS) for ion - beam processing: the surface modification of materials, cleaning of surface, sputtering, coating of thin films, and polishing. The operational principle of HF TIS is based on the excitation of electrostatic waves in plasma located in the external magnetic field. Low power HF TIS with diameter 92 rom gives the opportunity to obtain beams of inert and chemically reactive gases with currents range from 5 to 150 mA (current density $0.015\;~\;3.5\;mA/\textrm{m}^2$) and ion beam energy 100 ~ 2500 eV at a HF power level 10 ~ 150 W. Three grid concave type ion optical system (IOS) is used for extraction and formation ofion beam.n beam.

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The Use of Crude Extract of Kohlrabi (Brassica oleracea gongylodes) as a Source of Peroxidase in the Spectrofluorimetric Determination of Thiamine

  • Amjadi, Mohammad;Manzoori, Jamshid L.;Orooji, Maghsood
    • Bulletin of the Korean Chemical Society
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    • v.28 no.2
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    • pp.246-250
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    • 2007
  • The crude extract of kohlrabi (Brassica oleracea gongylodes) was prepared as a rich source of peroxidase and its enzymatic and specific activities in the presence of cross-linked polyvinylpyrrolidone as a stabilizer were determined. This extract was used to catalyze the oxidation of thiamine in the presence of hydrogen peroxide to thiochrome at pH 8.0. Thiochrome shows strong fluorescence at 436 nm with excitation at 370 nm. Based on the obtained results, a sensitive and simple spectrofluorimetric method was developed for the determination of thiamine. In the optimum conditions, the calibration graph was linear from 2 × 10-7 to 1 × 10-4 mol L-1, with a detection limit of 6.2 × 10-8 mol L-1. The relative standard deviation (RSD) was 1.2% for 5 × 10-6 mol L-1 thiamine. The method was successfully applied to the determination of thiamine in vitamin B1 and vitamin B complex tablets and vitamin B complex syrup.