• KSBB Journal
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• v.11 no.5
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• pp.606-612
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• 1996

A specific ammino auid in a mixture can be crystallized inside an ion exchange column when displacer concentration is high enough to concentrate the amino acid in a pure band beyond its solubility limit. Glutamic acid formpd a discrete crystal layer in a cation exchanger column by operating displacement development mode and using a high concentration of displacer NaOH. The glutamic acid crystal formed was eluded from the column with the effluent stream and collected in a fraction collector. When 1.0 M of NaOH was used as a displacer, more than 60% of the loaded glutamic acid was recovered as crystal. The continuous crystallization and dissolution of crystal occurred, resulting in apparent movement of the crystal along the column without clogging or pressure increase. NaOH was proved a better displacer than NaCl because hydroxide ions neutralized hydrogen ions released from the resin and thus reduced the number of hydrogen ion competing with sodium ion for re-adsorption. The displacement development process coupled with crystallization provided higher concentration and recovery of glutamic acrid than conventional chromatography.

• Economic and Environmental Geology
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• v.49 no.2
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• pp.89-95
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• 2016

Mo isotope, one of highly redox-sensitive isotopes, has been shown to be useful tracers of geochemical processes. Many studies for Mo isotope have documented with the help of recently developed analysis tools, but it has not yet been documented in the Korea. In this study, we introduce two-stage column separation method of Mo using column tube (BioRad PolyPrep(R) column, 10 ml) and anion exchange resin (BioRad Resin AG(R) 1-X8, 200-400 mesh). Mo isotope ratios in the solid SRMs (BHVO-2, SDO-1, PACS-2) and liquid SRM (IAPSO) were measured on MC-ICP-MS (Multi-collector Inductively Coupled Plasma Mass Spectrometer) and then compared with reference Mo isotope ratios. Mo isotope ratios in our study overlap with reference Mo isotope ratios within analytical error.

• Clean Technology
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• v.10 no.1
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• pp.9-17
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• 2004

Direct methanol fuel cell(DMFC) with proton exchange membrane (PEM) has advantages over the conventional power source (e.g. vehicle). DMFC, however, has a problem to be solved such as methanol crossover, high anodic overpotential and limiting current density, etc. The physicochemical phenomena in DMFC can be described by coupled PDEs (partial differential equations), which can be solved by a PDE solver. In this paper, we utilized a commercial software FEMLAB to solve the PDEs. The FEMLAB is one of the software programs available which are developed as a solver for building physics problems based on PDEs and is designed to simulate systems of coupled PDEs which may be 1D, 2D, 3D, non-liner and time dependent. We performed simulation using the Tafel equation as an electrochemical reaction model to analyze methanol concentration profile in DMFC system. We confirm that the rapid decrease of methanol concentration at anodic catalyst layer with the increase of the current density is a main reason of the low performance in DMFC through simulation results.

• Analytical Science and Technology
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• v.13 no.6
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• pp.781-788
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• 2000

Tellurium in simulated nuclear spent fuels (SIMFUEL) has been determined by hydride generation-inductively coupled plasma atomic emission spectrometry (HG-ICP-AES). Parameters such as concentrations of HCl and $NaBH_4$, flow rate of HCl and $NaBH_4$ were optimized and then the effects of U, Mo, Pd, Rh and Ru on the Te intensity were investigated. A thiourea as a masking agent was used to eliminate or minimize such interferences specially caused by palladium. Tellurium was measured by HG-ICP-AES and ICP-MS after separation of tellurium from SIMFUEL with cation exchange chromatography. The relative deviation between direct measurement and separation method was less than 6% based on the data by ICP-MS.

• Journal of the Korean Society of Systems Engineering
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• v.18 no.2
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• pp.58-74
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• 2022

Deterministic accident analysis plays a central role in the nuclear power plant (NPP) safety evaluation and licensing process. Traditionally the conservative approach opted for the point kinetics model, expressing the reactor core parameters in the form of reactivity and power tables. However, with the current advances in computational power, high fidelity multi-physics simulations using real-time code coupling, can provide more detailed core behavior and hence more realistic plant's response. This is particularly relevant for transients where the core is undergoing reactivity anomalies and uneven power distributions with strong feedback mechanisms, such as reactivity initiated accidents (RIAs). This work addresses a RIA, specifically a control element assembly (CEA) withdrawal at power, using the multi-physics analysis tool RELAP5/MOD 3.4/3DKIN. The thermal-hydraulics (TH) code, RELAP5, is internally coupled with the nodal kinetics (NK) code, 3DKIN, and both codes exchange relevant data to model the nuclear power plant (NPP) response as the CEA is withdrawn from the core. The coupled model is more representative of the complex interactions between the thermal-hydraulics and neutronics; therefore the results obtained using a multi-physics simulation provide a larger safety margin and hence more operational flexibility compared to those of the point kinetics model reported in the safety analysis report for APR1400. The systems engineering approach is used to guide the development of the work ensuring a systematic and more efficient execution.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.242-242
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• 2016

Magnetite, Fe3O4, is a ferrimagnet with a cubic inverse spinel structure and exhibits a metal-insulator, Verwey, transition at about 120 K.[1] It is predicted to possess as half-metallic nature, 100% spin polarization, and high Curie temperature (850 K). Cobalt ferrite is one of the most important members of the ferrite family, which is characterized by its high coercivity, moderate magnetization and very high magnetocrystalline anisotropy. It has been reported that the CoFe2O4/Fe3O4 bilayers represent an unusual exchange-coupled system whose properties are due to the nature of the oxide-oxide super-exchange interactions at the interface [2]. In order to evaluate the effect of interface interactions on magnetic and transport properties of ferrite and cobalt ferrite, the CoFe2O4/Fe3O4 superlattices on MgO (100) substrate have been fabricated by molecular beam epitaxy (MBE) with the wave lengths of 50, and $200{\AA}$, called $25{\AA}/25{\AA}$ and $100{\AA}/100{\AA}$, respectively. Streaky RHEED patterns in sample $25{\AA}/25{\AA}$ indicate a very smooth surface and interface between layers. HR-TEM image show the good crystalline of sample $25{\AA}/25{\AA}$. Interestingly, magnetization curves showed a strong antiferromagnetic order, which was formed at the interfaces.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.2C
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• pp.69-77
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• 2012

In general, geothermal energy pile and horizontal ground heat exchangers are installed in shallower depths than conventional vertical ground coupled heat pumps. Consequently their heat exchange performance is strongly governed by thermal conductivity of soil layer. Previous studies have shown that the thermal conductivity of soil above ground water table significantly affects the heat exchange rate because of partially saturated condition in soil and consequent variation of soil thermal conductivity. This paper presents a study result on the prediction of thermal conductivity of weathered granite soils. For weathered granite soils sampled from 5 locations, thermal conductivity tests were conducted with varying porosity and degree of saturation. The existing thermal conductivity models in literatures appeared inappropriate to the weathered granite soils. Hence, an empirical equation was proposed in this paper and its validity was examined by applying it to thermal conductivity test results obtained for weathered granite soils in this study and from literatures.

• Journal of the korean society of oceanography
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• v.37 no.3
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• pp.125-133
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• 2002

Water and salt budgets in the Yellow Sea and Bohai are analyzed based on the historical data and CTD data collected recently using box models. The amounts of volume transport and of water exchange across the boundary between the Yellow and East China Seas are estimated to be 2,330-2,840 $\textrm{km}^3$/yr and 109-133 $\textrm{km}^3$/yr, respectively, from the one-layer box model. Corresponding water residence time is 5-6 years. In the Bohai, water residence time is twice as long as that in the Yellow Sea, suggesting that the Yellow Sea and Bohai cannot be considered as a single system in the view of water and salt budgets. The results indicate that water and salt budgets in the Yellow Sea depend almost only on the water exchange between the Yellow and East China Seas. The computation with the coupled two-layer model shows that water residence time is slightly decreased to 4-5 years for the Yellow Sea. In order to reduce uncertainties for the budgeting results the amount of the discharge from the Changjiang that enters into the Yellow Sea, the vertical advection and vertical mixing fluxes across the layer interface have to be quantified. The decreasing trend of the annual Yellow River outflow is likely to result that water residence time is much longer than the current state, especially for the Bohai. The completion of the Three Gorges dam on the Changjiang may be change the water and salt budgets in the Yellow Sea. It is expected that cutting back the discharge from the Changjiang by 10% through the dam would increase water residence time by about 10%.

• Journal of Magnetics
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• v.20 no.1
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• pp.31-39
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• 2015

Macroscopic hysteresis loops and microscopic magnetic moment distributions have been determined by a three-dimensional (3D) model for exchange-coupled Sm-Co/${\alpha}-Fe$/Sm-Co trilayers with in-plane collinear easy axes. These results are carefully compared with the popular one-dimensional (1D) micromagnetic models and recent experimental data. It is found that the results obtained from the two methods match very well, especially for the remanence and coercivity, justifying the calculations. Both nucleation and coercive fields decrease monotonically as the soft layer thickness $L^s$ increases while the largest maximum energy product (roughly 50 MGOe) occurs when the thicknesses of hard and soft layers are 5 nm and 15 nm, respectively. Moreover, the calculated angular distributions in the thickness direction for the magnetic moments are similar. Nevertheless, the calculated nucleation and pinning fields as well as the energy products by 3D OOMMF are systematically smaller than those given by the 1D model, due mainly to the stray fields at the corners of the films. These demagnetization fields help the magnetic moments at the corners to deviate from the previous saturation state and facilitate the nucleation. Such an effect enhances as $L^s$ increases. When the thicknesses of hard and soft layers are 10 nm and 20 nm, respectively, the pinning field difference is as large as 30%, while the nucleation fields have opposite signs.

• Macromolecular Research
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• v.16 no.3
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• pp.204-211
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• 2008

A platinum-catalyzed polyelectrolyte porous membrane was prepared by solid-state compression of electrospun polystyrene (PS) fibers and in-situ metallization of counter-balanced ionic metal sources on the polymer surface. Using this ion-exchange metal-polymer composite system, fiber entangled pores were formed in the interstitial space of the fibers, which were surrounded by sulfonic acid sites ($SO_3^-$) to give a cation-selective polyelectrolyte porous bed with an ion exchange capacity ($I_{EC}$) of 3.0 meq/g and an ionic conductivity of 0.09 S/cm. The Pt loading was estimated to be 16.32 wt% from the $SO_3^-$ ions on the surface of the sulfonated PS fibers, which interact with the cationic platinum complex, $Pt(NH_3)_4^{2+}$, at a ratio of 3:1 based on steric hindrance and the arrangement of interacting ions. This is in good agreement with the Pt loading of 15.82 wt% measured by inductively coupled plasma-optical emission spectroscopy (ICP-OES). The Pt-loaded sulfonated PS media showed an ionic conductivity of 0.32 S/cm. The in-situ metallized platinum provided a nano-sized and strongly-bound catalyst in robust porous media, which highlights its potential use in various electrochemical and catalytic systems.