• 제목/요약/키워드: Exchange times

검색결과 814건 처리시간 0.028초

Single Ion Exchange Process에 의한 LCD용 기판유리의 강화 (Strengthening of Substrate Glass for LCD by Single ton Exchange Process)

  • 이회관;오영석;이용수;강원호
    • 한국세라믹학회지
    • /
    • 제39권7호
    • /
    • pp.675-679
    • /
    • 2002
  • 강화유리를 제조하기 위해서, 디스플레이 기판으로 사용되는 soda-lime-silicate 유리를 대상으로 단일이온교환 특성에 대하여 3점곡강도와 잔류응력을 조사하였다. 단일이온교환을 47$0^{\circ}C$에서 1시간 처리 후, 45$0^{\circ}C$에서 24시간 행하였을 때, 62.5$\times$10$_{6}$ kg/$m^2$의 최대 강도 값을 나타내었다. 또한, 곡강도 측정 후 얻어진 시편의 파단면에 존재하는 잔류응력층을 파괴분석을 통하여 관찰한 결과, 이 잔류응력층이 외부하중에 대한 탄성 변형에너지를 흡수하여 유연성을 증가시킴을 알 수 있었다 또한, 탄성변형에너지 흡수는 만곡변화, 균열가지수 및 취성특성 분석에서도 관찰되었다.

CKD 추출액내 KCl 제거를 위한 이온교환수지 조업조건 최적화 연구 (A study on the optimization of Ion Exchange Resin operating conditions for removal of KCl from CKD extract)

  • 장영희;이예환;김지유;박일건;이주열;박병현;김성철;이상문;김성수
    • 한국응용과학기술학회지
    • /
    • 제36권4호
    • /
    • pp.1088-1095
    • /
    • 2019
  • CKD 추출액은 시멘트공정에서 발생한 폐기물인 CKD를 시멘트 원료로 재사용하기 위해 공정 방해물질로 작용하는 KCl을 추출한 폐수이며, 폐수처리시설 증설 등의 문제로 추출액 무방류 및 이를 재이용하고자 하였다. 이온교환법을 적용하여 KCl을 제거한 결과, 이온교환 후 추출액의 pH는 12.7에서 pH 2 미만으로 감소하였으며 양이온교환수지의 H+가 이온교환을 거쳐 추출액에 용해되었음을 확인하였다. 이온교환의 선택성에 의해 Ca2+, K+ 순서로 제거되었으며, K+ 이온을 제거하기 위해 접촉시간의 증가가 필요함을 판단하였다. 이온교환수지와 직접접촉시간이 약 6배 높은 접촉시간을 갖는 회분식장치에서 연속흐름식장치 대비 4배 높은 K+ 제거 효율을, 7배 높은 Cl- 제거 효율을 확인하였다. 양이온교환수지의 H+가 음이온교환수지의 OH- 대비 1.2배 빠른 교환속도를 가짐을 추출액 pH 변화를 통해 확인하였다.

작업장에서 사용 가능한 방독마스크 정화통 교체주기 프로그램의 개발(II) - 냄새 서한도(odor threshold)를 이용하는 방법 (Development of feasible program of exchange period for chemical cartridge in the workplace (II) - Method of using odor threshold)

  • 한돈희;강민선;이광용
    • 한국산업보건학회지
    • /
    • 제19권2호
    • /
    • pp.102-112
    • /
    • 2009
  • The greatest concern of vapor/gas respirators is when to exchange chemical cartridges, but it is very difficult to estimate the breakthrough time of them in the workplace spot due to so many factors influencing on breakthrough. There needs to study on estimating cartridge exchange period available practically in the spot, even if it is not precise. In the previous study, authors suggested the method on estimating service-life of chemical cartridges using cartridges discarded after use. This followed study was to estimate exchange period for chemical cartridges using comparison of concentrations between Korean Occupational Exposure Limits (KOELs) and odor thresholds of chemicals. Chemicals were divided into four groups, I, II, III and IV groups. Group I chemicals are relatively safe if cartridges are just or slightly delayed exchanged when smelling since odor thresholds were less than 0.5 times KOELs. Odor threshold of Group II chemicals are 0.5~2.0 times KOELs and potentially hazardous if cartridges are exchanged when smelling. Those chemicals should be conducted program on estimating service-life of cartridges, which was just previously published (J Kor Soc Occup Environ Hyg 2008;18(3) 204-215). Group III chemicals (odor thresholds are more than 2.0 times KOELs) and Group IV chemicals (odorless or no data for smelling) must be performed the above mentioned program before cartridges. Even if this method on cartridge exchange using odor threshold is practically widely used in the workplace spot in the present, program on estimating service-life of cartridges is recommended for all chemicals to reduce potentially hazards.

Seawater Exchange and Residence Time in Gamak Bay Determined by Numerical Experiments

  • Lee, Moon-Ock;Kim, Byeong-Kuk
    • Fisheries and Aquatic Sciences
    • /
    • 제14권4호
    • /
    • pp.421-428
    • /
    • 2011
  • We conducted modeling experiments to evaluate the residence times and exchange rates of seawater in Gamak Bay, located on the southern coast of the Korean Peninsula. The results revealed that pollutants are more quickly dispersed in a fixed grid rather than in a variable grid system. Pollutant concentrations decayed exponentially with time after release near the mouth of the bay, whereas no exponential variations were seen at the northwest end of the bay. The mean exchange rate of the seawater was 1.58% per day in the variable grid system, and the residence time of pollutants was greater than 288 days in Gamak Bay. Conversely, the exchange rate of seawater in Gamak Bay, as revealed by the particle tracking method, was 65% over a 50-day simulation. The results suggest that the seawater exchange in Gamak Bay is so low that pollutants are likely to remain in the bay indefinitely.

용혈위기를 동반한 윌슨병에서 교환 수혈로 회복된 소아 1예 (Hemolytic Crisis Recovered by Exchange Transfusion in a Child with Fulminant Wilson's Disease)

  • 최희정;임해리;최병호
    • Pediatric Gastroenterology, Hepatology & Nutrition
    • /
    • 제9권1호
    • /
    • pp.108-113
    • /
    • 2006
  • 윌슨병에서 용혈성 빈혈과 전격성 간부전이 동반되면 혈장교환술이나 간이식이 필수적이다. 저자들은 간염과 용혈위기가 동반된 전격성 윌슨병 환아에서 혈장교환술을 계속하였으나 호전을 보이지 않아 교환수혈을 시행한 결과 용혈위기를 극복하였다. 현재까지 약물치료와 혈장교환술에 뒤이은 간이식이 일차 치료로 되어 있지만, 전격성 간부전이 응급으로 간이식을 해야 할 만큼 심하지 않은 경우에는 혈장교환술후 교환수혈을 시도할 수 있을 것으로 생각한다.

  • PDF

1,2,4-트리클로로벤젠용액 및 니트로벤젠용액 내에서의 브롬화갈륨과 브롬화 n-부틸의 브롬 교환반응 (Kinetics of the Bromine-Exchange Reaction of Gallium Bromide with n-Butyl Bromide in 1,2,4-Trichlorobenzene and in Nitrobenzene)

  • 권오천;최상업
    • 대한화학회지
    • /
    • 제20권6호
    • /
    • pp.479-485
    • /
    • 1976
  • 방사성 브롬으로 표시한 브롬화 n-부틸을 사용하여 1,2,4-트리클로로벤젠용액 및 니트로 벤젠용액 내에서 브롬화칼륨과 n-브롬화부틸 사이에 일어나는 브롬교환 반응의 속도를 19,25 및 40$^{\circ}C$에서 측정하였다. 본 실험의 결과는 이 브롬 교환반응이 브롬화칼륨에 관하여 2차반응이고 n-브롬화부틸에 관하여 1차 반응임을 보여준다. $19^{\circ}C$에서의 반응속도상수 값이 1,2,4-트리클로로벤젠용액에서 $1.15{\times}10^{-4} l^2{\cdot}mole^{-2}{\cdot}sec^{-1}$이고, 니트로벤젠용액에서 $4.21{\times}10-4 l2{\cdot}mole-2{\cdot}sec-1$임을 알았다. 그리고 반응속도상수와 온도와의 관계로부터 이 교환반응에 대한 활성화 에너지, 활성화 엔탈피 및 활성화 엔트로피 값을 계산하였다.

  • PDF

Impact of CO2 Emissions, Exchange Rate Regimes, and Political Stability on Currency Crises: Evidence from South Asian Countries

  • ULLLAH, Zia;FEN, Tan Xiao;TUNIO, Fayaz Hussain;ULLAH, Imran
    • The Journal of Asian Finance, Economics and Business
    • /
    • 제9권2호
    • /
    • pp.29-36
    • /
    • 2022
  • This study uses the panel probit model to investigate and evaluate the relationship between exchange rate regimes, political stability, and carbon dioxide during currency crises. To understand currency crisis times, we study a panel dataset of seven South Asian nations that contain annual observations from 1996 to 2020. Furthermore, we created the EMPI exchange market pressure indicator to detect crises. Our results strongly suggested that fixed exchange rate is negatively associated with currency crises, with good regulatory quality and better effective governments. Simultaneously, the floating exchange rate is positively related to the currency crises in those countries where the rule of law has less adequately flowed. However, CO2, exports, and interest rates are buoyantly associated with crises. The floating exchange rate, the rule of law, exports, and interest rate are associated positively and contribute more prone to the crisis episodes. Negatively associated variables contributed less amid crises episodes: fixed exchange rate regime, government effectiveness, and regulatory quality. Meanwhile, CO2 has a positive relationship with a currency crisis and contributes more likelihood to the probability of a currency crisis. Countries that adopted the fixed exchange rates with effective governments and regulatory quality faced more minor currency crises.

Stock Prices and Exchange Rate Nexus in Pakistan: An Empirical Investigation Using MGARCH-DCC Model

  • RASHID, Tabassam;BASHIR, Malik Fahim
    • The Journal of Asian Finance, Economics and Business
    • /
    • 제9권5호
    • /
    • pp.1-9
    • /
    • 2022
  • The study examines stock prices (LOGKSE) and exchange rate (LOGPK)-Pakistani Rupee vis-à-vis US Dollar- interactions in Pakistan. This study employs a multivariate VAR-GARCH model using monthly data from January 2012 to October 2020. The results of the Johansen cointegration test show that there is no relationship between Foreign Exchange Market and Stock Market in the long run. In the short-run, stock exchange returns are affected slightly negatively by the changes in the foreign exchange market, but the foreign exchange market does not seem to be affected by the ups and downs of the stock exchange. The VAR model and Granger Causality show that both markets are strongly influenced by their own lagged values rather than by the lagged values of one another and show weak or no correlation between the two markets. Volatility persistence is observed in both the stock and foreign exchange markets, implying that shocks and past period volatility are major drivers of future volatility in both markets. Thus greater uncertainties today will induce panic and consequently generate higher volatility in the future period. This phenomenon has been observed many times on Pakistan Stock Exchange especially. The results have important implications for local international investors in portfolio diversification decisions and risk hedging strategies.

자본유출입 급변동과 외환 및 유통시장 안정성에 관한 연구 (A Study on the Sudden Stop in Capital Flows and Foreign Exchange and Distribution Market Stability)

  • 김윤철;이명훈
    • 유통과학연구
    • /
    • 제14권12호
    • /
    • pp.79-87
    • /
    • 2016
  • Purpose - Since 1990, the sudden stop in capital flows has caused the economic crisis. The purpose of this research is to suggest the policy measures to mitigate the risk of the sudden stop in capital flows. To this end, we examine the theoretical framework and analyze the case study for countries which are faced with the sudden stop. Also we examine the structural problems of the foreign exchange market in Korea and derive the policy implications to prevent the sudden stop. Research design, data, and methodology - The criteria of whether the sudden stop in capital flows occurs are based upon Calvo et al. (2008). In case the proxy variable for the balance of capital account decreases from the average by over twice standard deviation, we determine that the sudden stop occurs for that country. The sample period is from January 1990 to December 2008, as in Calvo (2014). The sample countries are 17 developed countries and 19 emerging market countries, which are different from those of the previous papers as Agosin and Huaita (2012), and Calvo (2014). When the exchange market pressure index(EMPI) is deviated from the average by over three times standard deviation, we determine that the foreign exchange market is unstable for that country. Results - We find that the characteristics of the sudden stop in capital flows are the bunching or contagion among countries, the rapid drop in real effective exchange rate, and the huge decrease in foreign exchange reserves. Many countries tried to increase foreign exchange reserves and regulate capital flows. Also the foreign exchange market in Korea are found to be the volatile exchange rate, the vulnerable external debt and careless management of the foreign exchange derivatives transaction risk. Conclusions - To lessen the risk in the sudden stop of capital flows, this research suggests the some useful policy measures. To enhance the foreign exchange and distribution market stability, we should improve the price mechanism of exchange rate, hold the appropriate level of foreign exchange reserves, prevent excessive inflows of foreign exchange and promote sound transactions of foreign exchange derivatives.

An NMR Study of Unequal Site Exchange of 9-Methyl Group in Triptycene by Spin-Lattice Relaxation and 2D-EXSY Experiments

  • Cho, Jang-Geun;Ahn, Sang-Doo
    • 한국자기공명학회논문지
    • /
    • 제11권1호
    • /
    • pp.1-9
    • /
    • 2007
  • An unequal site exchanging system induced by restricted rotation of 9-methyl group in 1,8-dichloro-9-triptycene has been studied by spin-lattice relaxation and 2D-EXSY experiments. The exchange rate obtained from relaxation studies is very well coincident to the result of line shape analysis, and the difference of the relaxation times ($T_1$) in two different sites has an important role to analyze 2D-EXSY experimental data.

  • PDF