• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.1
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• pp.55-64
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• 2023

There is a gap in our understanding of the behavior of fused and molten fuel salts containing unavoidable contamination, such as those due to fabrication, handling, or storage. Therefore, this work used calorimetry to investigate the change in liquidus temperature of PuCl₃, having an unknown purity and that had been in storage for several decades. Further research was performed by additions of NaCl, making several compositions within the binary system, and summarizing the resulting changes, if any, to the phase diagram. The melting temperature of the PuCl₃ was determined to be 746.5℃, approximately 20℃ lower than literature reported values, most likely due to an excess of Pu metal in the PuCl₃ either due to the presence of metallic plutonium remaining from incomplete chlorination or due to the solubility of Pu in PuCl₃. From the melting temperature, it was determined that the PuCl₃ contained between 5.9 to 6.2mol% Pu metal. Analysis of the NaCl-PuCl₃ samples showed that using the Pu rich PuCl₃ resulted in significant changes to the NaCl-PuCl₃ phase diagram. Most notably an unreported phase transition occurring at approximately 406℃ and a new eutectic composition of 52.7mol% NaCl-38.7mol% PuCl₃-2.5mol% Pu which melted at 449.3℃. Additionally, an increase in the liquidus temperatures was seen for NaCl rich compositions while lower liquidus temperatures were seen for PuCl₃ rich compositions. It can therefore be concluded that changes will occur in the NaCl-PuCl₃ binary system when using PuCl₃ with excess Pu metal. However, melting temperature analysis can provide valuable insight into the composition of the PuCl₃ and therefore the NaCl-PuCl₃ system.

• Journal of The Korean Astronomical Society
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• v.18 no.2
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• pp.100-110
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• 1985

The HI features associated with HII regions and radio sources in the galactic-plane are searched in the Maryland-Green Bank Galactic 21-cm Line Survey. Among the twenty-eight such objects, twenty-five show HI depression features, two no feature, and an emission feature with excess HI brightness temperature. Most of these feature are surrounded by strong HI emissions. The depth of the HI depression is proportional to the radio continuum brightness temperature. The angular dimensions of the HI feature and radio source are comparable. The small HI depressions shown at the positions of HII region located in the outer solar circle are considered to be HI self-absorption features of very cold HI gas.

• Journal of Animal Environmental Science
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• v.12 no.1
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• pp.29-34
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• 2006

The effects of turning frequency were examined on the efficiency of composting lime treated excess sludge amended with sawdust from the activated sludge process after a liquid/solids separation process. The raw and excess sludge from the activated sludge process associated with the hog wastewater treatment system is a significant problem and composting is an effective method far reducing the pollution potential of hog wastewater sludge. The coagulant used sludge composting and ammonia emissions from composting are not well established. The effect of compost properties such as high total carbon, C/N ratio and pH value on performance of composting sludge and biofiltration of ammonia from composting process were investigated. The ammonia emission was not significantly increased during composting. The ammonia concentrations of the exhaust air of composter were ranged from 0.5 and 7 ppm about 12 days after composting. The performance of the hog wastewater sludge composting was the most sensitive to chemical treated sludge properties such as high total carbon and high C/N ratio of the initial compost mixes. Temperature in compost and ammonia emission were not greatly affected by the turning frequency.

• Progress in Superconductivity
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• v.9 no.1
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• pp.91-95
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• 2007

[ $YBa_2Cu_3O_{7-{\delta}}$ ] films have been prepared on $LaAlO_3$ (100) single-crystal substrates by the metal organic deposition using dichloroacetate precursors (DCA-MOD). DCA precursor solutions with different composition such as; Yttrium-excess(15 at%), barium-poor(25 at%), and a stoichiometric(Y:Ba:Cu=1:2:3) were prepared in order to investigate the effects of precursor composition on the properties of YBCO films prepared by DCA-MOD method. Coated films were calcined at low temperature up to $500^{\circ}C$ in flowing humid oxygen atmosphere. Conversion heat treatment was performed $800^{\circ}C$ for 2 h in flowing Ar gas containing 1000 ppm oxygen with a humidity of 9.45%. For the film prepared using excess yttrium composition, high critical current density ($J_c$) of $>2MA/cm^2$ was obtained whereas, for the films prepared using barium-poor composition, $J_c$ was lower than $1MA/cm^2$.

• 한국연소학회:학술대회논문집
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• 1999.10a
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• pp.111-115
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• 1999

In order to enhance the burner performance of household gas fired absorption chiller/heaters, the operating condition(excess air $\approx$ 10%) of the burner currently being used was required to be optimized. In this regard, we examined where the $CO_{\min}$. emission limit was located between blow off and yellow tip limit and how much amount of excess air was exhausted by means of observing blow off and yellow tip limit. It was found that the $CO_{\min}$ limit(excess air ${\approx}$ 4%) was determined near the yellow tip limit. The effect of exhaust pressure on the $CO_{\min}$. limit was that, if exhaust pressure was higher than that in steady condition, higher air blower fan rpm is demanded to maintain the $CO_{\min}$ limit. Therefore, it was necessary to optimize the operating condition of burner in terms of a thermal efficiency and safety.

• Journal of Power System Engineering
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• v.18 no.5
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• pp.35-41
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• 2014

The wood pellet, which is one of the woody biomass energy, has very high economic efficiency and combustion efficiency during their combustion. The existing pellet burner have many problems such as low combustion efficiency, flame stabilization, ash problem and ignition time etc. We developed cyclonic wood pellet burner aim to 20,000kcal/hr boiler and measured temperature profiles and exhaust gases in order to investigate the flame stability and optimum combustion condition at any air flow conditions. As results, we confirmed the reappearance and the isotropy of the experimental results in the burner. At the first air flow inlet condition of excess air ratio ${\alpha}=0.02$, second air flow $490{\ell}/min$ had the best combustion condition when pellet supplied 30g. This result means that we need much air supply only for the swirling of second air flow. So we tested various second air flux at first air excess air ratio ${\alpha}=0.7$ condition. At this condition, we could find out that we don't need much second air and total air flux compared to the former condition. We will continuously test this work of air flow distribution, and swirl effect of first air flow, and ash elimination.

• Journal of the Korean Ceramic Society
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• v.42 no.5 s.276
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• pp.308-313
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• 2005

In this study the electrical conductivity of excess BaO in $BaTiO_3$ was measured to investigate the relationship between defects and solubility in the temperature range of $900^{\circ}C$ to $1300^{\circ}C$ under various oxygen partial pressure. First of all, quenched $BaTiO_3$ powders of various Ba/Ti ratios were analysed by X-ray diffraction to confirm whether second phase is formed or not. As the results, we observed the solubility of BaO in the temperature range of $1200^{\circ}C$ to $1400^{\circ}C$, and it was also found that the conductivity minima move to lower $PO_2$ with increasing excess BaO within solubility limit.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.12
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• pp.764-768
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• 2016

To investigate excess $Na^+$ effect, $Bi_{0.5}(Na_{0.78+x}K_{0.22})_{0.5}TiO_3$ ($0{\leq}x{\leq}0.05$) (BNKT) ceramics were prepared by using a conventional solid-state reaction method. The structure and ferroelectric properties of BNKT ceramics were characterized by XRD (X-ray diffraction) and polarization dependence by external electric field. Also, the temperature dependence of dielectric constant and loss were studied. From these results, it was found that appropriate excess $Na^+$ into BNKT ceramics compensate the volatility and induce dense ceramics. The enhanced piezoelectric coefficient (158 pC/N) and depolarization temperature ($202^{\circ}C$) were obtained for the x=0.01 composition.

• Journal of the Korean Society of Propulsion Engineers
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• v.23 no.2
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• pp.118-125
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• 2019

Metals exposed to high temperature/high pressure/oxidant excess environment of an oxygen excess pre-combustor may undergo rapid oxidation. In this study, the test facility to simulate the high temperature/high pressure/oxidant excess environment was constructed and the oxidation resistance evaluation was carried out for various metal materials. As a result, the discoloration of the metallic materials, the change in the surface roughness and the peeling of the metal surface were observed, and the weight change was also observed. The resulst showed that oxidation-resistant coating of a metal material of the combustor is indispensably required, and the use of XM-19, which has the highest content of Cr and Ni, is expected to provide more structural stability.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.3
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• pp.110-116
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• 2016

Biogas yields point of view, the possibility of reusing excess sludge treated by thermal pretreatment for the purpose of improving the efficiency of the anaerobic digestion process has been investigated in recent year. Thermal pretreatment technology was considered as a pretreatment technique to improve excess sludge properties because of the solubilization of particulate organics. As a view point of sludge reduction and recycle, however, many researchers focused on the ability of particulate hydrolysis and COD solubilization under a high temperature, and few reports have addressed on the physical/chemical characteristics changing. This research was performed to evaluate the effects of a various temperature and chemical additives on carbon formation and fractionation in treated slurry from thermal pretreatment. Based on the results, it was revealed that oxidants injection and temperature changing have significantly caused the change of carbon fractions in slurry from thermal pretreament. Especially, it was considered that the efficiencies of particle hydrolysis increased with the increase of the reaction temperature. Low molecular weight(Mw < 350 g/mol) organic carbon formation increased with the increase of oxidants injection. It was expected that results of this research will provide an overview of the characteristics of thermal pretreatement for excess sludge reduction and recycle.