• 한국세라믹학회지
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• 제31권11호
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• pp.1299-1306
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• 1994

Effect of MgO content on microstructural evolution and microwave dielectric properties of Ba(Mg1/3Ta2/3)O3 system was investigated. MgO content was varied from 10 mol% deficiency to 10 mol% excess of stoichiometric composition, respectively. It was found that MgO-deficient specimen showed faster grain growth rate than stoichometric and MgO excess BMT system. Besides, sandwich type precipitates of Ba5Ta4O15 which was formed within the BMT grain, might lead to the anisotropic grain growth of BMT grain. On the contrary, in MgO excess specimen, BMT grain growth rate was retarded by precipitations of MgO phase in grain boundary. Besides, the Q values of MgO-deficient showed lower than MgO-excess due to precipitations of Ba5Ta4O15 within BMT grain.

• 전자공학회논문지T
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• 제36T권3호
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• pp.7-12
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• 1999

본 논문은 (1-x-y)PMN-yPT-xST세라믹스의 유전 및 변위특성을 ST의 양에 따라 조사하였다. ST의 성분은 1∼ 6㏖%이내로 변화시켰고 과잉 MgO에 따른 조성변화에 따라 결과를 조사하였다. ST의 성분의 증가에 따라 유전상수는 5㏖%인 조성에서 최대값을 나타내었다. 큐리온도는 ST의 성분이 증가함에 따라 선형적으로 감소하였다. 항전계와 잔류분극은 l㏖%인 조성에서 최대값을 나타내었다. 과잉 MgO의 효과에 따라 유전상수는 0.8PMN-0.12PT-0.04ST조성에서 MgO를 3㏖%까지 과잉 첨가함에 따라 증가하였으나 변위특성은 감소함을 나타내었다.

• 한국세라믹학회지
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• 제30권8호
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• pp.629-634
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• 1993

Dielectric and electrostrictive properties of 0.99Pb(Mg1/3Nb2/3)O3-0.01Pb(Mn2/3W1/3)O3 system using KCl-NaCl salts have been investigated as a function of the amount of excess MgO. For the specimens calcined at $700^{\circ}C$ for 1h and then sintered at 115$0^{\circ}C$ for 4h, the perovskite phase and the relative density were about 98% and 95%, respectively. With the addition of excess MgO up to 10mol%, the dielectric constant and the electrostrictive strain increased due to the increase of density and grain size, and these properties were degraded by the further addition of excess MgO. For the 10mol% excess MgO added specimen, the maximum electrostrictive strain, Xmax, and the electrostrictive coefficient, Q11, were 4.5$\times$10-4, 3.5$\times$10-2m4/C2, respectively. These results were correlated with the property of PMW and microstructure.

• 한국세라믹학회지
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• 제34권3호
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• pp.281-288
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• 1997

유전율이 높고 온도안정성이 우수하다고 알려져 있는 40Pb(Mg1/3Nb2/3)O3-30PbTiO3-30Pb(Mg1/2W1/2)O3계 세라믹스에 소결온도를 낮추기 위하여 저온에서 액상을 형성하는 91PbO-9WO3를 과잉첨가하여 소결성, 미세구조 및 유전성의 변화에 대하여 조사하였다. 91PbO-9WO3의 첨가량이 증가함에 따라 소결온도가 저하하였으며 6 mol%첨가시는 875$^{\circ}C$에서 소결이 가능하였다. 유전율은 기본조성에서 16,400이었고, 첨가제가 1 mol% 과잉첨가된 경우 18,500으로 최대값을 나타냈으며 이후 첨가량이 증가함에 따라 감소하였다. 첨가제의 첨가량이 2~4mol%인 시편의 온도에 따른 유전율 변화곡선에서 double peak maxima가 나타났으나, 첨가량이 5 mol% 이상인 시편에서는 입계에 텅스텐을 많이 포함하고 있는 결정상이 생성되었고 double peak maxima는 나타나지 않았다.

• 한국세라믹학회지
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• 제30권11호
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• pp.925-932
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• 1993

The perovskite phase in PZN-PMN-PT (Pb(Zn, Mg)1/3Nb2/3O3-PbTiO3) pseudoternary ceramics was stabilized by the addition of excess constituent divalent oxides (PbO, MgO and ZnO). The excess addition of 5mol% MgO or 7.5mol% PbO fully stabilized the perovskite phase. The enhanced diffuse phase transition (DPT) and the decrease in the electrical resistivity observed in the presence of excess ZnO or MgO were interpreted in terms of the additional formation of negatively charged, short-range ordered 1:1 domains with a concomitant generation of charge carriers, holes.

• 한국세라믹학회지
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• 제26권5호
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• pp.712-718
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• 1989

PMN ceramics with excess MgO addition in the range of 0 to 70m/o were prepared, and their electrical properties, such as dielectric constant, tan$\delta$, diffuseness coefficient, remanent polarization, coercive field and electrical conductivity were measured. Dielectric constant and remanent polarization increased with up to 5m/o excess MgO and then decreased presumely due to the precipitation of second phase, etc. Electrical conductivity slightly increased with the addition of excess MgO.

• 한국세라믹학회지
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• 제37권7호
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• pp.673-680
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• 2000

The effect of excess PbO(0, 1, 2, 4, and 8 mol%) on grain growth and densification of (65)Pb(Mg1/3Nb2/3)O3-(35)PbTiO3 [mol%] ceramics has been investigaetd. With increasing the amount of excess PbO and sintering time, densities of sintered samples decreased gradually. The samples containing less than 1 mol% of PbO showed normal grain growth behavior, however abnormal grain growth was observed to occur in the samples with more than 2 mol% of PbO. In the samples with more than 2 mol% of PbO, the number of abnormal grains decreased and thus the average grain size became smaller with increasing the amount of excess PbO. These results demonstrated that the abnormal grain growth started to occur when a critical amount of excess PbO was added to a (65)Pb(Mg1/3Nb2/3)O3-(35)PbTiO3 sample. Since PMN-PT grains in a liquid matrix were angular, the observed abnormal grain growth was explained to proceed through the two dimensional nucleation process.

• 한국세라믹학회지
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• 제34권1호
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• pp.31-36
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• 1997

유전율이 높고 온도안정성이우수하다고 알려져 있는 Pb(Mg1/3Nb2/3)O3-PbTiO3-Pb(Mg1/2W1/2)O3 계 세라믹스를 산화물혼합법 및 precursor방법으로 제조함에 있어 과잉 MgO의 첨가에 따른 미세구조와 유전특성의 변화에 대하여 조사하였다. MgO를 5mol%이상 과잉첨가하여 100$0^{\circ}C$에 소결한 시편의 유전율은 5000이상이고, -55$^{\circ}C$에서 1$25^{\circ}C$범위에서 변화율은 +25%에서 -5$0^{\circ}C$ 정도를 나타냈다. XRD 분석결과 perovskite상과 Pb2WO5 결정이 주된상이었으며, 소결온도 및 MgO 첨가량이 증가함에 따라 cubic pyrochlore상인 Pb3Nb4O13와 PbWO4는 감소하였다. SEM에 의한 미세구조의 관찰에서 MgO첨가량이 증가함에 따라 결정성장이 촉진되는 것을 알 수 있었으며 이것이 소결온도 증가에 따른 pyrochlore상의 감소와 함께 유전율을 증가시키는 원인이었다. BSE관찰에서 화학성분 분포의 불균일성이 나타났으며, 각각의 소결온도에서 생성되는 결정상과 함께 유전율의 온도의존성을 완만하게 만드는 원인임을 알 수 있었다.

• 한국세라믹학회지
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• 제22권2호
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• pp.17-24
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• 1985

In the composition of $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ the effect of particle size on PbO vaporization were measured, . The initial step of discontinuous vaporization of unreated PbO during the calcining process was depended on the particle size. All additives $La_2O_3Nb_2O_5$ and $Al_2O_3$ inhibited the grain growth of the composition $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ +2wt% excess PbO. The dielectric and piezoelectric properties of the composition $Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$ were improved by the addition of 2wt% excess PbO and proper additive. The electromechanical planar coupling factor of 0.65 and mechnical quality factor of 390 could be obtained by adding 5wt% $Nb_2O_5$ to the composition 2wt% excess PbO+$Pb(Mg_{0.15} W_{0.15})Ti_{0.35}-Zr_{0.35}O_3$.

• 한국세라믹학회지
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• 제35권9호
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• pp.905-910
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• 1998