• Title/Summary/Keyword: Evaporation gas

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The effects of Se evaporation temperature on CIS absorber layer fabricated by non-vacuum process (Se 증발온도가 비진공 공정으로 제조한 CIS 광흡수층에 미치는 영향)

  • Park, Myoung-Guk;Ahn, Se-Jin;Yoon, Jea-Ho;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.441-443
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    • 2008
  • A non-vacuum process for fabrication of $CuInSe_2$ (CIS) absorber layer from the corresponding Cu, In solution precursors was described. Cu, In solution precursors was prepared by a room temperature colloidal route by reacting the starting materials $Cu(NO_3)_2$, $InCl_3$ and methanol. The Cu, In solution precursors were mixed with ethylcellulose as organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of Cu, In solution with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents and to burn the organic binder material. Subsequently, the resultant CI/Mo/glass sample was selenized in Se evaporation in order to get a solar cell applicable dense CIS absorber layer. The CIS absorber layer selenized at $530^{\circ}C$ substrate temperature for 30 min with various Se gas evaporation temperature was characterized by XRD, SEM, EDS.

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Extinguishment of Liquid Fuel Fire by Water Mist Containing Additives

  • Park, Jae-Man;Won, Jung-Il;Shin, Chang-Sub
    • International Journal of Safety
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    • v.4 no.2
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    • pp.24-29
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    • 2005
  • An experimental study was presented for extinguishing characteristics of liquid fuel fire by water mist($Dv_{0.99}{\leq}200{\mu}m$) containing potassium acetate and sodium acetate trihydrate. To evaluate the extinguishing performance of water mist containing additives, the evaporation characteristics of a water droplet on a heated surface was examined. The evaporation process was recorded by a charge-coupled-device camera. Also, small-scale extinguishing tests were conducted for n-heptane pool fire in ventilated space. During the experiments, flame temperatures were measured, and concentrations of oxygen and carbon monoxide were analyzed by a combustion gas analyzer. The average evaporation rate of water droplet containing additives was lower than that of pure water at a given surface temperature and decreased with the concentration increase due to the precipitation of salt in the liquid-film and change of surface tension. In case of using additives, the fire extinguishing times was shorter than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing additives was increased. And also dissociated metal atoms, potassium or sodium, were reacted as a scavenger of the major radical species OH, H which were generated for combustion process. Moreover, at a high pressure of 4 MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.

Morphological control and electrostatic deposition of silver nanoparticles produced by condensation-evaporation method (증발-응축법에 의해 발생된 은(silver) 나노입자의 구조제어 및 전기적 부착 특성 연구)

  • Kim, Whidong;Ahn, Ji Young;Kim, Soo Hyung
    • Particle and aerosol research
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    • v.5 no.2
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    • pp.83-90
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    • 2009
  • This paper describes a condensation-evaporation method (CEM) to produce size-controlled spherical silver nanoparticles by perturbing coagulation and coalescence processes in the gas phase. Polydisperse silver nanoparticles generated by the CEM were first introduced into a differential mobility analyzer (DMA) to select a group of silver nanoparticles with same electrical mobility, which also enables to make a group of nanoparticles with elongated structures and same projected area. These silver nanoparticles selected by the DMA were then in-situ sintered at ${\sim}600^{\circ}C$, and then they were observed to turn into spherical shaped nanoparticles by the rapid coalescence process. With the assistance of modified converging-typed quartz reactor, we can also produce the 10 times higher number concentration of silver nanoparticles compared with a general quartz reactor with uniform diameter. Finally, the spherical silver nanoparticles with 30 nm were electrostatically deposited on the surface of silicon substrate with the coverage rate of ~4%/hr. This useful preparation method of size-controlled monodisperse silver nanoparticles developed in this work can be applied to the various studies for characterizing the physical, chemical, optical, and biological properties of nanoparticles as a function of their size.

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Effects of Injection Pressure and Injection Angle on Spray Characteristics in Loop Scavenged Type 2-stroke Engines (루프소기형태의 2행정기관에서 분사압력 및 분사각도에 따른 분무특성 연구)

  • Chae, S.;Ryou, H. S.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.1
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    • pp.165-176
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    • 1996
  • The flow field and spray characteristics for loop scavenged type 2stroke engine having pancake shape was numerically computed using KIVA-Ⅱ code. The cylinder has 1intake port, 2side intake ports and 1exhaust port with induced flow angle 25 deg. In engine calculation, the chop techniques is used to strip or add planes of cells across the mesh adjacent to the TDC and the BDC(ports parts) for preventing the demand of exceed time during the computation, providing a control on cell height in the squish region. The modified turbulent model including the consideration of the compressibility effect due to the compression and expansion of piston was also used. The case of 25 deg.(injection angle) which is opposite to scavenging flow direction shows better the distribution of droplets and the evaporation rate of droplets compared to other cases(0 deg., - 25 deg.). When injection pressure was increased, the spray tip penetration became longer. When injection pressure was increased, the interaction between the upward gas velocity and spray droplets strongly cause. Thus the breakup of droplets is strongly occurred and the evaporation rate of droplets was found to be better.

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1-D Analysis for Water Spray Cooling of Exhaust Gas in Combustor Test Facility (물 분무를 이용한 연소가스 냉각 1차원 해석)

  • Im, Ju Hyun;Kim, Myung Ho;Kim, Yeong Ryeon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.61-67
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    • 2015
  • The cooling of hot exhaust gas is an important issue for the construction of combustor test facility. Water spray is an effective method for exhaust gas cooling due to its large latent heat in process of evaporation. In this study, 1-D analysis has been performed based on continuity, energy conservation, and saturated vapor property to understand water spray cooling of combustion gas. In the exhaust duct of combustor test facility, the injected water decreases combustion gas temperature, and evaporates in the combustion gas. However, some of the injected water is collected in the sump due to condensation. The evaporation of water helps combustion gas cooling, but causes pressure increase inside the exhaust duct due to increase of vapor pressure. These phenomena has been analyzed by 1-D modeling in this study. From 1-D analysis, the adequate mass flow rate of water spray to cool combustion gas and to avoid excessive pressure rise inside the exhaust duct has been decided.

Comparison of Combustion and Emission Characteristics of Propane and n-butane in a Stratified DISI Engine (성층연소 직분식 엔진에서의 propane과 n-butane의 연소 및 배기특성 비교)

  • Joo, Yongjoon;Jung, Jinyoung;Bae, Choongsik
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.97-100
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    • 2014
  • The combustion and emission characteristics of propane and n-butane which are the main components of LPG were compared with gasoline. The experiment was performed in a stratified DISI engine under lean combustion conditions. Mixtures of propane and n-butane wre more homogeneous because propane and n-butane have better evaporation characteristics. As a result, combustion speeds of n-butane and propane were slower, and emission levels of NOx and PM were lower. However, in spite of better evaporation, PM from propane was higher.

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An experimental study on the mixing of evaporating liquid spray with duct flow (덕트 유동에서 증발을 수반하는 액상 스프레이의 혼합 특성에 대한 실험적 연구)

  • Kim, Young-Bong;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.93-96
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    • 2005
  • High temperature furnace such as Steam power plant and incinerator contribute considerable part of NOx generation and face urgent demand of De-NOx system. Reducing agents are necessary to use De-NOx system. In this study mixing caused by direct injection of reducing agent solution spray into flue gas duct was measured. Carbonated water was used as tracer and simulated agent because ammonia as a reducing agent is not proper to experiment. Mixing and evaporation must occur simultaneously and quickly enough to achieve desirable efficiency. To achieve that, the angle of attack of static mixer and the location is simulated and $CO_2$ concentration is measured.

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Measuring Nano-Width of Wave Fronts in Combustion: a Numerical Approach (연소시 발생하는 파면의 나노 사이즈 두께 측정: 수치적 접근)

  • Yoh, Jai-Ick
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.20-27
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    • 2005
  • I consider the structure of steady wave system which is admitted by the continuum equations for materials that undergo phase transformations with exothermic chemical reaction. In particular, the dynamic phase front structures between liquid and gas phases, and solid and liquid phases are computationally investigated. Based on the one-dimensional continuum shock structure analysis, the present approach can estimate the nano-width of waves that are present in combustion. For illustration purpose, n-heptane is used in the evaporation and condensation analysis and HMX is used in the melting and freezing analysis of energetic materials of interest. On-going effort includes extension of this idea to include broad range of liquid and solid fuels, such as rocket propellants.

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Study on the Flow and Mass Transfer in a PASB Arc Plasma Chamber (PASB 아크 플라즈마 챔버에서 발생하는 유동 및 물질전달에 관한 연구)

  • Lee, Jong-Chul;Kim, Youn-J.
    • The KSFM Journal of Fluid Machinery
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    • v.11 no.4
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    • pp.7-13
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    • 2008
  • The computational investigation is performed to find out the interaction of arc plasmas with surrounding materials and the thermal flow characteristics in a PASB (Puffer-Assisted Self-Blast) chamber, which is one of new breaking concepts in $SF_6$ switchgears. It is very important to define the flow and mass transfer happened during the full arcing history for further understanding complex physics inside the chamber. In this study, we have considered two diffusion processes by the hot arc plasma, one is PTFE nozzle ablation and the other is Cu electrode evaporation, simultaneously. It was found that the principle of the pressure-rise inside the chamber is confirmed by the computational results and the increase of the electrical conductivity of the residual gas near current zero is critical to the chamber design.

Analysis of the Impinging Spray Behavior Accompanying with Change of Phase (상변화를 동반한 충돌분무의 거동해석)

  • Song, Hong-Jong;Cha, Keun-Jong;Kim, Duck-Jool
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.6
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    • pp.852-859
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    • 2000
  • The emission in the exhaust gas from diesel engine is effected by the fuel spray characteristics. The spray of D.I. diesel engine impinges on a piston cavity and a cylinder wall. It is very important to know exactly the distribution and behavior of the spray inside cylinder. The objective of this study is to develop more accurate evaporation model. The EPISO code was used to analyze the flow characteristics in the engine. The Wakil model and the Faeth model are applied to the EPISO code to analyze the behavior of impinging spray. And also experimental and numerical analysis were carried out. The spray behavior characteristics were investigated by changing injection pressure, ambient pressure and temperature. The behavior of impinging spray was strongly effected by the change of ambient pressure and temperature. The effects of evaporation and rebounding droplet should be considered.