• 제목/요약/키워드: Eutectic Si

검색결과 182건 처리시간 0.025초

Al-7Si 합급의 결정립 미세화에 미치는 TiC 첨가의 영향 (Study on Grain Refinement of Al-7Si Based Alloys with TiC)

  • 한윤성;최창옥
    • 한국주조공학회지
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    • 제23권2호
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    • pp.63-68
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    • 2003
  • Al-Ti-C grain refiner form a relatively new alternative to the existing class of Al-Ti-B type grain refiners for achieving fine equiaxed structures in aluminum alloys during casting and solidification. The present study was carried out to investigate the influence of Al-Ti-C master alloys on the grain structure of Al-7Si alloys. The present study also investigates the relationship between grain refining efficiency and concentrations of Fe and Si in hypo-eutectic Al-Si alloys using Al-3Ti-0.13C master alloys. It is found that several parameters affect significantly the grain refining performance in silumin alloys. The present study reports the influence of various parameters such as alloy content, master alloy addition level, melt holding time and superheat on the grain refining efficiency in Al-7Si alloys.

급속응고 Al-20wt%Si-5wt%Fe 합금분말 압출재의 강도에 관한 연구 (Fabrication of Rapidly Solidified Al-20wt%Si-5wt%Fe Alloy Powder and Mechanical Properties of its Extrudates)

  • 김택수
    • 한국분말재료학회지
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    • 제1권1호
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    • pp.66-71
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    • 1994
  • Optical microstructures and mechanical properties of Na gas atomized Al-20Si-5Fe alloying powder and its hot extrudates were studied on 3 different types of powder size distribution. This powder showed the size distribution of 10~210 $\mu\textrm{m}$. Also the microstructures of $\alpha$-Al, primary and eutectic Si and needle shaped intermetallic compounds were observed by optical microscope. These needle shaped intermetallic compounds were identified as ${\delta}Al_4FeSi_2$- by XRD and EDX analysis. The ultimate tensile strength(UTS) of these alloy extrudates was increased from 324 to 390 MPa with decreasing powder size range from 120~210 $\mu\textrm{m}$ to 10~64 $\mu\textrm{m}$. A value of Micro-vic-kers hardness was simillar to the result of UTS. These extrudates showed better wear resistance than those of Al-20Si-2X(X : Ni, Cr, Zr), although they are insensitive to the size distribution. These results indicate that the presentation of ${\delta}Al_4FeSi_2$ intermetallic compounds contributed to the wear resistance improvement.

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알루미늄 - 규소 합금의 용탕단조시 유동도에 미치는 규소 함량 및 용탕 처리의 영향 (Effects of Si Content and Melt Treatment on the Fluidity of Al-Si Alloy during Squeeze Casting)

  • 이학주;권해욱
    • 한국주조공학회지
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    • 제26권6호
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    • pp.241-248
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    • 2006
  • The effects of silicon content and melt treatment on the fluidity of Al-Si alloys during squeeze casting were investigated. The fluidity of Al-3.0 wt%Si alloy was found to be lower than that of Al-1.0 wt%Si and the fluidity of the alloy with more than 3.0 wt%Si increased with the silicon content upto 13.0 wt% and rather decreased with15.0 wt%. The fluidity was also increased by the separated treatment of grain refinement or eutectic modification, and even more by the simultaneous treatment of both. The fluidity of hypereutectic alloy was increased by the refinement of primary silicon particle.

재활용 AC4A 알루미늄 합금의 인장특성에 미치는 (Ti-B), Sr 첨가제의 영향 (Effect of Sr and (Ti-B) Additives on Tensile Properties of AC4A Recycled Aluminum Casting Alloys)

  • 오승환;김헌주
    • 한국주조공학회지
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    • 제38권5호
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    • pp.87-94
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    • 2018
  • The effects of Sr and (Ti-B) additives on the tensile properties of AC4A recycled (35% scrap content) aluminum alloys were investigated. An acicular morphology of the eutectic Si phase of as-cast specimens was converted to a fibrous morphology upon the addition of Sr. Moreover, morphology of the Sr modified eutectic Si phase became finer due to a T6 heat treatment. The grain size of the ${\alpha}$-solid solution was decreased by the addition of (Ti-B) additives. Depending on the treatment conditions of the as-cast specimens, i.e., no addition, a Sr addition and a (Ti-B)+Sr addition, the tensile strength levels of the as-cast specimens were 182, 192, and 204MPa, respectively. The corresponding strengths of T6 heat-treated specimens were 293, 308, and 318MPa. Elongations of the as-cast specimens were 2.2, 3.1, and 5.6%, and the corresponding elongations of the T6 heat-treated specimens were 4.6, 6.1, and 7.6%. The percentage of the reduced section area in the tensile specimens was also increased by the Sr and (Ti-B) additives. Sr and (Ti-B) additives changed the microstructure and the distribution of defects in the castings, resulting in an improvement of the tensile properties of AC4A aluminum alloys. According to our test results, recycled (35% scrap content) AC4A aluminum alloy met all of the KS requirements of the tensile strength and elongation values of AC4A aluminum alloy except for the elongation value of the one specimen condition, in this case the as-cast no-addition condition.

전자교반식 수평연속주조법에 의한 반응고 Al 합금의 제조에 관한 연구 (A Study on the Fabrication of Semi-solid Al Alloys by EMS Horizontal Continuous Casting Process)

  • 박기범;송영배;김영환;김경헌;김인배
    • 한국재료학회지
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    • 제10권2호
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    • pp.117-123
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    • 2000
  • 본 연구에서는 반응고 Al합금을 얻기 위해서 3상 2극의 전자교반장치를 이용하였으며, 주입온도와 주입전압을 변화시켜 Al합금의 초정입자크기, aspect ratio, 표준편차, 경도 및 공정 Si 입자의 크기 및 형상 변화를 조사하였다. 같은 주입온도에서는 주입전압이 증가함에 따라 aspect ratio, 표준편차 및 초정입자의 크기는 감소되었다. 전자교반식 수평연속주조방법에 의한 Al 합금의 최적제조 조건은 주입전압 220V, 주입온도 68$0^{\circ}C$이었으며, 이 조건에서 초정입자의 크기는 54$\mu\textrm{m}$이었고, aspect ratio는 1.56이었으며 그 표준편차는 0.4이었다. 그리고 공정 Si의 크기는 0.5$\mu\textrm{m}$이었으며 제조된 Al합금의 경도는 72.1 Hv를 나타내었다. 본 연구를 위해 제작된 3상 2극 전자교반장치에 의해서 매우 낮은 aspect ratio 및 표준편자를 갖는 반응고 A356 Al합금을 제조할 수 있었다.

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Al합금 펄스 Nd:YAG 레이저 점 용접부의 균열 발생기구 (Mechanism of Crack Formation in Pulse Nd YAG Laser Spot Welding of Al Alloys)

  • 하용수;조창현;강정윤;김종도;박화순
    • Journal of Welding and Joining
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    • 제18권2호
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    • pp.213-213
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    • 2000
  • This study was performed to investigate types and formation mechanism of cracks in two Al alloy welds, A5083 and A7NO1 spot-welded by pulse Nd: YAG laser, using SEM, EPMA and Micro-XRD. In the weld zone, three types of crack were observed: center line crack($C_{C}$), diagonal crack($C_{D}$), and U shape crack($C_{U}$). Also, HAZ crack($C_{H}$), was observed in the HAZ region, furthermore, mixing crack($C_{M}$), consisting of diagonal crack and HAZ crack was observed.White film was formed at the hot crack region in the fractured surface after it was immersed to 10%NaOH water. In the case of A5083 alloy, white films in C crack and $C_D crack region were composed of low melting phases, Fe₂Si$Al_8$ and eutectic phases, Mg₂Al₃ and Mg₂Si. Such films observed near HAZ crack were also consist of eutectic Mg₂Al₃. In the case of A7N01 alloy, eutectic phases of CuAl₂, $Mg_{32}$ (Al,Zn) ₃, MgZn₂, Al₂CuMg and Mg₂Si were observed in the whitely etched films near $C_{C}$ crack and $C_{D}$ crack regions. The formation of liquid films was due to the segregation of Mg, Si, Fe in the case of A5083 alloy and Zn, Mg, Cu, Si in the case of A7N01 aooly, respectively.The $C_{D}$ and $C_{C}$ cracks were regarded as a result of the occurrence of tensile strain during the welding process. The formation of $C_{M}$ crack is likely to be due to the presence of liquid film at the grain boundary near the fusion line in the base metal as well as in the weld fusion zone during solidification. The $C_{U}$ crack is considered a result of the collapsed keyhole through incomplete closure during rapid solidification. (Received October 7, 1999)

A study on the squeeze casting of Al-7.0Si-0.4Mg alloy for fuel system parts

  • Kim Soon-Ho;Kim Seong-Soo
    • International Journal of Precision Engineering and Manufacturing
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    • 제6권3호
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    • pp.56-59
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    • 2005
  • Aluminum alloy casting is gaining increased acceptance in automotive and electronic industries and especially, squeeze casting is the most efficient method of mass manufacturing of such parts. In this study, the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C) alloy fabricated by squeeze casting process for development of fuel system parts (fuel rail) are investigated. The microstructure of squeeze cast specimen was composed of eutectic structure aluminum solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy was 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy had good corrosion resistance in electrochemical polarization test.

B390 알루미늄 합금의 초정Si 입자분포에 미치는 원심주조 공정인자의 영향 (Effect of Centrifugal Casting Parameters on The Distribution of Primary Si Particles of B390 Aluminum Alloy)

  • 박정욱;김헌주
    • 한국주조공학회지
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    • 제28권1호
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    • pp.25-30
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    • 2008
  • To develop a functionally graded microstructure of cylindrical liner, effect of centrifugal casting parameters such as pouring temperature of hyper-eutectic Al-Si alloy melt, mold pre-heating temperature, and rotational frequency of mold on distribution of primary Si particles across wall thickness were investigated. Segregation tendency of Si particles toward inner side of cylindrical liner increased as the increase of rotational frequency of mold, pouring temperature of melt and mold pre-heating temperature. Especially, distribution density of primary Si particles within 1.5 mm from inner surface of cylindrical liner was above 35% under the centrifugal casting condition of $750^{\circ}C$ melt pouring temperature, $300^{\circ}C$ mold pre-heating temperature, and 2500 rpm mold rotational frequency.

실리사이드 형성 과정에 대한 재 조명 (Reinvestigation on the silicide formation process)

  • 남형진
    • 반도체디스플레이기술학회지
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    • 제7권2호
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    • pp.1-5
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    • 2008
  • Silicide formation process and the formation sequence were investigated in this study. It was postulated that the formation of the second silicide phase involves glass formation between the first silicide phase and Si given that a thin metal film is deposited on a Si substrate. The concentration of glass was assumed to be located where the free energy of the liquid alloy with respect to the first nucleated compound and solid Si (${\Delta}$G') is most negative. It was also mentioned that the glass concentration is close to the composition of the second phase in order to achieve the maximum energy degradation. It was shown that the minimum ${\Delta}$G' concentration can be estimated by interpolating the portion of the liquidus where the liquid alloy is in equilibrium with the two solid constituents, namely the first compound phase and Si, thereby forming a hypothetical eutectic.

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Effect of Electromagnetic Stirring on Microstructure Evolution in Solidification of a Near-Eutectic Al-Si Alloy

  • Guo, Qing-Tao;Sim, Jae-Gi;Jang, Young-Soo;Choi, Byoung-Hee;Lee, Moon-Hyoung;Hong, Chun-Pyo
    • 한국주조공학회지
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    • 제28권5호
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    • pp.226-230
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    • 2008
  • 본 논문에서는 공정조성 부근의 Al-Si 합금의 미세구조에 미치는 전자기교반(EMS)의 영향에 대하여 연구하였다. 초정 a 상의 형상에 미치는 전자기교반의 세기의 영향을 조사하기 위하여 각각 교반장치에 60, 80,및 120V의 전압을 가하여 미세조직을 관찰하였다. 60V 이하의 전압이 인가되었을 때 전자기교반의 효과가 나타나지 않은 반면에, 80V 이상의 전압으로 5초 이상 인가되었을 때 구상화된 초정 a 상을 얻을 수 있었다. 인가된 전압이 120V일 때 초정 a 상은 보다 균일한 분포를 가지며 구상화 되었다. 전자기교반의 세기와 함께 교반시간의 영향을 확인하기 위하여 교반시간을 증가시키면서 미세조직을 관찰하였다. 또한 초정 a 상의 형상에 미치는 주조변수의 영향에 대해서도 실험하였다.