• Title/Summary/Keyword: Ethylene oxide

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Biodegradability of $Poly({\gamma}-benzyl{\;}L-Glutamate)/Poly(Ethylene Oxide)/poly({\gamma}-benzyl{\;}L-Glutamate)$ Block Copolymer in Mice

  • Oh, In-joon;Oh, Jhin-Yee;Cho, Chong-Su;Lee, Kang-Choon
    • Archives of Pharmacal Research
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    • v.18 no.1
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    • pp.8-11
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    • 1995
  • Biodegradability of poly $Poly({\gamma}-benzyl L-Glutamate)/poly(ethylene oxide)/Poly({\gamma}-benzyl L-Glutamate)$ block copolymer (GEG) having different content of poly(ethylene oxide) (PEO) were examined using magnetite as a tracer in mice. GEG microspheres containing magnetite were injected into mice through tail vein. Biodegradability and tissue distribution of microspheres were examined by analyzing the amount of magnetite in the microspheres recollected from mice organs after specific time interval. The results showed that GEG microsphere of high content of PEO was degraded more rapidly than those of low content of PEO in the mice organs.

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Storeability and Cooking Property of Dried Oak Mushroom Treated with Ethylene Oxide and Gamma Radiation (감마선 조사와 훈증 처리된 건조 표고버섯의 저장성 및 조리 적성)

  • 김영재;김종군;조한옥;변명우;권중호
    • Journal of Food Hygiene and Safety
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    • v.2 no.1
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    • pp.29-34
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    • 1987
  • ABSTRACT$.$ Ethylene oxide (E.O) fumigation and gamma irradiation were applied to compar$.$ ative researches on the microbiological, physical and cooking quality of dried oak mushroom stored at $25^{\circ}C$ and different relative humidities. The equivalent moisture contents of dried oak mushroom for the limiting growth of general molds and xerophilic mold at $25^{\circ}C$ were shown to be 17% and 27% respectively. Total aerobic bacteria, molds and coliforms were sterilized at 5 kGy irradiation but E.O. fumigation was proved insufficient to eliminate the molds. The hydration rate of dried oak mushroom increased according to the increase of irradiation dose and soaking temperatures. and an irradiation by 5 kGy could shorten the hydration time of the sample as compared to E.O. treatment and control group. Sensory evaluation for the irradiated cooked sample was not significantly different in flavour but the texture of the gamma irradiated sample was significantly better(p < 0.01) than that of E. O. fumigated sample.sample.

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Kinetics of Isothermal Crystallization in Poly(ethylene oxide) and Poly(styrene-co-acrylic acid)Blends (Poly(ethylene oxide)/Poly(styrene-co-acrylic acid) Blends의 등온 결정화 속도에 관한 연구)

  • Lee, Sang-Cheol;Lee, Mu-Seong;Jo, Won-Ho
    • Korean Journal of Materials Research
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    • v.1 no.3
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    • pp.151-155
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    • 1991
  • The kinetics of isothermal crystallization in blends of poly(ethylene oxide) (PEO) and poly(styrene-co-acrylic acid) (SAA) has been examined as a function of the blend ratio, the copolymer composition, and the crystallization temperature, based on the Avrami eauation. The Avrami exponents were mostly chose to 2, independent of the crystallization temperature. The crystallization rate of PEO in PEO/SAA blends decreased with the increase of SAA content. And also, the higher the acrylic acid content in the SAA copolymer, 7he slower the crystallization rate of PEO in the blends.

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Synthesis of Multi-walled Carbon Nanotube/Poly(ethylene oxide) Hybrids (다중벽 탄소나노튜브/폴리(에틸렌 옥사이드) 복합체 합성)

  • Hong, Chae-Hwan;Han, Do-Suk;Nam, Byeong-Uk
    • Polymer(Korea)
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    • v.34 no.3
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    • pp.198-201
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    • 2010
  • We have worked a surface modification to release a strong agglomeration of multi-walled carbon nanotube(MWCNT) and a incorporation of hydrophilic polymer to improve compatibility between MWCNT and polymers. Carboxylated MWCNT was easily obtained by acid treatment and the carboxylate was converted to acylchloride by thionyl chloride. Then, we tried one more synthesizing routes to achieve covalent bonds with poly(ethylene oxide) having amine end groups of low molecular weight. We measured the polymer content on the surface of MWCNT by TGA and observed increased diameter of MWCNT by SEM and TEM analysis.

Microbiological and Physicochemical Properties of Dried Fishery Treated with Ethylene Oxide(E. O) and Gamma Irradiation Products (Shucked Shellfish and Shucked Mussel Powder) (방사선 조사 및 Ethylene Oxide 처리된 건조 수산물 (조개살, 홍합살)의 미생물 및 화학적 특성)

  • 조한옥;변명우;권중호;양재승;이재원
    • Journal of Food Hygiene and Safety
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    • v.1 no.1
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    • pp.39-46
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    • 1986
  • Comparison of ethylene oxide(E.O) fumigation and gamma irradiation on the sterilization, microbiological, physicochemcial and sensory quality of dried fishery products (shucked shellfish and mussel powder) were investigated. The viable cell count of mesophilic total bacterial was reduced by over 2 to 3 log cycles with irradiation of 3 to 5 kGy, and those samples were completely sterilized by irradiation dose of 7 to 10 kGy. In view of reduction of microorganisms, D10 value of each samples were ranged from 1. 36-1. 46 kGy. fungi, mesophilic spores, acid tolerant bacteria and coliforms were sterilized at 5 to 7 kGy irradiation but E.O. fumigation proved insulfficient to eliminate the mesophilic total bacteria and fungi. In the physicochemical and sensory quality of samples, such as the amino acid, TBA value, TMA-N, color difference and overall acceptability irradiated sample with optimum dose was similar to those of the nonirradiated sample, while E.O. fumigated sample was remarkably deteriorated in the physicochemical and sensory quality of samples.

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The Research of Optimal Plant Layout Optimization based on Particle Swarm Optimization for Ethylene Oxide Plant (PSO 최적화 기법을 이용한 Ethylene Oxide Plant 배치에 관한 연구)

  • Park, Pyung Jae;Lee, Chang Jun
    • Journal of the Korean Society of Safety
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    • v.30 no.3
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    • pp.32-37
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    • 2015
  • In the fields of plant layout optimization, the main goal is to minimize the construction cost including pipelines as satisfying all constraints such as safety and operating issues. However, what is the lacking of considerations in previous researches is to consider proper safety and maintenance spaces for a complex plant. Based on the mathematical programming, MILP(Mixed Integer Linear Programming) problems including various constraints can be formulated to find the optimal solution which is to achieve the best economic benefits. The objective function of this problem is the sum of piping cost, pumping cost and area cost. In general, many conventional optimization solvers are used to find a MILP problem. However, it is really hard to solve this problem due to complex inequality and equality constraints, since it is impossible to use the derivatives of objective functions and constraints. To resolve this problem, the PSO (Particle Swarm Optimization), which is one of the representative sampling approaches and does not need to use derivatives of equations, is employed to find the optimal solution considering various complex constraints in this study. The EO (Ethylene Oxide) plant is tested to verify the efficacy of the proposed method.

Sanitary Sterilization of Dried Fishes and Mixed Condiments (주요건조 수산물 및 혼합조미료의 위생적 살균)

  • Hong, Won-Joo
    • Korean journal of food and cookery science
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    • v.6 no.2
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    • pp.97-104
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    • 1990
  • 건조 수산가공품 및 혼합조미료 각 5종의 위생적 살균 및 저장방법의 개발을 목적으로 현행살균 방법으로 살균효과의 불충분, 제품의 품질저하, 약제성분의 잔유 등 많은 문제점을 내포한 ethylene oxide에 의한훈증처리와 방사선 조사와의 미생물 살균효과, 이화학적 특성 및 관능적 품질에 미치는 영향을 검토한 결과는 다음과 같다. 시료의 미생물 오염은 전 세균이 $10^3~10^7$ CFU/g으로 그중 90%이상이 내열성 세균이었으며, 곰팡이류는 $10^2~10^3$ CFU/g, 대장균도 시료 5종에서 $10^2~10^6$ CFU/g이나 오염되었다. 살균효과 실험에서 대장균군, 곰팡이류는 5~10 kGy 방사선 조사로서 완전 사멸되었으며, 전세균도 오염도가 매우 높았던 혼합조미료 몇종을 제외하고는 제거되었다. 반면, ethylene oxide훈증처리는 전 미생물의 살균이 불충분하였다. 이 화학적 특성 즉, TBA가 TMA-N 함량, 아미노산, 무기질, 색도 등은 적정 선량의 방사선 조사로서는 무처리구 시료와 거의 차이가 없었으나, ethylene oxide 훈증처리구는 심한 품질의 변화를 나타내었다. 또한 관능검사에 의한 전반적 기호성에 있어서도 방사선조사구가 무처리구 및 ethylene oxide 처리구보다 유의적으로 우수함을 나타냈다.

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Synthesis and Properties of Block Copolymer Comprising of Poly(DL-lactic acid) and Poly(ethylene oxide) (Poly(DL-lactic acid)/Poly(ethylene oxide)을 포함한 블록공중합체의 합성 및 특성)

  • 이찬우;배기서
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.582-588
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    • 2002
  • The block copolymers were prepared by the ring opening polymerizati on of DL-lactide by poly(ethylene oxide) (PEO) with diethylzinc (ZnE$_2$) as a catalyst. When the feed ratio of PEO was over 30% relative to DL-lactide, the polymerization of DL-lactide took place from the PEO hydroxyl terminals to provide the desired A -B-A or A-B block copolymer. The block copolymers were made of films by cast method and the films obtained was drawn to 2.5 times at 60 $\^{C}$. At the same draw ratio, the tensile modulus of the films was decreased with increasing PEO content in the block copolymers. It was therefore suggested that the block copolymers comprising of PDLLA and PEO, had high potentials as the biomaterials with improved flexibility.