• Title/Summary/Keyword: Ethylene Recovery

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Strength Restoration of The DP Finished Cotton Fabric by Enzymatic Treatment (수지 가공 면직물의 강도 회복을 위한 효소처리 연구)

  • 전미선;김주혜;박명자
    • The Research Journal of the Costume Culture
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    • v.12 no.5
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    • pp.737-742
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    • 2004
  • The purpose of this study is restoration for tearing strength of the durable press (DP) finished 100% cotton fabric by enzymatic treatment. Dimethylol Dihydroxy Ethylene Urea (DMDHEU) was used as a DP finish chemical. Enzymes (cellulase, pectinase, protease, lipolase) were selected based on their specific reaction activities. Ideal application of the enzymes for this work was to remove cross-links created by DMDHEU on the surface of the fibers to offer migration property between microstructures of cellulose, yet cross-links that exist inside of the fibers are still remained to impart effect of wrinkle resistance. Physical characteristics (tearing strength, wrinkle recovery, FT-IR) of enzyme treated samples were measured and compared. It was found out that, in case of enzyme treatment, most of enzymes didn't have a great effect on tearing strength, but, in case of Protease, tearing strength increased at DMDHEU 2% treatment. As a result of an experiment on wrinkle recovery of the textiles treated with enzyme making density of DMDHEU different whenever respective experiment was made, it was discovered that density of DMDHEU increased as wrinkle recovery increased and, in the relation to enzyme treatment especially in Lipase enzyme treatment, the lesser density of DMDHEU, the more wrinkle recovery increased.

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Synthesis of 4o-vinylbenzo-15-crown-5 and its copolymerization behavior with Di(ethylene glycol) ethyl ether acrylate (4′-vinylbenzo-15-crown-5의 합성과 Di(ethylene glycol) ethyl ether acrylate와의 라디칼 공중합)

  • Soukil Mah;Jin, Long-Yi;Kyuchan Han
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.195-198
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    • 2002
  • Poly(crown ether)s as a functional polymer materials have powerful and selective complexation properties with a large number of metal cations and have advantage of facility of their recovery and modification of their complexation properties in contrast to their monomeric analogues. Poly(crown ether)s having pendant macrocyclic groups can easily form 2:1-type crown ether ring-to-cation complexes with particular metal ions which are a little larger than the cavity of the crown ether ring. (omitted)

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Low temperature-operating NiO-CoO butane gas sensors

  • Jung, Dong-Ho;Choi, Soon-Don;Min, Bong-Ki
    • Journal of Sensor Science and Technology
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    • v.17 no.4
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    • pp.303-307
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    • 2008
  • $NiO,\;Cu_2O,\;Mn_2O_3$ and $Cr_2O_3$ as p-type semiconductors were added in CoO with 15 wt.% ethylene glycol binder and measured the butane gas sensing characteristics. The highest sensitivity is obtained for the NiO-CoO sensors. CoO-20 at.% NiO sensor with 15 wt.% ethylene glycol binder sintered at $1100^{\circ}C$ for 24 h exhibits high sensitivity of 90 % to 5000 ppm butane gas at the sensor temperature of $250^{\circ}C$, compared to low sensitivities at the low operating temperature for commercial sensors. Response and recovery times are, respectively, within few seconds and 1min in the static flow system, indicating rapid adsorption and desorption of butane gas on sensor surface even at this low temperature.

Adsorption Dynamics of Activated Carbon and Carbon Molecular Sieve Beds for Ethylene Recovery (배가스로부터에틸렌 회수를 위한 활성탄과 CMS 흡착탑의 흡착거동 특성)

  • Yoon, Ki-Yong;Jun, Phillip;Woo, En-Ji;Ahn, Hyungwoong;Lee, Chang-Ha
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.527-534
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    • 2012
  • The adsorption dynamics of activated carbon (AC) and carbon molecular sieve (CMS) beds were studied to recover ethylene from FCC fuel gas. In this study, the FCC fuel gas used consisted of six-component mixture ($CH_4/C_2H_4/C_2H_6/C_3H_6/N_2/H_2$,32:15:14:2:12:25 vol.%). And the breakthrough experiments of adsorption and desorption were carried out. The breakthrough sequence in the AC bed was $H_2$ < $N_2$ < $CH_4$ < $C_2H_4$ < $C_2H_6$ while the sequence in the CMS bed was $H_2$ < $CH_4$ < $N_2$ < $C_2H_6$ < $C_2H_4$. The separation performance of the CMS bed during the adsorption step was lower than that of the AC bed. However, due to the characteristics of kinetic separation, the CMS bed could remove $CH_4/N_2$ as well asthe molecules that are larger than $C_2H_6$, which was not easy to be done by the AC bed. Since it was hard to regenerate the adsorption bed by simple depressurization, vacuum regeneration should be adopted. As a result, the pressure vacuum swing adsorption (PVSA) process, consisting of CMS pretreatment process and AC main process, was suggested to recover ethylene efficiently.

Effect of Glycols and Catalysts on Cotton Fabrics Treated with Glyoxal

  • Lee, Eui-So;Kim, Seung-Il
    • Fibers and Polymers
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    • v.5 no.3
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    • pp.230-233
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    • 2004
  • The optimum conditions for durable press treatment of cotton fabrics using glyoxal as a nonformaldehyde crosslinking agent were investigated. Crosslinking reaction was conducted in the presence of different catalysts such as aluminum sulfate, magnesium chloride, or magnesium chloride-citric acid mixture at various mole ratios of catalyst to glyoxal. Aluminum sulfate was proven the most effective one among those used. Glycol addition into a glyoxal padding bath increased the wrinkle recovery angle(WRA) and whiteness of treated fabrics. The optimum mole ratio of glycol to glyoxal was 1:1. Diethylene glycol addition produced better overall performance to the glyoxal-crosslinked fabric compared to ethylene glycol addition.

Separation and Recovery of Cyclodextrin Glucanotransferase Using Aqueous Two-Phase Systems (수성2상계를 이용한 Cyclodextrin Glucanotransferase 분리 및 회수)

  • 김진현;홍승서;이현수
    • KSBB Journal
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    • v.15 no.6
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    • pp.556-559
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    • 2000
  • Cyclodextrin Glucanotransferase(EC 2.4.1.19 : 1,4-${\alpha}$-glucano) transferase, cyclizing; CGTase) can be separated and recovered in an aqueous two-phase system composed of poly(ethylene glycol)(PEG)/dextran and PEG/salt. In an aqueous two-phase system consisting of PEG 35000 (5%) and dextran T2000 (7%), all cell and debris were collected at the interphase. CGTase partitioned to the denser dextran phase at an yield of 83.4%. On the other hand, in an aqueous two-phase system consisting of PEG 35000 (10%) and sodium phosphate (15%), CGTase partitioned to the denser salt phase at an yield of 95.5%. In order to recover CGTase using an aqueous two-phase system, the PEG/salt system proved to be more efficient than the PEG/dextran system in terms of yield and cost.

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Preparation of a Semi-Conductive Thin Film Sensor for Measuring Occlusal Force

  • Yu, Siwon;Kim, Nari;Lee, Youngjin
    • Journal of Sensor Science and Technology
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    • v.24 no.2
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    • pp.88-92
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    • 2015
  • In order to study the semi-conductive characteristics of carbon black-filled ethylene-propylene-diene monomer (EPDM) composite film, which is used for measuring occlusal force, composite samples with volume ratios of carbon black to EPDM ranging from 30% to 70% were prepared. The process of making a composite film consists of two steps, which involve the preparation of a slurry composition and the fabrication of a thin film using solution casting and a lamination process. To prepare the slurry composition, we dispersed carbon black nanoparticles into an organic solvent before mixing with an EPDM solution in toluene. The mechanical and electrical properties of the resulting carbon black-filled EPDM film were then investigated, and the results showed that the electrical resistance of a film decreases with the increase in the carbon black content. Furthermore, improved elastic recovery was observed after cross-linking the EPDM.

Prediction Method of Long Term Creep Behavior for ETFE Foil by Using Viscoelastic-Plastic Model (점탄소성 모델을 이용한 ETFE 막재의 장기 크리프 거동 예측기법 연구)

  • Kim, Jae-Yeol
    • Journal of Korean Association for Spatial Structures
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    • v.14 no.3
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    • pp.93-100
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    • 2014
  • Ethylene Tetrafluoroethylene (ETFE) has been widely used in long-span buildings because of its light weight and high transparency. This paper studies the short and long term creep behaviour of ETFE foil. A series of short-term creep and recovery tests were performed, in which the residual strain was observed. A long-term creep test of the ETFE foil was also performed over 110 days. A viscoelastic-plastic model was then established to describe the short-term creep and recovery behaviour. The model contains a traditional multi-Kelvin part and an added steady-flow component to represent the viscoelastic and viscoplastic behaviour, respectively. The model successfully fit the data for three stresses and six temperatures. Additionally, time-temperature equivalency was adopted to predict the long-term creep behaviour of ETFE foil. Horizontal shifting factors were determined from the process of shifting creep-curves at six temperatures. The long-term creep behaviours at three temperatures were predicted. Finally, the long-term creep test showed that the short-term creep test at identical temperatures insufficiently predicted additional creep behaviour, and the long-term test verified the horizontal shifting factors derived from the time-temperature equivalency.

Synthesis of Oxyethlyene Modified Silixoane Surfactants for Polyurethane Foam and the Characteristics of Fine Cell Formation (폴리우레탄 폼용 옥시에틸렌 변성 폴리실록산계 계면활성제의 합성 및 미세 셀 발포 특성)

  • Kim, Daeheum;Park, Seungwoo;Yeo, Seungbyung
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.260-266
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    • 2006
  • For the synthesis of polyurethane memory foam stabilizer with fine cells, hydrosilylation reaction with various polyalkyleneoxides and hydrogen functional group of polymethylhydrogensiloxane (D = 75, D' = 15) was conducted. Polyalkyleneoxides (PAO) used in this research were ethylene oxides or ethylene-co-propylene oxides with terminal groups of hydroxides or methyl groups. To analyze the molecular structures and molecular weights as well as the reaction yields (98%), NMR and GPC analysis were executed. Synthesized siloxane surfactants modified with polyalkylene (EO = 12 units) were applied to producing flexible polyurethane fine memory foams from 0.6 pphp to 2.0 pphp. By controlling the amount of the surfactant, physical characteristics, the polyurethane memory foam with cell size (minimum $0.868{\mu}m$), air flows (-78 KPa), and recovery times (8 sec) were achieved.

Study for Mechanical Properties of Electroless (Ni/Au) Plated Monodisperse Polymer Particles (무전해 (니켈/금) 도금 처리된 단분산 가교고분자 미립자의 기계적 물성 연구)

  • Kim, Dong-Ok;Jin, Jeong-Hee;Shon, Won-Il;Oh, Seok-Heon
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.410-416
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    • 2007
  • Monodisperse polymer particles were prepared via one- step seeded polymerization using PMMA as seed particles, and HDDA, triEGDMA or EGDMA as crosslinking monomer. For the study, the effects of 1) the ratio of the absorbed monomer to the seed polymer particles (swelling ratio), 2) the characteristics of crosslinking monomer, 3) electroless Ni plating, and 4) electroless Au Plating on the variation of mechanical properties of polymer particles, such as recovery rate, K-values, breaking strength and breaking displacement were investigated by using MCT (micro compression test). It was observed that swelling ratio of polymer particles influenced only on breaking strength of polymer Particles, while electroless plating did on recovery rate, K-values ($K_{10}\;and\;K_{20}$) and breaking strength of electroless plated polymer particles. However, breaking displacement and K-values ($K_{30}{\sim}K_{50}$) were more or less insensitive to electroless plating.