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http://dx.doi.org/10.5369/JSST.2008.17.4.303

Low temperature-operating NiO-CoO butane gas sensors  

Jung, Dong-Ho (School of Metallurgical and Materials Engineering, Yeungnam University)
Choi, Soon-Don (School of Metallurgical and Materials Engineering, Yeungnam University)
Min, Bong-Ki (Instrumental Analysis Center, Yeungnam University)
Publication Information
Journal of Sensor Science and Technology / v.17, no.4, 2008 , pp. 303-307 More about this Journal
Abstract
$NiO,\;Cu_2O,\;Mn_2O_3$ and $Cr_2O_3$ as p-type semiconductors were added in CoO with 15 wt.% ethylene glycol binder and measured the butane gas sensing characteristics. The highest sensitivity is obtained for the NiO-CoO sensors. CoO-20 at.% NiO sensor with 15 wt.% ethylene glycol binder sintered at $1100^{\circ}C$ for 24 h exhibits high sensitivity of 90 % to 5000 ppm butane gas at the sensor temperature of $250^{\circ}C$, compared to low sensitivities at the low operating temperature for commercial sensors. Response and recovery times are, respectively, within few seconds and 1min in the static flow system, indicating rapid adsorption and desorption of butane gas on sensor surface even at this low temperature.
Keywords
butane sensors; NiO-CoO; low temperature-operating; solid solution;
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  • Reference
1 Y. Kim, 'Gas sensor and application', Kijun Press, Korea, pp. 44-51, 1992
2 Y. Nakamura, 'Stability of the sensitivity of based elements in the field', Chem. Sens. Technol., vol. 2, pp. 71-80, 1989
3 T. Oyabu, T. Osawa, and T. Kurobe, 'Sensing characteristics of tin oxide thick film gas sensors', J. Appl. Physic., vol. 53, no. 11, pp. 7125-7130, 1982   DOI
4 J. H. Chung and S. D. Choi, '$Co_3O_4$ butane gas sensor operating at low temperature (1)', J. Kor. Sensors Soc., vol. 5, pp.7-14, 1996
5 B. D. Cullity, 'Elements of X-ray diffraction', 2nd. ed., Addison-Wesley, pp. 102-103, 1978
6 C.O. Xu, Y. Tamaki, N. Miura, and N. Yamazoe, 'Grain size effects on sensitivity of porous $SnO_2$- based elements', Sensors and Actuators B, vol. 3, pp. 147-155, 1991   DOI   ScienceOn
7 E. Aukurst and A. Muan, Trans. AIME, vol. 230, p. 379, 1964
8 K. Ihokura and J. Watson, 'The stannic oxide gas sensor, principles and applications', CRC Press, pp. 60-62, 1993.E. Aukurst and A. Muan, Trans. AIME, vol. 230, p. 379, 1964
9 S. D. Choi and B. K. Min, '$Co_3O_4$ -based isobutane sensor operating at low temperatures', Sensors and Actuators B, vol. 77, pp. 330-334, 2001   DOI   ScienceOn
10 R. Lalauze and Z. Pijolat, 'A new approach to selective detection of gas by an $SnO_2$ solid state sensor', Sensors and Actuators, vol. 5, pp. 55-63, 1984   DOI   ScienceOn
11 D. D. Lee and D. H. Choi, 'Thick-film hydrocarbon gas sensors', Sensors and Actuators B, vol. 1, pp. 231-235, 1990   DOI   ScienceOn
12 J. R. Anderson and M. Boudart, 'Catalysis-science and technology', vol 3, Springer-Verlag, pp. 83-90, 1982
13 S. Yamauchi, Chemical sensor technology, vol 4, Kodansha Ltd. pp. 32-33, 1992