• Title/Summary/Keyword: Ethylene Oxide

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A Study on the Drag Reduction for Performance the Improvement of Low Temperature Utilization Systems (저온 활용 시스템의 효율 제고를 위한 마찰 저항 감소 연구)

  • Chun, Won-Gee;Kim, Chul-Am;Sung, Jun-Hee;Choi, Hyoung-Jin;Kim, Chong-Bo;Kim, Hyung-Taek
    • Solar Energy
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    • v.17 no.4
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    • pp.13-22
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    • 1997
  • Drag reduction produced by the dilute solution of polymer under turbulent flow in a rotating disk apparatus(RDA) was investigated in this study for the purpose of potential application to the Ocean Thermal Energy Conversion(OTEC) system. Four different molecular weights of poly(ethylene oxide)(PEO) were used as drag reducing additives, and synthetic seawater was adopted as a solvent. Experiments were undertaken to observe the dependence of drag reduction on various factors such as polymer molecular weight, polymer concentration and the rotating speed of the disk. The concentration dependence on the drag reduction of this polymer system was shown to obey an empirical drag reduction equation of the Virk's universal correlation.

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Synthesis of C2 Chemicals from Methane in a Dielectric Barrier Discharge (DBD) Plasma Bed (메탄으로부터 촉매와 유전체 장벽 방전 반응기를 활용한 C2 화합물의 합성)

  • Oh, Ji-Hwan;Jeon, Jong Hyun;Jeoung, Jaekwon;Ha, Kyoung-Su
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.125-132
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    • 2018
  • The direct synthesis of $C_2$ chemical directly from methane was studied by employing catalysts with ordered mesopores in a dielectric barrier discharge plasma reactor. The reaction was carried out using MgO/OMA (ordered mesoporous alumina), $MgO/{\gamma}-Al_2O_3$ and $MgO/{\alpha}-Al_2O_3$ as catalysts. When MgO/OMA was applied, it showed excellent performance in the plasma reactor using pulse-type power supply and the selectivity of $C_2$ chemicals was measured as 67%. The effects of metal oxide type, textural property of support, alumina phase and power supply type on catalytic performance were investigated especially in terms of $C_2$ chemical formation. BET (Brunauer, Emmett, Teller), X-ray diffraction, transmission electron microscope and thermogravimetric analysis were used to investigate the characterization of the catalyst before and after the reaction.

Detergency and Water Wetting/Retention Properties of Soiled Cotton Cloths in Nonionic Surfactant Solutions (비이온계 계면활성제 수용액에서 면 오염포의 습윤특성과 세척성)

  • Kim, Chun-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.3 s.162
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    • pp.433-439
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    • 2007
  • The effects of nonionic surfactants on detergency and water wetting/retention properties of soiled cotton cloths were reported. Two different soiled cloths were used. soiled cotton cloth 1 was made in the lab. with carbon black, tripalmitin, n-dodecane & palmitic acid on Korea Apparel Testing & Research Institute(KATRI) cotton testcloth and soiled cotton cloth 2(EMPA 101) was purchased from Testfabrics, Inc., USA. The following nonionic surfactants; l.e., Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, & 85, were used in the study. The water retention ratio(W/H) values of soiled cotton cloths were decreased, whereas the water contact angle values of soiled cloth were not changed markedly compared with those of unsoiled testcloths. The wetting and water retention of soiled cotton cloth 1 was improved with addition of nonoinic surfactants. The surfactants which have more hydrophilic characterictics or unsaturated hydrophobe tails were effective in improving wetting and water retention properties of soiled cotton cloth 1. The water contact angle values of soiled cotton cloths were extremely low with Span 20, presumably due to the high adsorption density or the surfactant. The detergency of soiled cloths were low in Span 20 and high in Tween 20, 40, 60 & 80 0.1g/dl surfactant solutions. Nonionic surfactants having higher ethylene oxide contents resulted in better detergency. In the range studied, the wetting and water retention of soiled cotton cloths did not show any particular relation to the detergency, whereas the surfactant characteristics, especially HLB values, influenced the detergency of soiled cotton cloths.

Effects of the Mechanical Stretch on Aligned Multi-Layered Nanofibrous Scaffolds Seeded with Smooth Muscle Cells (기계적 자극이 다층 구조의 나노파이버 지지체의 평활근 세포에 미치는 영향)

  • Shin, Ji-Won;Kim, Dong-Hwa;Heo, Su-Jin;Kim, Su-Hyang;Kim, Young-Jick;Shin, Jung-Woog
    • Journal of Biomedical Engineering Research
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    • v.29 no.1
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    • pp.52-58
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    • 2008
  • The object of this study is to investigate the effects of intermittent cyclic stretching on the smooth muscle cells (SMCs) seeded onto aligned multi-layered fibrous scaffold. To make multi-layered fibrous scaffold, polyurethane (PU) and poly(ethylene oxide) (PEO) were electrospun alternatively, then were immersed into distilled water to extract PEO. Various types of scaffolds were fabricated depending on fiber directions, i.e., aligned or randomly oriented. The direction of stretching was either parallel or vertical to the fiber direction for the aligned scaffolds. The stretching was also applied to the randomly aligned scaffolds. The duration of stretching was 2 min with 15 min resting period. During the stretching, the maximum and minimum strain was adjusted to be 10 and 7%, respectively with the frequency of 1 Hz. The bioactivities of cells on the scaffolds were assessed by quantifying DNA, collagen, and glycosaminoglycan (GAG) levels. And the cell morphology was observed by staining F-actin. SMCs under parallel stretching to the fiber direction responded more positively than those in other conditions. From the results, we could explain the morphological effect of a substrate on cellular activities. In addition the synergistic effects of substrate and mechanical stimuli effects were confirmed.

SEM STUDY ON THE BACTERIAL ADHESION TO THE DENTIN OF THE ROOT CANAL (미생물의 근관내 상아질 부착에 대한 주사전자현미경적 연구)

  • Jeong, Sang-Kyun;Oh, Tae-Seok;Bae, Kwang-Shik
    • Restorative Dentistry and Endodontics
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    • v.25 no.1
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    • pp.116-122
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    • 2000
  • On the instrumented root canal wall, amorphous, irregular smear layer can be observed with Scanning Electron Microscope(SEM). The purpose of this study was to evaluate the effect of the presence or absence of smear layer on the adhesion of Staphylococcus aureus to the dentin of the root canal. Human incisors, extracted within 7 days, with no caries, no fracture, no calcification of canal, were selected. After cutting crown portion at cemento-enamel junction, root canal preparation was done by modified crown-down technique using Profile and Gates - Glidden Drill. During canal preparation, 10ml physiologic saline solution(group1&3) or 10ml 3.5% NaOCl(group2&4) was used as irrigation solution. And 10ml physiologic saline solution(group1&3) or 10ml 0.5M EDTA(group2&4) was applicated for final flush. After vertical sectioning and ethylene oxide gas sterilization, samples(group1&2) were immersed into BHIYHM broth inoculated with Staphylococcus aureus (ATCC 31153) and incubated for 3hrs at $37^{\circ}C$. All samples were prepared for and observed with SEM(JEOL JSM840S). The data were analyzed by Mann-Whitney rank sum test. The conclusions are as follows ; 1. Smear layer covers entire root canal surface after root canal preparation. 2. Smear layer has been removed away and the entrances of dentinal tubules have opened widely, when applying 0.5M EDTA and 3.5% NaOCl. 3. A significantly higher number of bacteria were adhered to the root canal dentin without smear layer(p<0.0001). 4. Smear layer produced during root canal preparation impedes bacterial adhesion and colonization to dentin matrix, therefore inhibits canal reinfection.

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Cases Series of Malignant Lymphohematopoietic Disorder in Korean Semiconductor Industry

  • Kim, Eun-A;Lee, Hye-Eun;Ryu, Hyung-Woo;Park, Seung-Hyun;Kang, Seong-Kyu
    • Safety and Health at Work
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    • v.2 no.2
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    • pp.122-134
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    • 2011
  • Objectives: Seven cases of malignant lymphohematopoietic (LHP) disorder were claimed to have developed from occupational exposure at two plants of a semiconductor company from 2007 to 2010. This study evaluated the possibility of exposure to carcinogenic agents for the cases. Methods: Clinical courses were reviewed with assessing possible exposure to carcinogenic agents related to LHP cancers. Chemicals used at six major semiconductor companies in Korea were reviewed. Airborne monitoring for chemicals, including benzene, was conducted and the ionizing radiation dose was measured from 2008 to 2010. Results: The latency of seven cases (five leukemiae, a Non-Hodgkin's lymphoma, and an aplastic anemia) ranged from 16 months to 15 years and 5 months. Most chemical measurements were at levels of less than 10% of the Korean Occupational Exposure Limit value. No carcinogens related to LHP cancers were used or detected. Complete-shielded radiation-generating devices were used, but the ionizing radiation doses were 0.20-0.22 uSv/hr (background level: 0.21 ${\mu}Sv/hr$). Airborne benzene was detected at 0.31 ppb when the detection limit was lowered as low as possible. Ethylene oxide and formaldehyde were not found in the cases' processes, while these two were determined to be among the 263 chemicals in the list that was used at the six semiconductor companies at levels lower than 0.1%. Exposures occurring before 2002 could not be assessed because of the lack of information. Conclusion: Considering the possibility of exposure to carcinogenic agents, we could not find any convincing evidence for occupational exposure in all investigated cases. However, further study is needed because the semiconductor industry is a newly developing one.

Changes of Strength and Stiffness of Freeze-Dried Bovine Cortical Bone according to Rehydration Time in Electrolyte Solution (동결건조한 소의 치밀골에서 전해질용액의 침지시간에 따른 Strength와 Stiffness의 변화)

  • 김남수;장세웅;김희은;정인성;최성진;최인혁
    • Journal of Veterinary Clinics
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    • v.20 no.4
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    • pp.482-488
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    • 2003
  • Transplanted cortical bone grafts of freeze-dried bones also function as sustaining for defected bones, however, it has less strength and is fragile without rehydration. In this study, strength and stiffness of freeze-dried bone from bovine cortical bones were evaluated by three point bending test according to different time frames such as rehydration times of 0.5, 3, 6, 12 and 24 hrs in electrolyte solution and was compared with those of frozen bones. The strength and stiffness of frozen bone were $264.4\pm36.7$ MPa, $17.0\pm1.5$ GPa, respectively. The strength and stiffness of freeze-dried bone which fat was removed by treatments of chloroform-methanol solutions for 6 days, then was freeze-dried at $-80^{\circ}C$ and sterilized with ethylene oxide gas, were $224.9\pm27.6$ MPa, $19.2\pm2.8$ GPa, respectively. The strength and stiffness of feeze-dried bone were decreased 15.0% and increased 13.2% than these of frozen bone, respectively. The strength and stiffness of freeze-dried bone rehydrated for 6 hrs were restored to 96.0% strength and 99.2% stiffness of frozen bone. The rehydration time of freeze-dried bone which had the highest strength and stiffness was six hours and three hours, respectively. The results of the mathematica program for the variation of the strength and stiffness showed 3 hours and 30 minutes of rehydration time in electrolyte solution for the best condition in the strength and stiffness which was adequate to treat freeze-dried cortical bone.

Effect of the Inert Ceramic Powder on the Electrical and Mechanical Properties of the Polymer Electrolytes (비활성 세라믹 분말이 고분자 전해질의 전기적, 기계적 특성에 미치는 영향)

  • Kim, Dong-Won;Park, Jung-Ki;Kim, Chang-Jung;No, Kwang-Soo
    • Korean Journal of Materials Research
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    • v.3 no.3
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    • pp.237-244
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    • 1993
  • The characteristics of composite polymer electrolytes obtained by adding a fine ceramic powder($\gamma-{LiAlO}_{2}$) with a diameter of $1{\mu}$m to a poly(ethylene oxide)/lithium trifluoromethane sulfonate (LiC$F_3$S$O_3$) complex are described in terms of morphological and mechanical behavior. The addition of uniformly dispersed ceramic powder greatly improves the electrical and mechanical properties of solid polymer electrolytes at ambient temperature. For the composite polymer electrolytes under this study, the optimum composition of the $\gamma-{LiAIO}_{2}$ in the composite for maximum ionic conductivity was found to be 20 wt%.

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Preparation and Properties of EPDM/Zinc Methacrylate Hybrid Composites (에틸렌 프로필렌 디엔 고무/메타크릴산아연 하이브리드 복합체의 제조와 물성에 관한 연구)

  • Chang, Young-Wook;Won, Jong-Hoon;Joo, Hyun-Seok
    • Elastomers and Composites
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    • v.40 no.1
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    • pp.59-65
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    • 2005
  • Zinc methacrylate(ZMA) was incorporated into ethylene-propylene diene rubber(EPDM) by direct mixing of the metal salt with the rubber or was in-situ prepared in the rubber matrix through neutralization reaction of zinc oxide(ZnO) and methacrylic acid(MAA). Tensile and tear tests showed that ZMA had a great reinforcing effect for the EPDM. It was also found that ZMA reinforced EPDM vulcanizates can retain their mechanical properties under thermo-oxidative aging. Moreover the incorporation of ZMA induces a substantial improvement in the adhesive strength of the EPDM onto aluminum substrate. The reinforcing effect and an enhancement in adhesion was greatly manifested when the ZMA is in-situ formed with an excess amount of ZnO. The extraordinary improvement in the properties is supposed to be related with the formation of ionic crosslink as well as the degree of dispersion or ZMA domain in the rubber matrix.

Microstructure Control and Upconversion Emission Improvement of Y2O3:Ho3+/Yb3+ Particles Prepared by Spray Pyrolysis

  • Bae, Chaehwan;Jung, Kyeong Youl
    • Current Optics and Photonics
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    • v.5 no.4
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    • pp.450-457
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    • 2021
  • Upconversion (UC) properties of Y2O3:Ho3+/Yb3+ spherical particles synthesized by spray pyrolysis were investigated by changing the dopant concentration and calcination temperature. Citric acid (CA), ethylene glycol (EG) and N, N-dimethylformamide (DMF) were used to control the microstructure of Y2O3:Ho3+/Yb3+ particles. In terms of achieving the highest UC green emission intensity, the optimal concentrations of Ho3+ and Yb3+ were found to be 0.3% and 3.0%, respectively. In addition, the UC intensity of Y2O3:Ho3+/Yb3+ showed a linear relationship with the crystallite size. The use of organic additives allows Y2O3:Ho3+/Yb3+ particles to have a spherical and dense structure, resulting in significantly reducing the surface area while maintaining high crystallinity. As a result, the UC emission intensity of Y2O3:Ho3+/Yb3+ particles having a dense structure showed the UC emission intensity about 3.8 times higher than that of hollow particles prepared without organic additives. From those results, when Y2O3:Ho3+/Yb3+ particles are prepared by the spray pyrolysis process, the use of the CA/EG/DMF mixtures as organic additives has been suggested as an effective way to substantially increase the UC emission intensity.