• Title/Summary/Keyword: Ethanol-water Mixture

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Pervaporation Separation of Water-Ethanol Mixture Using Crosslinked PVA/PSSA_MA/TEOS Hybrid Membranes (PVA/PSSA_MA/TEOS 막을 이용한 물/에탄올 계의 투과증발 분리)

  • Rhim, Ji-Won;Lee, Byung-Seong;Kim, Dae-Hoon;Yoon, Seok-Won;Im, Hyeon-Soo;Moon, Go-Young;Nam, Sang-Yong
    • Membrane Journal
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    • v.18 no.1
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    • pp.44-52
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    • 2008
  • Pervaporation separation for water-ethanol mixtures has been carried out using crosslinked poly(vinyl alcohol) (PVA) membranes with poly(styrene sulfonic acid-co-maleic acid) (PSSA_MA) and at which tetraethylorthosilicate (TEOS) was introduced. The concentration of PSSA_MA was fixed 7 wt% over PVA and the TEOS contents, 3, 5, and 7 wt%, were varied against PVA. The composition of the feed mixtures were 10, 20, 30 and 50 wt% of water in it. PVA/PSSA_MA/5 wt% TEOS membrane showed the separation factor, 1730 and the permeability, $16.3g/m^2{\cdot}hr$ for water : ethanol = 10 : 90 at $50^{\circ}C$.

Inhibitory Effect of Yam (Dioscorea batatas DECENE) Extracts on the Mutagenicity (돌연 변이원에 대한 마(Dioscorea batatas DECENE)추출물의 억제 효과)

  • 이임선;정세영;신창섭;구성자
    • Korean journal of food and cookery science
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    • v.11 no.4
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    • pp.351-355
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    • 1995
  • The inhibitory effects of methanol, ethanol, chloroform/ methanol and water extracts from natural and cultural yams on the mutagenicity in the cooked pork (broiled and panfried) and the chemically induced mutagen, sodium azide, benzo(a)pyrene and 2-aminofluorene were investigated using salmolla typhimurium TA 100. In the presence of the S9 mixture, ethanol extract from natural yam showed high inhibitory effect on the mutagenicity of the cooked pork. But benzo(a)pyrene, supposed to be produced in mutagen during cooking, did not show high inhibitory effect in same extract. Besids, the yam extract on the mutagenicity of the sodium azide without S9 mixture showed low inhibitory effect. However 2-aminoflourene with S9 mixture showed high inhibitory effect, 91.5%.

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Pervaporation Characteristics of Water/Ethanol Mixture through Hydrophilic Zeolite Membranes (친수성 제올라이트 분리막의 물/에탄올 투과증발 특성)

  • Ahn, Hyoseong;Lee, Hyeryeon;Lee, Yongtaek
    • Applied Chemistry for Engineering
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    • v.16 no.1
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    • pp.61-67
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    • 2005
  • Zeolite membranes show better thermal, mechanical, chemical stabilities than polymer membranes. Water was separated from water/ethanol mixtures by pervaporation using the NaA and the NaY zeolite membranes synthesized in our laboratory. The effects of concentration of ethanol at the feed side and temperature were studied on the permeation flux and separation factor of water. The separation factors obtained with the NaA zeolite membrane was found to be 1000 times higher than those obtained with the NaY. However, the water flux through the NaA zeolite membrane was observed to be lower than 1/2 of that through the NaY zeolite membrane.

Efficacy of Brown Seaweed Hot Water Extract Against Hcl-ethanol Induced Gastric Mucosal Injury in Rats

  • Raghavendran Hanumantha Rao Balaji;Sathivel Arumugam;Devaki Thiruvengadam
    • Archives of Pharmacal Research
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    • v.27 no.4
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    • pp.449-453
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    • 2004
  • Effect of pre-treatment with hot water extract of marine brown alga Sargassum polycystum C.Ag. (100 mg/kg body wt, orally for period of 15 days) on HCI-ethanol (150 mM of HCI-etha-not mixture containing 0.15 N HCI in $70\%$ v/v ethanol given orally) induced gastric mucosal injury in rats was examined with respect to lipid peroxides, antioxidant enzyme status, acid/pepsin and glycoproteins in the gastric mucosa. The levels of lipid peroxides of gastric mucosa and volume, acidity of the gastric juice were increased with decreased levels of antioxidant enzymes and glycoproteins were observed in HCI-ethanol induced rats. The rats pre-treated with seaweed extract prior to HCI-ethanol induction reversed the depleted levels of antioxidant enzymes and reduced the elevated levels of lipid peroxides when compared with HCI-ethanol induced rats. The levels of glycoproteins and alterations in the gastric juice were also maintained at near normal levels in rats pre-treated with seaweed extract. The rats given seaweed extract alone did not show any toxicity, which was confirmed by histopathological studies. These results suggest that the seaweed extract contains some anti-ulcer agents, which may maintain the volume/acidity of gastric juice and improve the gastric mucosa antioxidant defense system against HCI-ethanol induced gastric mucosal injury in rats.

Antibacterial and Antioxidative Activity of Roasted Coffee and Red Ginseng Mixture Extracts (로스팅 커피와 홍삼 혼합추출물의 항균 및 항산화 효과)

  • Choi, Yu-Hyun;Kim, Sang-Eun;Huh, Jin;Han, Yeong-Hwan;Lee, Moon-Jo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.3
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    • pp.320-326
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    • 2012
  • This study was conducted to investigate the antibacterial and antioxidative activities of water and ethanol extracts from a mixture of roasted coffee and red ginseng. The antibacterial effects of each extract were determined by the classical paper disc method. A water extract of mixture samples inhibited growth of all strains, but antibacterial effects were mostly weakened. Ethanol extracts showed stronger antibacterial effects than water extracts in all strains except Gram negative Escherichia coli and the fungi strain Candida albicans. Also, the antibacterial effect of the Bacillus cereus strain appeared in all samples, and the ES2 sample formed a clear zone of 19 and 20 mm against Pseudomonas aeruginosa and S. Typhimurium respectively (MIC=0.25 and 0.125 mg/mL). Determinations of free radical elimination for the different mixture extracts using 1,1-diphenyl-2-picrylhydrazyl (DPPH) were compared with ascorbic acid and butylated hyderoxytoluene as positive controls. The water and ethanol extracts of mixture samples (100 ${\mu}g/mL$) showed 55.38~60.01% and 59.37~70.50% DPPH scavenging activities, respectively. DPPH scavenging activities of all mixture samples were slightly higher than roasted coffee and red ginseng samples. However, DPPH scavenging activity decreased when red ginseng extract composed more than 70% of the total extract. The total polyphenol in the mixture samples measured by the Folin-Denis method revealed the highest level of polyphenol content in ethanol extract of sample 3, whereas polyphenol content differed with different mixture ratios, ranging from 105.16~119.79 mg/g in ethanol extract. In the water extract, the polyphenol content was greatest with water extract of sample 1, whereas in other samples the content varied from 93.75~109.18 mg/g.

Solubilization of Alcohols in Aqueous Solution of Cetylpyridinium Chloride

  • Chung Jong Jae;Lee Sang Wook;Kim Young Chul
    • Bulletin of the Korean Chemical Society
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    • v.13 no.6
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    • pp.647-649
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    • 1992
  • The critical micelle concentration (CMC) values of cetylpyridinium chloride (CPC) in some alcohol-aqueous solutions were determined by UV-Vis spectroscopy at 25$25^{\circ}C$. The CMC of CPC was increased with the addition of methanol and ethanol, while with the addition of propanol it was decreased because of the solubilization of propanol into the micelle of CPC. The ratio (${\beta}$) of the number of counterions to that of surfactant ions associated into micelles in alcohol (methanol, ethanol and propanol) aqueous solutions was measured by using the Shinoda $equation^{17}$. The ratio of counterion binding to the CPC micelles in methanol-and ethanol-water mixtures was larger than in pure water, while the ratio in propanol-water mixture might be much decreased.

An Experimental Study of a Heat pipe with Binary Mixture Working Fluid for Solar Collector (2 성분 혼합물을 작동유체로 사용하는 태양열 집열기용 히트파이프의 실험적 연구)

  • Jung, Eui-Guk;Boo, Joon-Hong;Chung, Won-Bok
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.13-18
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    • 2003
  • Heat pipes with binary mixture fabricated and tested for applications where condenser temperature is in a range of $10^{\circ}C$ to $130^{\circ}C$. The pipe materials 8.0 mm O.D. cupper tube and the working fluids are ethanol-water mixtures. The total length of test of the heat pipe was 1710mm in which evaporator section was 1570mm, adiabatic section was 50mm and condenser section was 90mm. Mixing ratios of ethanol and water could be variable in mole fraction. Temperature of condenser section was $10^{\circ}C$, $80^{\circ}C$ and $130^{\circ}C$. Heat pipe performance experimental study was accomplished with change of mixing ratio in these temperatures. The fill charge ratio was 20% of the heat pipe volume. Wick structure was woven-wire and method of experimental work was that thermal load was increased 20W step until the heat pipe wall temperature reached at $150^{\circ}C$. Results were following: At coolant $10^{\circ}C$ and $130^{\circ}C$, mixing ratio that have beat thermal performance was 0.8M+ and at coolant $80^{\circ}C$, was 0.3 ${\sim}$ 0.5 M+.

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Corn Straw as Substrate for Producing Ethanol by Solid-State-Fermentation

  • Dong, Yong-Sheng;Qiao, Chang-Sheng;Wang, Rui-Ming;Wang, Li-Yan;Jia, Shi-Ru
    • Proceedings of the Korean Society for Applied Microbiology Conference
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    • 2005.06a
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    • pp.204-211
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    • 2005
  • The technology of Solid-State-Fermentation (SSF) with corn straw by Pichia ohmeri T021 was studied in this article. After being crushed, the corn straw powder was added into vitriol solutions to hydrolysis, which the quality proportion of corn straw: water: vitriol (98%) is 20:80:1. The mixtures was incubated at 120$^{\circ}C$ for 1 hour, and the hydrolysis rate reached 19%. Following, the mixture was adjusted to pH 4.5 by sodium carbonate and added cellulase (25IFPU/g). The hydrolysis rate reached 15% after the mixture was incubated at 50$^{\circ}C$ for 25h. The mixture which hydrolysed by vitriol was inoculated by Pichia ohmeri T021 (5${\times}10^7$cell/g) and added cellulase (25 IFPU/g) at the same time. The ethanol yield reached 2.99g per 100 gram substrate after the fermenting grains was incubated at 33$^{\circ}C$, pH 4.5 for 5 days.

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Dehydration of Alcohol Solutions Through Crosslinked Chitosan Composite Membranes III. Effects of Substrate, Neutralization and Active Layer Thickness on Pervaporation of Water/Ethanol Mixture (가교키토산 복합막을 통한 알콜수용액의 탈수 III. 화학가교시 지지체, 중화에 의한 효과와 이온가교시 활성층두께 변화에 의한 효과)

  • 이영무;남상용;유제강;류경옥
    • Membrane Journal
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    • v.6 no.4
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    • pp.250-257
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    • 1996
  • Surface crosslinked chitosan composite membranes were prepared with glutaraldehyde and surfuric acid. Effects of neutralization for complex between chitosan and acetic acid and of water permeability for substrate membranes on pervaporation performance were investigated. For ionically crosskinked membranes, effect of active layer thickness on separation factor of water/ethanol mixture was studied. With increasing the water permeability of the substrate, the membrane showed an increased separation factor, while it maintained a constant permeate flux. Neutralized chitosan composite membranes revealed a decreased separation factor and a constant permeate flux. When the thickness of the active layer increased, an optimum crosslinking time to achieve higher separation factor shifted to a prolonged times.

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A Model for Predicting the Density of Glycerol Water Mixture, and Its Applicability to Other Alcohol Water Mixture

  • Liu, Tianhao;Lee, Seung Hwan;Lim, Jong Kuk
    • Journal of Integrative Natural Science
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    • v.14 no.3
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    • pp.99-106
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    • 2021
  • A mixture of alcohol and water is commonly used as antifreeze, liquor, and the fundamental solvents for the manufacture of cosmetics, pharmaceuticals, and inks in our daily life. Since various properties of alcohol water mixtures such as density, boiling or melting point, viscosity, and dielectric constant are determined by their mixing ratio, it is very important to know the mixing ratio to predict their properties. One of simple method to find the mixing ratio is measuring the density of the mixtures. However, it is not easy to predict the mixing ratio from the density of the mixtures because the relationship between mixing ratio and density has not been established well. The relationship is dependent on the relative sizes of solute and solvent molecules, and their interactions. Recently, an empirical model to predict the density of glycerol water mixture from their mixing ratio has been introduced. The suggested model is simple but quite accurate for glycerol water mixture. In this article, we investigated the applicability of this model to different alcohol water mixtures. Densities for six different alcohol water mixtures containing various alcohols (e.g., ethylene glycol, 1,3-propane diol, propylene glycol, methanol, ethanol, and 1-propanol) were simulated and compared to experimentally measured ones to investigate the applicability of the model proposed for glycerol water mixtures to other alcohol water mixtures. The model predicted the actual density of all alcohol water mixtures tested in this article with high accuracy at various ratios. This model can probably be used to predict the mixing ratio of other alcohol water mixtures from their densities beyond 6 alcohols tested in this article from their densities.