• Title/Summary/Keyword: Erosion/Corrosion

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Investigation on electrochemical performance of Al anode material for marine growth prevention system

  • Kim, Seong-Jong;Jang, Seok-Ki;Han, Min-Su;Lee, Seung-Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.8
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    • pp.968-973
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    • 2014
  • Aluminum anode of marine growth prevention system for ship is installed in seachest or sea water strainer. The Al anode is connected to a control panel that feeds a current to the anode. The dissolved ions produced by the anode are transferred in sea water, spreads through the sea water pipe system and creates a protective film in the pipelines. Thereby, corrosion in pipeline system significantly is reduced. In application on condition as a steel ship, the big accident can be caused by the corrosion. Accordingly, in this research, we evaluated influence of applied current and flow velocity on electrochemical characteristics of Al anode for marine growth prevention system (MGPS). Based on the results of the erosion-cavitation experiments, cavitation rate increased greatly until 120 min. of the experimental time and decreased a little at the point of 180 min. where pit grew and merging occurred but showed a tendency of steadily increasing consumption rates. Based on the results of the Tafel analysis, compared to static states, corrosion current densities show a rapidly increasing tendency when flow occurred.

A Study on the Influence of Al Alloy Sacrificial Anode Efficiency due to Marine Environmental Variation (해양환경 변화가 알루미늄합금 희생양극의 효율에 미치는 영향에 관한 연구)

  • 김도형
    • Journal of Ocean Engineering and Technology
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    • v.14 no.2
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    • pp.106-111
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    • 2000
  • Recently it was reported that the life of Al Sacrifical anode is being used in port piers has been significantly shortened compared with the original design life (e.g. average life shortened from 20 years to 13-15 year) Those factors involving these problems mentioned above were seemed to be a quality of anode material and diverse environmental factors such as pH flow rate temperature Dissolved oxygen Chemical oxygen demand and resistivity etcm In this study flow rate and contamination degree(pH) of sea water affecting to sacrificial anode life hve been investigated in terms of electrochemical characteristics of Al alloy sacrificial anode It was known that the lifetime of Al alloy anode was shortened not only by increasing of self-corrosion quantity by varying flow rate of sea water but also by increasing corrosion current density due to the potential difference increment between Al anode and steel structure cathode by varying contamination degree of sea water. Especially when anode current density is from 1mA/cm2 to 3mA/cm2 and flow rate of sea water is under 2m/s anode current efficiency is 90% above However flow rate is over 2m/s anode current efficiency fell down sharply due to erosion corrosion as well as galvanic corrosion.

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Numerical simulations on flow and particle behaviors in the upper part of a syngas cooler for IGCC (IGCC 합성가스 냉각기 상부의 열유동 및 입자거동 특성에 대한 전산해석 연구)

  • Park, Sangbin;Ye, Insoo;Ryu, Changkook;Kim, Bongkeun
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.147-148
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    • 2012
  • The syngas produced from coal gasification is cooled down for gas cleaning by a syngas cooler that produces steam. Due to the presence of fly slag in the syngas, erosion, slagging and corrosion especially in the upper part of the syngas cooler may cause major operational problems. This study investigates the flow, heat transfer and particle behaviors in the syngas cooler of a 300MWe IGCC plant by using computational fluid dynamics. For various operational loads and geometry, the gas and particle flows directly impinged on the wall opposite to the syngas inlet, which may lead to erosion of the membrane wall. In the evaporate channels inside the syngas cololr, the particle flows were concentrated more on the outer channel where slagging becomes more serious. The heat transfer to the wall was mainly by convection which was larger on the side wall below the inlet level.

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A Study on The Corrosion Appearance of Mortar by The Sulfuric-Acid for Some Kinds of Cements (각종 시멘트의 황산에 의한 모르타르의 침식현상에 관한 연구)

  • 이웅종;정연식;김동석;양승규;유재상;이종열
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.281-286
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    • 2003
  • This study presents the results of investigations with the object to determine the resistance to sulfuric acid for some kinds of cements containing 0%-70% of slag powder. The specimen is immersed 5% H$_2$SO$_4$ solution after the 28th days, is measured chemical analysis, XRD, SEM and etc after the immersed 35th days and is measured the erosion depth after the immersed 168th days. The results of experiment are founded out that alumina cement containing slag power was excellent at a point of view for the sulfuric acid resistance and the erosion depth was suitable to the evaluated method of the sulfuric acid resistance in the stead of the evaluated method of weight loss.

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A study on the behaviour of cavltation eroslon atalloy metals of slide bearing for internal combustion engine (내연기간용 슬라이드 베어링 합금재의 캐비테이션 침식겅동에 관한 연구)

  • 임우조;안석환;이진열
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1992.11a
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    • pp.44-49
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    • 1992
  • 액체를 취급하는 기계.장치는 유속 및 회전속도 등이 빠르게 되면 유체충격과 정압의 저하에 따른 국부적 비등으로 인해 캐비테이션(cavitation) 현상이 발생한다. 이러한 캐비테이션현상에 따른 소음과 진동율 초래하고, 또한 기포의 붕괴에 따른 형격압으로 캐비테이션-침식(cavitation-erosion)이 발생하여 기계.장치의 구성재료에 손실이 일어남으로써 이들 기계의 효율을 저하시킴과 아울러 수명을 단종시킬 수 있다. 더욱이 부식성의 액체에 사용되는 기계.장치의 금속재료에는 캐비테이션(erosion-corrosion)이 중첩하여 발생하는 경우는 침식과 부식이 상호간에 가속하는 상승효과 때문에 기계.장치의 수명에 치명적인 영향을 미친다. 따라서 본 연구에서는 초음파 진동장치에 의한 각종 유중에서 베어링 합금 1종, 7종 및 켈-멧 4종에 대한 캐비테이션-침식실험을 실시하여, 침식손상거동및 특성등을 구명하고저 하였다.

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Analysis of Pipe Failure Period Using Pipe Elbow Erosion Model by Computational Fluid Dynamics (CFD) (전산유체역학 배관 곡면 침식 모사를 통한 배관 실패 주기 분석)

  • Nam, Chongyong;Lee, Yongkyu;Park, Gunhee;Lee, Gunhak;Lee, Won Bo
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.133-138
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    • 2018
  • Safety management has become even more important because of the safety and environmental issues that have arisen since the 2000s. However, the safety study requires many empirical data, so there are many limitations. In the case of pipe safety, simulation programs exist, but it is difficult to get data about the pipe internal erosion of the pipe. In this study, the erosion rate of the pipe elbow was simulated using computational fluid dynamics (CFD). Also, the failure period of the pipe was calculated by the limit state function using erosion rate. In the case of CFD pipe, a sample which is actually operated in Yeosu industrial complex was used, and the geometry and mesh formation were rationalized in terms of typical fluid dynamics simulations. Using the Discrete Phase Model (DPM) and the corrosion model, the erosion rate ($3.09227mm{\cdot}yr^{-1}$) was obtained from CFD simulations. As a result of applying the erosion rate to the limit state function, we obtained the pipe failure period value, 14.2 years to trigger a leak and 28.2 years to trigger a burst. Through these processes, we concluded that pipe erosion is one of the major failure modes. In addition to the results, this study has significance for suggesting the methodology of the pipe safety study.

Corrosion and Materials Selection for Bitumen with Heavy Naphthenic Acid in Canadian Oil Sands

  • Eun, Thomas Jung-Chul
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.350-361
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    • 2008
  • Canada's oil sands contain one of the largest reserves of oil in the world. According to recent estimates, there are nearly 180 billion barrels of oil in the Canadian oil sands trapped in a complex mixture of sand, water and clay. More than 40 companies have been currently operating or developing oil sands facilities since the first production in 1967. The process of oil sands upgrading is similar with down stream refinery, but the corrosion environment in upgrading refinery is often more severe than in the refinery because of high chlorides, mineral contents, carbonic acid, heavy viscosity and fouling, higher naphthenic acid [$NA-R(CH_{2})nCOOH$], and greater sulfur contents. Naphthenic acid corrosion (NAC) which is one of the most critical corrosion issues in up & downstream refinery plants was observed for the first time in 1920's in refinery distillation processes of Rumania, Azerbaizan (Baku), Venezuela, and California. As a first API report, the 11th annual meeting stated sources and mechanism of NAC in early 1930's. API has been developing the risk base standards, such as API RP580, 571, and Publication 581 which are based on the worst NAC damage in the world since 2000. Nevertheless not only the NAC phenomena and control in Canadian sands oil process are not much widely known but also there are still no engineering guidances for the Canadian sands oil in API standards. This paper will give NAC phenomina and materials selection guidance against NA environment in Canadian oil sands upgrading processes.

Uniaxial Compressive Strength Characteristic of Shotcrete Immersed in Chemical Solution (화학적 침식에 의한 숏크리트의 압축강도 특성)

  • Lee, Gyu-Phil;Kim, Dong-Gyou;Bae, Gyu-Jin;Kim, Hong-Sam
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.1291-1298
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    • 2005
  • Shotcrete for the support of tunnel can contact with groundwater. The hazardous components in the groundwater cause the corrosion of shotcrete. Also, the hazardous components may deteriorate the engineering properties of shotcrete, such as compressive strength, bond strength, and flexural strength. The more the effect of the hazardous components on the shotcrete may increase, the more the stability of tunnel structure may decrease. It was analyzed to find the hazardous components in the ground water. The uniaxial compressive strength test, XRD, SEM were conducted to evaluate the durability and corrosion of shotcrete. These tests were performed on shotcrete specimens at 2, 4, 8, and 16 weeks. The specimens were immersed in various chemical solutions including hazardous components after the specimens were made at the construction site.

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The Investigation of the Plasma Sprayed Coatings for the Application of OG Cooling Tube in Steel Making Plant

  • Kim, HyungJun;Kwon, YoungGak
    • Corrosion Science and Technology
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    • v.4 no.1
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    • pp.23-28
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    • 2005
  • Several plasma-sprayed ceramic coatings with two- and three-layers were characterized and tested for the application of cooling tube coatings of oxygen convert gas recovery system (OG cooling system) in the steel making plant. Thermal cycling tests using a torch heating with compressed air cooling were carried out and characterized before and after the tests. The effects of metallic bond coat as well as ceramic top coat were also studied. Possible failure mechanisms with low carbon steel substrate were assessed in term of microstructure, porosity, bond strength, thermal expansion coefficient, and the phase transformation. Finally, the results of field tests at the OG cooling system are presented and discussed their microstructural degradation. Test results have shown that three-layered coatings perform better than two-layered coatings.

Economic Analysis of Installing Fixed and Removable Insulation for Pipe Wall Thinning Management (배관감육 관리를 위한 고정식 및 탈착식 보온재 설치 경제성 분석)

  • Hwang, Kyeongmo;Yun, Hun
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.320-325
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    • 2016
  • To perform ultrasonic testing (UT) thickness measurement of the secondary side piping installed in nuclear power plants, the insulation for preventing heat loss should be removed. The type of insulation can be divided into fixed and removable insulation. Fixed and removable insulation have their own strengths and weaknesses. Removable insulation has been installed in the components susceptible to wall thinning caused by FAC and erosion from Shin-Kori unit 1, which commenced its commercial operation in 2011. In this paper, the number of repeated inspections of components and the number of replacements of fixed insulation were estimated and a more economical way was identified based on the manufacturing and installation costs for fixed and removable insulation.