• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.75-81
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• 2003

In this paper, the study of effects of flow variables on flame structure and NOx emission concentration was performed in co-axial laminar partially premixed methane/air flames. the objectives are to reveal its effect as parameters were varied and to understand the correlation between flame structure and NOx emission characteristics in the reaction zone. equivalence ratio(${\Phi}$), fuel split degree(${\sigma}$), and mixing distance(x/D) were defined as a premixing degree and varied within $1.36{\sim}3.17$(equivalence ratio), $50{\sim}100$(fuel split degree), and $5{\sim}20$(mixing distance). the image of $OH{\ast}$ and $CH{\ast}$, and NOx concentration were obtained with an ICCD camera and a NOx analyzer. additionally the maximum intensity location of $OH{\ast}$ chemiluminescence and $CH{\ast}$ chemiluminescence were measured to compare each flame structures. In conclusion flame structure and NOx emission characteristics were changed from diffused to premixed flame when mixing degree was on the increase. the main effect on flame structure and NOx production was at first equivalence ratio(${\Phi}$), and next fuel split degree(${\sigma}$), and finally mixing distance(x/D).

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.31-36
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• 2007

The supersonic combustion experiments are carried out using T3 free-piston shock tunnel. Hydrogen Fuel is injected in the cavity parallel with air(or nitrogen fuel) flow. The equivalence ratios in this study are 0.132 and 0.447. Experimental measurements use OH-PLIF near the cavity and pressures in the combustor. For parallel fuel injection case, direct fuel add into cavity leads to increase of cavity pressure. And Flame exists just near the bottom wall for low equivalent ratio. There is no flame in the cavity because of no mixing in it. Compared to the inclined fuel injection, ignition delay length is longer for low equivalence ratio in both case. OH distribution is not a single line but a repeatable fluctuation flame structure by turbulence. Pressure distributions have nothing to do with the fuel injection position.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.54-59
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• 2001

OH radical concentration have been measured in a methane-air partially premixed flames using PLIF. Excitation lines were selected $Q_{1}(6)$ branch, (1,0) band. The system is consisted of Nd:YAG laser, dye laser and frequency doubler to make pump beam for OH radical. On the direct photographs, flame height increases as fuel flow rate and equivalence ratio increase. And on the PLIF images, OH radical is distributed from premixed flame front to nonpremixed flame front through the flame structure with all equivalence ratio. OH overall concentrations increase with equivalence ratio. At the stoichiometric equivalence ratio, the peak of OH radical concentration exists strongly near the inner cone. As equivalence ratio is changed to richer, OH radical distribution goes thinly and the peak is increased as longitudinal direction. As the flow goes to the downstream, OH radical concentration decreases and broadens, because OH radical reacts with another species after OH formation at the initial oxidization. This phenomenon resembles radial distribution. At the l00cc fuel flowrate, the radial peak of OH radical exists from x/R=l.0 to 1.5.

• Journal of the Korean Society of Combustion
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• v.12 no.2
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• pp.20-25
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• 2007

The supersonic combustion experiments are carried out using T3 free-piston shock tunnel. Hydrogen Fuel is injected in the cavity parallel with air(or nitrogen) flow. The equivalence ratios in this study are 0.132 and 0.447. Experimental measurements use OH-PLIF near the cavity and pressures in the combustor. For parallel fuel injection case, direct fuel add into cavity leads to increase of cavity pressure. And Flame exists just near the bottom wall for low equivalent ratio. There is no flame in the cavity because of no mixing in it. Compared to the inclined fuel injection, ignition delay length is longer for low equivalence ratio in both case. OH distribution is not a single line but a repeatable fluctuation flame structure by turbulence. Pressure distributions have nothing to do with the fuel injection position.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.7
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• pp.1022-1029
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• 1998

The relation of the inlet fuel distribution, velocity, and overall equivalence ratio to the stability of a lean burning no-swirl dump combustor was examined. Premixed or partially premixed natural gas was introduced into the air stream, which flowed to the dump region through an annular inlet pipe. Inlet air was preheated upto 400 deg.C. Combustion instability was observed to occur at higher value of equivalence ratio (> 0.6) as the degree of unpremixedness was increased. Instabilities exhibited a dominant frequency of ~ 500 Hz, which corresponded to a half wave mode of combustor. CH chemiluminescence and pressure fluctuations were in-phase when combustion instabilities occurred. Acetone LIF images revealed that there was a strong fuel concentration gradient across the inlet annulus. Phase resolved OH LIF images showed that inlet fuel distribution was affected by the combustion instabilities.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.103-108
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• 2003

The effect of equivalence ratio and fuel/air mixing quality on the phase-resolved gas temperatures at different phases of the oscillating pressure cycle was experimentally investigated. An atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane with heat release rate of 1.59kW was used. Temperature measurements were made using coherent anti-Stokes Raman spectroscopy (CARS) at several spatial locations for typical unstable combustion conditions. Analysis was conducted using parameters such as phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs). Also the probability on the occurrence of high temperature (over 1900K) was investigated to get the information on the perturbation of equivalence ratio and NOx emission characteristics. It was shown that most of temperature histograms exhibit Gaussian profile which has short breadth of temperature fluctuation at equivalence ratio of 0.6, while beta profile was predominant for the cases of other equivalence ratios (${\Phi}$=0.55, 0.50). The characteristics on the occurrence of high temperature also displayed periodic wave form which is very similar to the pressure signal. And the amplitude of this profile goes larger as the fuel/air mixing quality become poorer. These also provided additional information on the perturbation of equivalence ratio at flame as well as NOx emission characteristics.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.2
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• pp.19-26
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• 2000

This paper presents the effects of initial pressure of mixture on CO, $CO_2$ and NOx emissions in constant volume combustion chamber. The CO, $CO_2,O_2,N_2$ concentrations in the chamber are determined by thermal conductivity detection (Gas-chromatograph) wile the NOx concentration is measured by chemiluminescent detection (NOx Analyser). Methane-air mixture is used as premixed fuel and the measurements are taken with equivalence ratios($\phi$) varing from 0.6 to 1.3, and initial pressures of methane-air mixture varing from 0.1MPa to 0.8MPa in constant volume combustion chamber. The NOx concentration steadily increases with increasing equivalence ratio, peaks in lean flame ($\phi$=0.85~0.9), and then rapidly decreases. However, as the initial pressure of mixture is increased, the equivalence ratio corresponding to the point of peak [NOx] shifts towards leaner conditions. This is caused by a similar shift in the peak [CH], which is caused by the variation with pressure and equivalence ratio of the rate of CH production from $CH_2$ and OH. The maximum combustion pressure peaks at $\phi$ =1.05 and the $CO_2$ concentration peaks at $\phi$=0.95~1.0 while the CO concentration rises sharply at the condition of fuel-rich mixtures. This is caused by complete combustion at $\phi$=0.95.

• Journal of ILASS-Korea
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• v.2 no.4
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• pp.7-14
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• 1997

Laser Raman scattering method has been applied to measure equivalence ratio of methane/air mixture in injected spray. We used high power KrF excimer laser$(\lambda=248nm)$ and a high gain ICCD camera to capture low intensity signal. Raman shifts and Raman scattering cross -sections of $H_2,\;O_2,\;N_2,\;CO_2,\;CH_4\;and\;C_3H_8$ are measured precisely. Our results show an excellent agreement with those of other groups. Mole fraction measurement of $O_2\;and\;N_2$ from air shows that $O_2:N_2=0.206:0.794$. We used gas injector which was operated at 1 bar. Methane is used as a fuel. Spray region is $10mm\times37mm$ and this region is divided into 80 points. In Raman signals are obtained and ensemble averaged for each point. 3-d and contour plot of distribution of equuivalence ratio is presented. Our measured results show that the equivalence ratio of methane/air mixture in methane-rich region is reasonable. However, more study is necessary for methane-lean region because background noise level is almost same as Raman intensity of methane.

• Journal of ILASS-Korea
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• v.16 no.4
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• pp.167-175
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• 2011

The HCCI engines have been known with high efficiency and low pollution and can be actualized as the new internal combustion engines. However, As for(??) the ignition and combustion depend strongly on the oxidation reaction of the fuel, so it is difficult to control auto-ignition timing and combustion duration. Purpose of this paper is creating the database for development of multi-dimensional simulation and investigating the influence of different molecular structure. In this research, the effect of n-heptane mole ratio in fuel (XnH) on the ignition delay from homogeneous charge compression ignition(HCCI) has been investigated experimentally. By varying the XnH, it was possible to ascertain whether or not XnH is the main resource of ignition delay. Additionally, the information on equivalence ratio for varying XnH was obtained. The tests were performed on a RCM (Rapid Compression Machine) fueled with n-heptane and iso-octane. The results showed that decreasing XnH (100, 30, 20, 10,0), the ignition delays of low temperature reaction (tL) and high temperature reaction (tH) is longer. And the temperature of reaction increases by about 30K. n-heptane partial equivalence ratio (fnH) affect on tL.and TL. When ${\phi}$nH was increased as a certain value, tL was decreased and TL was increased.

• Journal of the Korean Society of Combustion
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• v.12 no.1
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• pp.11-20
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• 2007

The supersonic combustion experiments are carried out using T3 free-piston shock tunnel. Different shock tube fill pressures have various inflow conditions. $15^{\circ}$ inclined hydrogen fuel injection is located before the cavity. Oblique shock is generated from the cavity and reflects off the top and bottom wall. For non-reacting flow, fuel makes the shear layer thicker above the cavity therefore, the shock is generated just before the trailing edge. This research has self-ignition in the combustor. For reacting flow, as the equivalence ratio increases, flame starts to generate near the injector or occur in the recirculation zone before the injector. High fuel injection sustains the jet shape in the cross flow and air can mix with fuel along the shear layer. Therefore, two flame layers find above the cavity for high equivalence ratio.