• 대한화학회지
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• 제49권6호
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• pp.521-530
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• 2005

• 대한기계학회논문집B
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• 제26권10호
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• pp.1427-1435
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• 2002

The main aim of the present article is numerically to investigate the micro-scale heat transfer phenomena in a silicon microstructure irradiated by picosecond-to-femtosecond ultra-short laser pulses. Carrier-lattice non-equilibrium phenomena are simulated with a self-consistent numerical model based on Boltzmann transport theory to obtain the spatial and temporal evolutions of the lattice temperature, the carrier number density and its temperature. Especially, an equilibration time, after which carrier and lattice are in equilibrium, is newly introduced to quantify the time duration of non-equilibrium state. Significant increase in carrier temperature is observed for a few picosecond pulse laser, while the lattice temperature rise is relatively small with decreasing laser pulse width. It is also found that the laser fluence significantly affects the N 3 decaying rate of Auger recombination, the carrier temperature exhibits two peaks as a function of time due to Auger heating as well as direct laser heating of the carriers, and finally both laser fluence and pulse width play an important role in controlling the duration time of non-equilibrium between carrier and lattice.

• 대한교통학회지
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• 제24권5호
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• pp.135-142
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• 2006

교통류 이론에서 fundamental diagram이라고 불리는 교통량-밀도 관계는 stationary 상태에서의 교통량과 밀도사이의 평형관계 (equilibrium relation)를 나타낸다 본 연구에서는 개별차량 데이터를 이용하여 교통량-밀도 관계의 전제조건인 stationary 조건을 만족하는 데이터를 추출하는 방법을 제시하였고, stationary 조건을 만족하는 데이터를 교통량-밀도 평면에 도시하였다. 개별차량의 흐름이 자유교통류상태와 혼잡교통류상태에서 상이하며 지점에서 관측된 데이터가 서로 다른 특성의 시계열특성을 보인다는 점에 근거하여 두 가지 상태에 따라 서로 다른 stationary조건을 제시하였다. 본 논문에서 제시된 stationary 조건을 실제로 관측된 데이터에 적용한 결과 자유교통류상태의 stationary조건을 만족하는 데이터는 현재까지 알려진 바와 같이 교통류-밀도 관계의 왼쪽가지에 위치하고. 혼잡교통류상태의 stationary조건을 만족하는 데이터는 교통류-밀도관계의 오른쪽 가지에 위치한다. 또한 본 연구에서 제시된 방법론에 따라 교통류-밀도관계의 전범위에 걸쳐 stationary조건을 만족하는 데이터를 구별하여 교통류-밀도평면에 도시한 결과 교통류의 거의 전영역에 걸쳐 재현 가능한 관계가 나타나는 것을 확인할 수 있었다.

• 한국환경보건학회지
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• 제27권1호
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• pp.83-87
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• 2001

In this study, the characteristics of lead removal by PVA and alginate bead which used widely as immobilizing agents were investigated, and the difference of removal amounts between pure PVA/alginate bead and Sargassum thunbergii immobilized bead was studied. All PVA beads, pure and S. thunbergii immobilized, reached an equilibrium state in about 1 hour, and S. thunbergii immobilized bead adsorbed more lead than pure one. But in the case of alginate beads, they needed much time, about 5 hours, to reach an equilibrium state, and adsorbed lead four times higher than PVA beads. Therefore, it was considered that alginate beads had more mass transfer resistance and function groups which adsorb lead such as hydroxyl, carboxyl and etc. than PVA bead. To examine the continuous usage of alginate beads, the process of adsorption/desorption of lead was conducted repeatedly. As the process proceeded, the amounts of lead adsorption decrease, so it was indicated that the non-desorbed lead from alginate bead at first adsorption/desorption process remained constantly.

• 대한기계학회논문집A
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• 제25권12호
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• pp.2056-2061
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• 2001

Non-proportional loading tests of Nylon 66 at room temperature exhibit path dependent behavior and plasticity-relaxation interactions. The uniaxial formulation of the viscoplasticity theory based on overstress (VBO), which has been used to reproduce the nonlinear strain rate sensitivity, relaxation, significant recovery and cyclic softening behaviors of Nylon 66, is extended to three-dimensions to predict the response in strain-controlled, comer-path tests. VBO consists of a flow law that is easily written for either the stress or the strain as the independent variable. The flow law depends on the overstress, the difference between the stress and the equilibrium stress that is a state variable in VBO. The evolution law of the equilibrium stress in turn contains two additional state variables, the kinematic stress and the isotropic stress. The simulations show that the constitutive model is competent at modeling the deformation behavior of Nylon 66 and other solid polymers.

• 대한전기학회논문지
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• 제35권2호
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• pp.67-76
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• 1986

It is observed that an appreciable short-circuit current (Is) flows by the time variation of temperature without applying external field in M1(metal)-P(polymer)-M2(metal)system. In M1-P-M2(A1) system, Is flows in the direction from the electrode(A1) having a lower workfunction to the counter electrode(M1) during heating and its magnitude increases as the thickness of polymer is decreased and as the heating rate is raised. The sign of Is is reversed in lower temperature region (under glass transition temperature) when the direction of temerature variation is changed during heating and cooling. From these experimental results, we can sugest that Is flows in the external short-circuit during the space charge distribution formed around both interfacial surfaces (M1-P and P-M2) is continuously maintained in the non-equilibrium state but not in equilibrium state.

• 한국세라믹학회지
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• 제48권2호
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• pp.117-120
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• 2011

In this study, the redox state of iron in sodium silicate glasses was varied by changing the melting conditions, such as the melting temperature and particle size of iron oxide. The oxidation states of the iron ion were determined by wet chemical analysis and UV-Vis spectroscopy methods. Iron commonly exists as an equilibrium mixture of ferrous ions, $Fe^{2+}$, and ferric ions $Fe^{3+}$. In this study, sodium silicate glasses containing nanoparticles of iron oxide (0.5% mol) were prepared at various temperatures. Increase of temperature led to the transformation of ferric ions to ferrous ions, and the intensity of the ferrous peak in 1050 nm increased. Nanoparticle iron oxide caused fewer ferrous ions to be formed and the $\frac{Fe^{2+}}{Fe^{3+}}$ equilibrium ratio compared to that with micro-oxide iron powder was lower.

• 대한기계학회논문집B
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• 제29권1호
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• pp.159-168
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• 2005

In recent studies, it was reported that there existed the temperature discontinuity at a liquid-vapor interface in an equilibrium state. However, from the viewpoint of the classical thermodynamics, it is highly questionable result although considering that the experiments related with a boundary layer is very difficult due to the extremely thin thickness of it. To clarify whether the temperature discontinuity over a liquid-vapor interface really exists, the computer simulations were performed. From the simulation results, it could be concluded that the misconception in a temperature calculation might result in non-uniform temperature distributions over an interface under an equilibrium state.

• 대한전기학회논문지:전력기술부문A
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• 제52권11호
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• pp.668-674
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• 2003

The electric marketplace is in the midst of major changes designed to promote competition. No longer vertically integrated with guaranteed customers and suppliers, electric generators and distributors will have to compete to sell and buy electricity. Unit commitment (UC) in such a competitive environment is not the same as the traditional one anymore. The objective of UC is not to minimize production cost as before but to find the solution that produces a maximum profit for a generation firm. This paper presents a hi-level formulation that decomposes the UC game into a generation-decision game (first level game) and a state(on/off)-decision game (second level game). Derivation that the first-level game has a pure Cournot Nash equilibrium(NE) helps to solve the second-level game. In case of having a mixed NE in the second-level game, this paper chooses a pure strategy having maximum probability in the mixed strategy in order to obviate the probabilistic on/off state which may be infeasible. Simulation results shows that proposed method gives the adequate UC solutions corresponding to a NE.

• Macromolecular Research
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• 제11권1호
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• pp.53-61
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• 2003

A molecular-thermodynamic model is developed for the salt-induced protein precipitation. The protein molecules interact through four intermolecular potentials. An equation of state is derived based on the statistical mechanical perturbation theory with the modified Chiew's equation for the fluid phase, Young's equation for the solid phase as the reference system and a perturbation based on the protein-protein effective two body potential. The equation of state provides an expression for the chemical potential of the protein. In a single protein system, the phase separation is represented by fluid-fluid equilibria. The precipitation behaviors are simulated with the partition coefficient at various salt concentrations and degree of pre-aggregation effect for the protein particles. In a binary protein system, we regard the system as a fluid-solid phase equilibrium. At equilibrium, we compute the reduced osmotic pressure-composition diagram in the diverse protein size difference and salt concentrations.