• Title/Summary/Keyword: Equilibrium Distribution

Search Result 620, Processing Time 0.033 seconds

Monte Carlo Simulation for Vapor-Liquid Equilibrium of Binary Mixtures CO2/CH3OHCO2/C2 H5OH, and CO2/CH3CH2CH2OH

  • Moon, Sung-Doo
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.6
    • /
    • pp.811-817
    • /
    • 2002
  • Gibbs ensemble Monte Carlo simulations were performed to calculate the vapor-liquid coexistence properties for the binary mixtures $CO_2/CH_3OH$, $CO_2/C_2H_5OH$, and $CO_2/CH_3CH_2CH_2OH.$ The configurational bias Monte Carlo method was used in the simulation of alcohol. Density of the mixture, composition of the mixture, the pressure-composition diagram, and the radial distribution function were calculated at vapor-liquid equilibrium. The composition and the density of both vapor and liquid from simulation agree considerably well with the experimental values over a wide range of pressures. The radial distribution functions in the liquid mixtures show that $CO_2$ molecules interact more stogly with methyl group than methylene group of $C_2H_5OH$ and $CH_3CH_2CH_2OH$ due to the steric effects of the alcohol molecules.

A study on the physical behavior of arc plasmas in transferred-type Torch (이행형 토치에서의 아크 플라즈마의 물리적 거동에 관한 연구)

  • 김외동;고광철;강형부
    • The Transactions of the Korean Institute of Electrical Engineers
    • /
    • v.45 no.3
    • /
    • pp.415-425
    • /
    • 1996
  • This study presents an analytical method of solving the behaviors of arc plasma in a nozzle constricting transferred-type torch and purposes to obtain the basic data for the design of a plasma torch, which can be obtained from the temperature, pressure, velocities and voltage distributions. We have to solve some conservation equations simultaneously and need to know the exact thermal gas properties in order to obtain the correct behaviors of arc plasma. It is also necessary to give the relevant physical or geometric boundary conditions. For the simplicity of analysis, we assumed that (a) the plasma flow is laminar, (b)the local thermodynamic equilibrium, i.e. LTE, prevails over the entire arc column region. The electrode sheath effects were neglected and the nozzle area was excluded from the analysis by assuming that the current flow into the nozzle is zero. We solved the momentum transfer equation including the self-magnetic pinch effect, and obtained the temperature distribution from the energy conservation equation. From this temperature, we could get arc voltage distribution. (author). refs., figs., tabs.

  • PDF

Probabilistic tunnel face stability analysis: A comparison between LEM and LAM

  • Pan, Qiujing;Chen, Zhiyu;Wu, Yimin;Dias, Daniel;Oreste, Pierpaolo
    • Geomechanics and Engineering
    • /
    • v.24 no.4
    • /
    • pp.399-406
    • /
    • 2021
  • It is a key issue in the tunnel design to evaluate the stability of the excavation face. Two efficient analytical models in the context of the limit equilibrium method (LEM) and the limit analysis method (LAM) are used to carry out the deterministic calculations of the safety factor. The safety factor obtained by these two models agrees well with that provided by the numerical modelling by FLAC 3D, but consuming less time. A simple probabilistic approach based on the Mote-Carlo Simulation technique which can quickly calculate the probability distribution of the safety factor was used to perform the probabilistic analysis on the tunnel face stability. Both the cumulative probabilistic distribution and the probability density function in terms of the safety factor were obtained. The obtained results show the effectiveness of this probabilistic approach in the tunnel design.

The Measurement of Dose Distribution in the Presence of Air Cavity and Underdosing Effect Result from Lack of Electronic Equilibrium (조사면내 공동의 존재에 따른 선량분포의 변화측정)

  • Jo, Jeong-Hui;Bang, Dong-Wan;Park, Jae-Il
    • The Journal of Korean Society for Radiation Therapy
    • /
    • v.8 no.1
    • /
    • pp.75-81
    • /
    • 1996
  • When high energy photon beam is incident upon an air cavity interface the effect of ionization build-up observed . This phenomenon is resulting from the surface layers of the lesions are significant deficiency of electrons reaching the layers because of the replacement, of solid scattering material by the air cavity, that is lack of electronic equilibrium. Measurement have been made in an acrylic phantom with a parallel plate chamber and high energy photon beams, CO-60, 4MV, 6MV and 10MV X-rays have been investigated. The result of our study show that a significant effect was measured and was determined to be very dependent on field size, air cavity dimension and photon energy. The reductions were much larger for 10MV beam, underdosage at the interface was 12, 12.2, 16.9 and $20.6\%$ for the CO-60, 4MV, 6MV and 10MV, respectively. It was found that this non-equilibrium effect at the interface is more severe for the higher energy beams than that of lower energy beams and the larger cavity dimensions the larger beam reductions occur. This problem is of clinical concern when lesions such as carcinoma beyond air cavities are irradiated, such as larynx, glottic and the patients with maxillectomy and ethmoidectomy and so forth.

  • PDF

Solvent Extraction of Nd from Chloride Solution with PC88A (염산용액에서 PC88A에 의한 Nd의 용매추출)

  • Lee Gwang-Seop;Lee Jin-Young;Kim Sung-Don;Kim Joon-Soo;Lee Man-Seung
    • Resources Recycling
    • /
    • v.13 no.4
    • /
    • pp.39-45
    • /
    • 2004
  • Solvent extraction experiments of Nd from chloride solution were studied with PC88A. Solvent extraction reaction of Nd with PC88A and the equilibrium constant were evaluated from the extraction experimental data and extraction conditions. Nd$aq^{3+}$ + 1.5 $H_2$$A_2$,org = $NdA_3$,org + 3H/sun $aq^{+}$ , K=0.25 The predicted distribution coefficients of Nd agreed well with the experimental results. The effect of saponification of PC88A on the extraction of Nd and on the change of equilibrium pH was investigated. Saponified PC88A present as a monomer in the organic reaction and enhanced the distribution coefficient of Nd. The initial extraction conditions had a great effect on the equilibrium pH.

타이밍 벨트구동에서 불완전 맞물림 이의 하중분포 해석

  • 김현수;여창기;이인환
    • Journal of the korean Society of Automotive Engineers
    • /
    • v.14 no.1
    • /
    • pp.54-63
    • /
    • 1992
  • Force distribution of incomplete meshing teeth for the OHC drive timing belt system is investigated analytically. Finite difference equations of the belt tension are derived based on the force equilibrium and the deformation of the belt tooth. From the numerical results, it is found that of the force distribution prior to the boundary point shows higher values compared with those of the complete meshing state and the force distribution after the boundary point shows lower values. Also, the magnitude of the incomplete meshing region increases as the rotational speed increases and the tight side belt tension decreases.

  • PDF

Some Partial Orderings of Life Distributions

  • Jeen-Kap Choi;Kil-Ho Cho;Sang-Lyong Kim
    • Communications for Statistical Applications and Methods
    • /
    • v.2 no.2
    • /
    • pp.20-32
    • /
    • 1995
  • The concept of positive ageing describes the adverse effects of age on the lifetime of units. Various aspects of this concept are described in terms of conditional probability distribution of residual life times, failure rates, equilibrium distributions, etc. In this paper, we will consider some partial ordering relations of life distributions under residual life functions and equilibrium distributions. Under residual life distributions, we study the relationships of IFR, NBU and NBUFR classes and that of DMRL and NBUE classes, By using WLR ordering comparison between F and its equilibrium $H_F$, we can decide if F belongs to NBUFR class.

  • PDF

Food Ethics Approach to Korean New Food Words of Years 1994-2005 (1994-2005년 한국 음식 신어에 대한 음식 윤리적 접근)

  • Kim, Suk Shin
    • Journal of the Korean Society of Food Culture
    • /
    • v.27 no.5
    • /
    • pp.445-458
    • /
    • 2012
  • This study was conducted to approach the Korean new food words for the years 1994-2005 from the stance of food ethics. The new food words were categorized into food industry, foodstuffs, cooking, various foods, processed foods, distribution, and consumer health. The principles of food ethics applied to new food words include a respect for life, justice, environmental preservation, priority of safety, and dynamic equilibrium. Seventy percent of new food words were ethically neutral, while 30% had significant ethical meaning. There were more words with a negative ethical meaning than with a positive one. All of the principles, except respect for life, could be successfully applied to new food words. Dynamic equilibrium was the most appropriate principle for the new food words, followed by a priority for safety, justice, and environmental preservation. The results of this study implied that moderation and balance is required in our modern dietary life.

Solvent Extraction of Zinc from Strong Hydrochloric Acid Solution with Alamine336

  • Lee, Man-Seung;Nam, Sang-Ho
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.7
    • /
    • pp.1526-1530
    • /
    • 2009
  • Solvent extraction reaction of Zn(II) by Alamine336 from strong HCl solution up to 10 M was identified by analyzing the data reported in the literature. The equilibrium constant of this reaction was estimated by considering the complex formation between zinc and chloride ion. The necessary thermodynamic parameters, such as equilibrium constant for the formation of complexes and the interaction parameters, were evaluated from the thermodynamic data reported in the literature. The following solvent extraction reaction and the equilibrium constant was obtained by considering the activity coefficients of solutes present in the aqueous phase with Bromley equation. $Zn^{2+}\;2Cl^{-}\;+\;R_3NHCl_{org}\;=\;ZnCl_3R_3NH_{org},\;K_{ex}\;=\;6.33\;{\times}\;10^2$ There was a good agreement between measured and calculated distribution coefficients of Zn(II).

Formation of Corporate Governance in Korea: The Rise of Chaebols (1910-1980)

  • Gwon, Jae-Hyun
    • Asian Journal of Business Environment
    • /
    • v.5 no.4
    • /
    • pp.67-72
    • /
    • 2015
  • Purpose - This aim of this study is to examine how conglomerates in Korea have evolved from the perspective of institutional economics. The growth of the economy, dominated by large conglomerates, is projected in light of the dynamic equilibrium between government and capitalists. Research design, data, and methodology - The historical formation of big business groups is examined in chronological order. For the analysis, we divide the assessment into three different eras: Japanese colonial rule, liberation up to the civil war, and the fast growing period since the military coup. Each period is viewed as a dynamic equilibrium that is shaped by economic agents. Results and Conclusion - Despite the rise of modern commerce during the colonial era, contemporary conglomerates came into being with the "enemy property" allotted by the government. Around the civil war, the government coexisted with prototype conglomerates through foreign aid. As the external aid decreased, the system could not be sustained anymore, thus the military coup took place. The reinstated strong bond between government and the conglomerates has shaped the forms of the modern conglomerates thereafter.