• Corrosion Science and Technology
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• v.14 no.5
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• pp.213-217
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• 2015

Recently, household electronic industries require environmentally-friendly and highly functional steels in order to enhance the quality of human life. Customers especially require both excellent corrosion and abrasion resistant anti-fingerprint steels for digital TV panels. Thus POSCO has developed new functional electro-galvanized steels, which have double coated layers with organic-inorganic composites on the zinc surface of the steel for usage as the bottom chassis panel of TVs. The inorganic solution for the bottom layer consists of inorganic phosphate, magnesium, and zirconium compounds with a small amount of epoxy binder, and affords both improved adhesion properties by chemical conversion reactions and corrosion resistance due to a self-healing effect. The composite solution for the top layer was prepared by fine dispersion of organic-inorganic ingredients that consist of a urethane modified polyacrylate polymer, hardener, silica sol and a titanium complex inhibitor in aqueous media. Both composite solutions were coated on the steel surface by using a roll coater and then cured through an induction furnace in the electro-galvanizing line. New anti-fingerprint steel was evaluated for quality performance through such procedures as the salt spray test for corrosion resistance, tribological test for abrasion resistance, and conductivity test for surface electric conductance regarding to both types of polymer resin and coating weight of composite solution. New composite coated anti-fingerprint steels afford both better corrosion resistance and abrasion properties compared to conventional anti-fingerprint steel that mainly consists of acrylate polymers. Detailed discussions of both composite solutions and experimental results suggest that urethane modifications of acrylate polymers of composite solutions play a key role in enhanced quality performances.

• Journal of the Korean Wood Science and Technology
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• v.34 no.2
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• pp.58-67
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• 2006

The relationship between acoustic property and coating hardness of musical instruments was investigated using a sound level meter and a pendulum hardness tester. Urethane topcoat, oil stain, natural oil varnish, and UV-curable epoxy acrylate coatings were applied on four different substrates: Paulownia coreana, Pinus koraiensis, Castanea crenata var. dulcis and Pinus densiflora. The influence of the coating type on the acoustic properties was stronger than that of the substrate. In the case of an oil stain formed with tacky coating layer, the sound pressure level (SPL) and surface hardness decreased with increasing of coating thickness. In the other coatings, SPL decreased and hardness increased as the coating layer thickened. However, SPL began to increase again at coating thickness above $100{\mu}m$.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.11
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• pp.3433-3440
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• 1996

This paper was investigation of the stres corrosion cracking(SCC) mechanism and the properties of corrosion fracture surface of glass fiber reinforced plastics(GFRP) produced by hand lay up(HLU) method in synthetic sea water. Test material is GFRP, that was used vinylester type epoxy acrylate resin and an unsaturated polyester as the matrix and the chopped strand mat(CSM) type E-glss fiber as the reinforcement. The slow strain rate test(SSRT) was performed on dry, wet and saturated wet specimens in sea water. Here the pH concentration of synthetic sea water was 8.2 and the strain rate is 1 x $10^{-6}$($sec^{-1}$) and test temperature ranges varied from $-60^{\circ}C$ to $80^{\circ}C$. It could be confirmed the fact that wet specimens tested at a particular test temperature ranges were appeared the eviences of SCC such as con-planar, mirror and hackle zone. Moreover, SCC of GFRP in sea water was characterised by falt fracture surfaces with only small amounts of fiber pull-out, in partial.

• Journal of Adhesion and Interface
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• v.11 no.2
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• pp.41-49
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• 2010

Furan-containing epoxide monomers (8, 9) were designed and synthesized as carbon-neutral, environment-friendly adhesion material. Bicyclic skeleton were constructed using the Diels-Alder reaction of furan and methyl acrylate, both readily accessible starting material from a biomass via bio-refinery process. After reduction of ester functionality, resulting hydroxyl moieties were coupled to epichlorohydrin to provide the epoxy-functionalized furanic monomers (8, 9). The structure of new furanic monomers was confirmed by $^1H$ and $^{13}C$ NMR spectroscopy. As UV-curable monomers, basic properties such as UV curing time and the extent of UV curing were evaluated by photo DSC. Photo-curing shrinkages were measured by linear variable differential transformer transducer (LVDT) and the effect of molecular structure on shrinkage was considered. In addition, new synthetic compounds showed the shear strength over 3 MPa when they were photo-cured between polycarbonate plates, which indicates these compounds are feasible to use as photo-curable adhesive materials.

• Journal of Adhesion and Interface
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• v.15 no.3
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• pp.116-122
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• 2014

This work deals with the effects of different oligomers, monomers, photoinitiators, and steel plates on the variation of gloss for UV coated steel plates at $20^{\circ}$ and $60^{\circ}$ (ASTM D523). The gloss value was more significantly varied with $20^{\circ}$ angle as compared with $60^{\circ}$. No substantial change in gloss was observed for the type of single oligomer; however, the gloss varied with the mixing ratios of oligomers, type and mixing ratio of monomers, type and concentration of photoinitiator, and type of steel plate. The maximum gloss value was observed when the mixing ratio of polyurethane acrylate (UA) to epoxy acrylate (EA) was 70 : 30, the mixing ratio of trimethylolpropantriacrylate (TMPTA) to tetrahydrofurfurylacrylate (THFA) was 5 : 5, the content of the mixed oligomer (UA : EA = 70 : 30) was 90 wt%, respectively. Darocur MBF of liquid type showed better gloss property than the solid type of Irgacure 184, and the gloss was decreased as the concentration of Darocur MBF increased from 1 to 4 wt%. Regarding the type of steel plate, GI steel plate showed better gloss property as compared with EG and primer-coated steel plates. The maximum gloss values of 95 GU and 120 GU, respectively, at $20^{\circ}$ and $60^{\circ}$ angles throughout the parametric study in the absence of leveling agents enhancing the gloss.

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.499-506
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• 2013

As the usuage of tempered glass for touch panel increased rapidly with the development of industry, the amount of UV curable coating solution used to protect glass surfaces during a tempered glass manufacturing process increased as well. The UV curable coating has advantages compared to thermal curing such as shortened curing time and non-solvent. Appropriated polymer and monomer were used as an acid polymer to grant an alkali peeling ability. The monomers were 2-hydroxyl methylacrylate, 1,6-hexanediol diacrylate and dipentaerythritol hexaacrylate which have acryl groups of 1, 2, and 6, respectively. The combination of three different types of photoinhibitors were used and bisphenol A epoxy diacrylate was used as an oligomer. In this study, experiments were carried out by controlling the amount of photoinitiator, oligomer, and additive while maintaining the constant content of the acid polymer and the acrylic monomer. The changes in physical properties according to the additive content were investigated. It was found that the combination of photoinitiators was necessary to achieve the hardness above 4H and it was possible to control the delamination type of the coating film from a sheet to pieces by the addition of TPO as an initiator. The increase in oligomer contents increased the hardness and adhesiveness alongside dissection time. Talc content of 20 wt% showed the best results.

• Journal of Dental Rehabilitation and Applied Science
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• v.33 no.4
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• pp.260-268
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• 2017

Purpose: Manufacturing with AM (Additive manufacturing) technique has many advantages; but, due to insufficient study in the area, it is not being widely used in the general clinic. In this study, differences of flexural strength among various materials of 3 unit fixed dental prosthesis were analyzed. Materials and Methods: A metal jig for specimens that had a 3-unit-fixed dental prosthesis figure were fabricated. The jigs were made appropriately to the specifications of the specimens. Three different kinds of materials of specimens which were NC (mathacrylic esther based), DP-1 (Bisphenol A epoxy acrylate type oligomer based), and DT-1 (urethane acrylate based) were printed with DLP machine. Five specimens for each kind of material were printed with an angle of $30^{\circ}$ from the horizontal surface. The specimens were placed on the jig and the flexural strength was measured and recorded using Universal testing machine. The recorded data was analyzed in SPSS using One-way ANOVA and Tukey HSD to determine the significance of the differences of flexural strength among the groups. Results: The flexural strengths of each group were the followings: NC, $1119{\pm}305$ N; DP-1, $619{\pm}150$ N; DT-1, $413{\pm}65N$. Using One-way ANOVA and Tukey Honestly Significant Difference test, significant difference was found between NC and the other groups (P < 0.05), but there was no significant difference between DP-1 and DT-1 (P > 0.05). Conclusion: Higher flexural strength was shown in 3-unit-fixed dental prosthesis that were 3D printed using a DLP machine with NC material.

• Korean Journal of Optics and Photonics
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• v.31 no.1
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• pp.13-19
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• 2020

To measure underwater acoustics using a fiber-optic Sagnac interferometric sensor, the sensitivities of ring-type probes are investigated by theoretical and experimental studies. A ring-type probe was fabricated by packaging a single-mode fiber wound around an acrylate cylinder of diameter 5 cm with epoxy bond. The probes were prepared as A-type, which was packaged with 46.84 m of sensing optical fiber, and B-type, which was packaged with 112.22 m of sensing fiber. The underwater acoustic test was performed at frequencies of 50, 70, and 90 kHz, and over a range of acoustic pressure of 20-100 Pa, to study the sensitivity. A commercial acoustic generator was located 1 m from the acoustic sensor, such as the ring-type probe or a commercial acoustic sensor. From the experimental test, the acoustic sensitivity of the ring-type probe had different values due to acoustic frequencies, unlike the theoretical prediction. Therefore, the experimental sensitivities were averaged for comparison to the theoretical values. These averaged sensitivities are 25.48 × 10^-5 rad/Pa for the A-type probe and 60.79 × 10^-5 rad/Pa for the B-type probe. The correction coefficient of Young's modulus c was determined to be 0.35.