• Title/Summary/Keyword: Epoxy composite

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Preparation of Amine-epoxy Adducts(AEA)/Thin Multiwalled Carbon Nanotubes (TWCNTs) Composite Particles using Dry Processes

  • Jung, Hyun-Taek;Cho, Young-Min;Kim, Tae-Ho;Kim, Tae-Ann;Park, Min
    • Carbon letters
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    • v.11 no.2
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    • pp.107-111
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    • 2010
  • We prepared the amine epoxy adducts (AEA)/thin multiwalled carbon nanotubes (TWCNTs) composite particles using nonsolvent based methods including dry mechano-chemical bonding(MCB) process and supercritical fluid (SCF) process. The resulting TWCNTs/AEA composite particles have been used as curing agents for urethane modified bispheol A type epoxy resin. The thermal, thermomechanical properties of the epoxy resins cured with TWCNTs/AEA composite particles were measured by DMA and the dispersion of CNT was characterized by SEM. Because of high degree of CNT dispersion, thermal and mechanical properties of the epoxy resin cured with TWCNTs/AEA composite particles prepared by SCF process are better than those cured with mechano-chemically prepared TWCNTs/AEA composite particles.

Properties of Conductive Polymer Composite Films Fabricated under High Intensity Electric Fields : Effect of CF Sizing Treatment (고전기장을 이용한 전도성 고분자 복합필름의 제조 및 특성 연구 : 탄소섬유 Sizing처리가 탄소섬유/폴리에틸렌 필름의 특성에 미치는 영향)

  • 고현협;김중현;임순호;김준경;최철림
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.293-301
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    • 2001
  • Electrically conductive carbon fiber/high density polyethylene (CF/HDPE) composite films were fabricated by new method, so called electron-ion technology (EIT) and the effects of CF epoxy sizing on the volumetric resistivity. tensile strength and interphase properties of the films were investigated. While epoxy sizing increased conductivity of composite films resulting from enhanced tunneling effect it reduced interphase adhesion between CF and HDPE because polar epoxy sizing and nonpolar HDPE are incompatible. Consequently epoxy sized CF(CF(S)) caused significant reduction in the volumetric resisitivity and tensile strength of composite films when compared with unsized CF(CF(U)). Epoxy sizing reduced nucleating efficiency of CF(S), therefore CF(S)/HDPE composite films showed nonuniform transcrystalline layer when compared with CF(U)/HDPE composite films.

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Development of Epoxy Composites with SWCNT for Highly Thermal Conductivity (고방열 재료 개발을 위한 에폭시/단일벽 탄소나노튜브 복합체 개발)

  • Kim, Hyeonil;Ko, Heung Cho;You, Nam-Ho
    • Composites Research
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    • v.33 no.1
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    • pp.7-12
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    • 2020
  • Over the past decade, liquid crystalline epoxy (LCER) has attracted much attention as a promising matrix for the development of efficient heat dissipation materials. This study presents a comprehensive study including synthesis, preparation and chacterization of polymer/inorganic composites using typical 4,4-diglycidyloxybiphenyl (DP) epoxy among LECR. To confirm the thermal conductivity of composite materials, we have prepared composite samples composed of epoxy resin and single-wall carbon nanotube (SWCNT) as a filler. In particular, DP composites exhibit higher thermal conductivity than commercial epoxy composites that use the same type of filler due to the highly ordered microstructure of the LCER. In addition, the thermal conductivity of the DP composite can be controlled by controlling the amount of filler. In particular, the DP composite containing a SWCNT content of 50 wt% has the highest thermal conductivity of 2.008 W/mK.

Study on the Thin-walled carbon nanotubes (TWNTs)/Amine epoxy additive composite via supercritical fluid process (초임계 공정을 이용한 Thin-walled carbon nanotubes (TWNTs)/아민계 에폭시 첨가제의 복합체 제조)

  • Kim, Yong-Ryeol;Jeong, Hyeon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.486-491
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    • 2014
  • We have been fabricated Thin-walled carbon nanotubes (TWNTs)/amine epoxy additives composite using Eco-friendly solvent system such as supercritical process and dry mixed process. TWNTs/amine epoxy additives composite has used as a curing agent for urethane based bisphenol A type epoxy resin. The thermo-mechanical property of the epoxy resin cured by TWNTs/amine epoxy additives composite is characterized by dynamic mechanical analysis(DMA) and dispersability of the nanotubes in the epoxy matrix is also confirmed by scanning electron microscope(SEM). As a results, the epoxy resin cured by TWNTs/amine epoxy additives composite with supercritical process shows enhanced dispersability of the TWNTs in the matrix and thermo-mechanical property when compare to dry mixed process.

A study on the optimal condition of the fabrication glass-cloth/epoxy composite material (Glass-cloth/epoxy 복합재료의 최적제작조건에 관한 연구)

  • Kwak, Young-Soon;Cho, Jung-Soo;Choi, Se-Won;Lee, Kyu-Chul;Lee, Jong-Ho
    • Proceedings of the KIEE Conference
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    • 1989.11a
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    • pp.68-71
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    • 1989
  • This paper is to investigate the optimal condition of fabrication for glass-cloth/epoxy composite material. According to the result in this paper, in fabrication of composite materials, the optimal condition of treatment for epoxy silane coupling agent is 1.5% water solution of silane coupling agent by weight. Then, % weight ratio of silane coupling agent VS, glass cloth is about 0.3%. And the optimal post cured condition of glass cloth/epoxy composite material is about 30 hours at 100$^{\circ}C$.

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Delamination of a composite laminated under monotonic loading

  • Achache, Habib;Benzerdjeb, Abdelouahab;Mehidi, Abdelkader;Boutabout, Benali;Ouinas, Djamel
    • Structural Engineering and Mechanics
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    • v.63 no.5
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    • pp.597-605
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    • 2017
  • Our work aims to analyze using the finite element method the evolution of the stress intensity factor (SIF) parameter K of three laminated folded plates stacks [$+{\alpha}$, $-{\alpha}$], made of the same epoxy matrix and different reinforcement fibers (boron, graphite and glass). Our results show that the angle of orientation of the boron/epoxy composite has no great influence on the variation of the parameter KI. Compared to composite graphite/epoxy and glass/epoxy, the laminated composite boron/epoxy reduces more the SIF KI in the middle of the plate for angles $0^{\circ}{\leq}{\alpha}{\leq}30^{\circ}$.

A Study on Improving the Fatigue Life for a Woven Glass Fabric/Epoxy Laminate Composite Applied to Railway Vehicles (철도차량용 직물 유리섬유/에폭시 적층 복합재의 피로수명 향상 방안 연구)

  • Ko, Hee-Young;Shin, Kwang-Bok;Kim, Jung-Seok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.2
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    • pp.203-209
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    • 2010
  • In this study, the fatigue characteristics and life of a woven glass fabric/epoxy laminate composite applied to railway vehicles was evaluated. The fatigue test was conducted using a tension-tension load with a stress ratio R of 0.1 and frequency of 5 Hz. Two types of woven glass fabric/epoxy laminate composite was used in the fatigue test: with and without carbon/epoxy ply reinforcement. In addition, the fatigue life of the woven glass fabric/epoxy laminate composite was compared with that of aluminum 6005, which is used in the car body and underframe structures of railway vehicles. The test results showed that the failure strength and life of the woven glass fabric/epoxy laminate composite reinforced with three carbon/epoxy plies had a remarkable improvement compared with that of the bare specimen without reinforcement.

Development of Highly Thermal Conductive Liquid Crystalline Epoxy Resins Bearing Phenylcyclohexyl Mesogenic Moieties (Phenylcyclohexyl mesogenic moieties를 함유한 고 열전도성 액정성 에폭시 수지의 개발)

  • Jeong, Iseul;Kim, Youngsu;Goh, Munju
    • Composites Research
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    • v.30 no.6
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    • pp.350-355
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    • 2017
  • The new liquid crystalline (LC) epoxy was designed by substituting the phenylcyclohexyl (PCH) mesogen moiety with an alkyl chain at the 2,5 position of the diglycidyl terephthalate. The mesomorphic properties were evaluated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). All LC epoxy derivatives exhibited an enantiotropic smectic phase upon heating and cooling process. The LC phase temperature range was widened by mixing the eutectic mixture of LC epoxies. Interestingly, the cured LC epoxy exhibited the highest thermal conductivity of $0.4W{\cdot}m^{-1}{\cdot}K^{-1}$. The novel LC epoxy with high thermal conductivity might be used as a composite material for electronic and display devices.

Enhanced Manufacturing and Performance Analysis of Flexible Composite Propeller (유연 복합재료 프로펠러 제작개선 및 성능분석)

  • Lee, Sang-Gab;Nam, Jae-Hyung;Hyun, Beom-Soo;Paik, Bu-Geun;Lee, Chang-Sup;Jang, Hyun-Gil;Nho, In Sik
    • Journal of the Society of Naval Architects of Korea
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    • v.49 no.6
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    • pp.521-527
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    • 2012
  • It is well known that flexible composite material propeller has superior radiation noise characteristics with outstanding damping effects. In this paper, three flexible composite material propellers were produced using compression molding process, and their hydrodynamic performances and radiation noise characteristics were measured. One propeller, C1, was made up from carbon/epoxy composite laminates, and the other two ones, G1 and G2, from glass/epoxy ones. Their fiber arrays were selected by the progressive damage structural analysis of propellers using composite material model MAT_162 (Composite_DMG_MSC) linked with LS-DYNA code. Carbon/epoxy and glass/epoxy composite specimen tests were performed, their damage mechanisms were figured out, and their parameters were calibrated by their progressive damage structural analysis according to their damage criteria.

Mechanical and thermal properties of MWCNT-reinforced epoxy nanocomposites by vacuum assisted resin transfer molding

  • Lee, Si-Eun;Cho, Seho;Lee, Young-Seak
    • Carbon letters
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    • v.15 no.1
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    • pp.32-37
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    • 2014
  • Multi-walled carbon nanotube (MWCNT)/epoxy composites are prepared by a vacuum assisted resin transfer molding (VARTM) method. The mechanical properties, fracture surface morphologies, and thermal stabilities of these nanocomposites are evaluated for epoxy resins with various amounts of MWCNTs. Composites consisting of different amounts of MWCNTs displayed an increase of the work of adhesion between the MWCNTs and the matrix, which improved both the tensile and impact strengths of the composites. The tensile and impact strengths of the MWCNT/epoxy composite improved by 59 and 562% with 0.3 phr of MWCNTs, respectively, compared to the epoxy composite without MWCNTs. Thermal stability of the 0.3 phr MWCNT/epoxy composite increased compared to other epoxy composites with MWCNTs. The enhancement of the mechanical and thermal properties of the MWCNT/epoxy nanocomposites is attributed to improved dispersibility and strong interfacial interaction between the MWCNTs and the epoxy in the composites prepared by VARTM.