• 마이크로전자및패키징학회지
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• 제26권2호
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• pp.1-8
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• 2019

금속, 세라믹스, 플라스틱 등 고체의 표면에 적용되는 접착제와 페인트 도장막의 수요와 중요성은 점점 증가하고 있다. 본 연구에서는 금속 피착재에 고분자 재료인 접착제 혹은 페인트 도장막을 적용할 때, 이들 고분자 코팅층과 금속 피착재 사이의 접착강도 측정시 영향인자에 대한 연구를 돌리테스트로 수행하였다. 접착제로는 2액형 에폭시 접착제가 사용되었으며, 페인트로는 방청용 2액형 에폭시 페인트인 EH2350가 사용되었다. 특히, 영향인자로는 피착재의 종류(Al, Fe, STS, Cu, Zn), 표면거칠기 및 표면오염(수돗물, 소금물) 등을 선택해서 접착강도에 미치는 영향에 대해 연구하였다. 접착제와 피착재의 접착강도는 동일한 접착제를 사용해도 피착재의 종류가 달라지면 다르게 나타났으며, 수돗물 혹은 소금물로 산화 오염된 피착재의 표면은 페인트 도장공정 이전에 수돗물로 스프레이 세척이 필수적임을 알았다. 본 연구의 결과로 돌리테스트는 도장막과 피착재의 접착강도를 측정하는데 향후 널리 사용될 수 있음을 확인하였다.

• Structural Engineering and Mechanics
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• 제55권3호
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• pp.511-523
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• 2015

Damaged steel-concrete composite girders can be repaired and retrofitted by epoxy-bonded carbon fiber-reinforced polymer (CFRP) sheets to the critical areas of tension flanges. This paper presents the results of a study on the behavior of damaged steel-concrete composite girders repaired with CFRP sheets under static loading. A total of seven composite girders made of I20A steel sections and 80mm-thick by 900mm-wide concrete slabs were prepared and tested. CFRP sheets and prestressed CFRP sheets were used to repair the specimens. The specimens lost the cross-sectional area of their tension flanges with 30%, 50% and 100%. The results showed that CFRP sheets had no significant effect on the yield loads of strengthened composite girders, but had significant effect on the ultimate loads. The yield loads, elastic stiffness, and ultimate bearing capacities of strengthened composite girders had been changed as a result of prestressed CFRP sheets, the utilization ratio of CFRP sheets could be effectively improved by applying prestress to CFRP sheets. Both the yield loads and ultimate bearing capacities had been changed as a result of steel beam's flange damage level and CFRP sheets could cover the girders' shortage of bearing capacity with 30% and 50% flange damage, respectively.

• 콘크리트학회논문집
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• 제15권5호
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• pp.739-746
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• 2003

Various researches on the application of polymer dispersions to the cement mortar and concrete have been carried out in many countries like America, Japan and Germany and so on due to their high performance and good modification effect. PAE of polymer dispersion widely used in situ was employed that the high flowability may be induced in the cement mortar. In order to investigate the modification of cement mortar with high flowability by PAE and fracture mode of adhesive strength properties in tension of that, experimental parameters were set as PAE solid-cement ratio(P/C) and cement: fine aggregate(C:F) and the experiments such as unit weight, flow, consistency change, crack resistance and segregation that inform on the general properties have been done. Adhesion in tension is measured with a view to comprehending the properties and fracture mode in tensile load. Consistency change of cement mortar modified by PAE did grow better as the ratio of PAE solid-cement increased and was much superior to that of resin based flooring such as polyurethane and epoxy which recorded the loss of consistency in 90 min. after mixing. Adhesive strength in tension increased with continuity during curing period and showed the maximum in case of C:F=1:1 and P/C=20%.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2000년도 춘계학술발표대회 논문집
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• pp.159-162
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• 2000

Interfacial and microfailure properties of carbon fiber/epoxy matrix composites were evaluated using both tensile fragmentation and compressive Broutman tests with acoustic emission (AE). Amino-silane and maleic anhydride polymeric coupling agents were used via the dipping and electrodeposition (ED), respectively. Both coupling agents exhibited higher improvements in interfacial shear strength (IFSS) under tensile tests than compressive cases. However, ED treatment showed higher IFSS improvement than dipping case under both tensile and compressive test. The typical microfailure modes including fiber break, matrix cracking, and interlayer failure were observed during tensile test, whereas the diagonal slippage in fiber ends was observed during compressive test. For both the untreated and treated cases AE distributions were separated well under tensile testing. On the other hand, AE distributions were rather closer under compressive tests because of the difference in failure energies between tensile and compressive loading. Under both loading conditions, fiber breaks occurred around just before and after yielding point. Maximum AE voltage fur the waveform of carbon or basalt fiber breakage under tensile tests exhibited much larger than those under compressive tests.

• Structural Engineering and Mechanics
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• 제67권4호
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• pp.403-415
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• 2018

In the present study, nonlinear dynamic response of polymer-CNT-fiber multiscale nanocomposite plate resting on elastic foundations in thermal environments using the finite element method is performed. In this regard, the governing equations are derived based on Inverse Hyperbolic Shear Deformation Theory and von $K{\acute{a}}rm{\acute{a}}n$ geometrical nonlinearity. Three type of distribution of temperature through the thickness of the plate namely, uniform linear and nonlinear are considered. The considered element is C1-continuous with 15 DOF at each node. The effective material properties of the multiscale composite are calculated using Halpin-Tsai equations and fiber micromechanics in hierarchy. The carbon nanotubes are assumed to be uniformly distributed and randomly oriented through the epoxy resin matrix. Five types of impulsive loads are considered, namely the step, sudden, triangular, half-sine and exponential pulses. After examining the validity of the present work, the effects of the weight percentage of SWCNTs and MWCNTs, nanotube aspect ratio, volume fraction of fibers, plate aspect, temperature, elastic foundation parameters, distribution of temperature and shape of impulsive load on nonlinear dynamic response of CNT reinforced multi-phase laminated composite plate are studied in details.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.1-2
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• 2003

While aromatic polyimides and polyamides have found widespread use as high performance polymers, the present work addressed the need for organosoluble materials through the use of a hyperbranching scheme. The $AB_2$ monomers were prepared. The $AB_2$ monomers were then polymerized via aromatic fluoride-displacement and Yamazaki reactions to afford the corresponding hydroxyl-terminated hyperbranched polyimides (HT-PAEKI) and amine-terminated hyperbranched polyamides, respectively. HT-FAEKI was then functionalized with allyl and propargyl bromides as well as epichlorohydrin to afford allyl-terminated AT-PAEKI, propargyl-terminated PT-PAEKI, and epoxy (glycidyl)-terminated ET-PAEKI, in that order. All hyperbranched poly(ether-ketone-imide)s were soluble in common organic solvents. AT-PAEKI was blended with a bisphenol-A-based bismaleimide (BFA-BMI) in various weight ratios. Thermal, rheological, and mechanical properties of these blend systems were evaluated. Two characteristic hyperbranched polyamides, which the one has para-electron donating groups to the surface amine groups and the other has para-electron withdrawing groups to the surface amine groups, were selected to compare BMI curing behaviors. The electron rich polymer displayed ordinary Michael addition type exothermic reaction, while electron deficient polymer did display unusual curing behaviors. Based on analytical data, the later system provided the strong evidences to support room temperature curing of BMI by reactive intermediates instead of reactive primary amine groups on the macromolecule surface.

• 폴리머
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• 제24권5호
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• pp.690-700
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• 2000

본 연구에서는 온도의 상승에 의하여 부피가 팽창하는 열팽창 고무 치공구의 팽창 특성을 이용하여 열경화성 복합재료를 경화하고 압축하는 과정을 실험과 모델링을 통하여 해석하였다. 열팽창 고무치공구가 사용되는 닫힌계 (fixed-volume process)와 열린계 (variable-volume process)에서 예상되는 압력을 이론적으로 유도하였고, 경화가 수반되는 과정에 있어서는 실험을 통하여 열팽창 치공구와 프리프레그가 나타내는 압력을 측정하였다. 온도가 상승하고 경화가 수반되는 경우에 등속도 압축실험에 의하여 얻어진 응력-변형율 곡선은 비선형 점탄성 특성을 보여주었는데, 본 연구에서는 Maxwell모델을 KWW (Kohlrausch-Williame-Watts)식으로 변형시킨 모델식을 이용하여 이를 매우 정확하게 표현할 수 있었다. 이 모델을 이용하여 몰드의 부피를 고정시킨 상태에서 경화시키는 닫힌계 공정에서 예상되는 압력을 예측하였으며 따라서 열팽창 치공구를 열경화성 복합재료의 경화압축 공정에 성공적으로 적용하였고 이를 해석하였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2000년도 추계학술발표대회 논문집
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• pp.79-83
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• 2000

Interfacial and microfailure properties of carbon liber/bismaleimide (BMI) composites were evaluated using both tensile fragmentation and compressive Broutman tests with acoustic emission (AE). Since BMI is rather difficult matrix to apply for the conventional fragmentation test because of its too low elongation and too brittle and high modulus properties, dual matrix composite system was applied. After carbon fiber/BMI composite was prepared for rod shape by controlling differing curing stage, composites rod was embedded in toughened epoxy as outer matrix. The typical microfailure modes including fiber break, matrix cracking, and interlayer failure were observed during tensile testing, whereas the diagonal slippage in fiber ends was observed during compressive test. On the other hand, AE amplitudes of BMI matrix fracture were higher than carbon fiber tincture under tensile test because BMI matrix has very brittle and high modulus. The waveform of signals coming from BMI matrix fractures was consistent with AE amplitude result under tensile tests.

• 접착 및 계면
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• 제21권1호
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• pp.20-26
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• 2020

Single lap-shear joints (SLJ) specimens with and without partial round fillets were fabricated to measure the average shear strength of adhesives. The effects of the length of the adherend on the SLJ specimens were also investigated. An epoxy adhesive was used to bond aluminum alloy. Tensile tests were performed on the adhesive bulk specimens to measure the mechanical properties. The finite element analysis (FEA) method was used to measure the adhesive stress distributions, i.e., the peel and shear stresses, on the bonded part. The experimental results revealed that the specimen consisting short length of adherend and without the partial round fillets exhibited the smallest average shear strength of adhesive among the investigated specimens. FEA revealed that the low average shear strength for the specimen with a short adherend length was caused by high stress concentrations on the adhesive at the edge of the bonded part.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.137-140
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• 2006

In this study, a seismic performance of reinforced concrete columns strengthened by a sprayed fiber reinforced polymer (SFRP) is investigated. For this purpose, six column specimens approximately scaled into 2/3, are designed and tested under a constant axial load, 10% of the nominal axial strength of column, and pseudo-static reversed cyclic lateral loading system. Four specimens are strengthened by Sprayed FRP using different combinations of short fibers (carbon or glass fiber) and resins (epoxy or vinyl esther). For comparison, the test investigated in this study also includes a specimen strengthened using carbon fiber reinforced polymer (CFRP), and also a control specimen without strengthening. The results revealed that specimens strengthened using SFRP showed a improved structure behavior, compared to control specimen, in terms of strength, ductility, lateral drift capacity, and energy-absorbtion capacity. In addition, compared to the specimen strengthened using CFRP, Sprayed FRP-strengthened specimens reasonably showed a equivalent seismic performance.