• Title/Summary/Keyword: Environmental water samples

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Evaluation of Organic Matter Sources of Phytoplankton in Paldang Reservoir using Stable Isotope Analysis (팔당호 내 식물플랑크톤 안정동위원소 분석을 통한 유기물 기원 평가)

  • Kim, Jongmin;Kim, Bokyong;Kim, Minseob;Shin, Kisik
    • Journal of Korean Society on Water Environment
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    • v.31 no.2
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    • pp.159-165
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    • 2015
  • The organic matter sources of phytoplankton and related environmental factors influencing algal bloom in Paldang reservoir were studied using nitrogen and carbon isotope ratio(${\delta}^{15}N$, ${\delta}^{13}C$). Phytoplankton samples for stable isotope analysis were collected from four points in reservoir using a plankton net. Physicochemical water quality, algal taxa and hydrological data were collected from published monitoring material. Phytoplankton samples were analyzed by IRMS. CN ratio of each sample was very similar to that of phytoplankton from literature cited. ${\delta}^{15}N$ of each sample was decreased during July. Mixing and dilution of nitrogen sources due to increment of influx by concentrated rainfall were considered as the main reason for the decline of ${\delta}^{15}N$. Based on analyzed ${\delta}^{15}N$ value of each sample, nitrogen source of Bughan river sample was presumed to come from soil. The nitrogen sources of Namhan river and Kyeongan stream samples seemed to be sewage or animal waste. Low ${\delta}^{15}N$ value in August (2012) seemed to be influenced by isotope fractionation due to the blooming of nitrogen-fixation blue-green algae (Anabaena spp.). Variation in ${\delta}^{15}N$ values particularly by blue-green algal bloom was considered the important factor for estimating the organic matter sources of phytoplankton.

Hydrogeochemical and geostatistical study of shallow alluvial groundwater in the Youngdeok area

  • Kim, Nam-Jin;Yun, Seong-Taek;Kwon, Man-Jae;Kim, Hyoung-Soo;Kim, Chang-Hoon;Koh, Yong-Kwon
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.232-236
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    • 2000
  • Multi-regression statistical analyses were applied for the water quality data of shallow alluvial ground water (n = 47) collected from the Youngdeok area, in order to quantitatively generalize the natural (non-anthropogenic) causes of regional water quality variation. Seven samples having the high contamination index ( $C_{a}$ > 3) reflect the striong effects by anthropogenic activity. Most of the alluvial groundwaters have acquired their quality primarily due to the dissolution of carbonate minerals. The results of multi-regression analysis show that chlorine is mainly derived from seawater effect. Sulfur isotopic compositions of dissolved sulfur and the S $O_4$/Cl ratio also enable us to discriminate the samples (n = 18) which are affected by atmospheric input of marine aerosol (sea-spray) and also by mixing between freshwater and seawater. Hydrogen and oxygen isotope data of the samples collected lie close to the local meteoric water line obtained from nearby Pohang city but has lower slope (5.45) on the $\delta$D-$^{18}$ O plot, indicating that alluvial groundwater was recharged from infiltrated meteoric water which has undergone some degree of kinetic evaporation. The estimated initial isotopic composition of the recharged water ($\delta$D = -74.8$^{0}$ /$_{00}$, $\delta$$^{18}$ O = -10.8$^{[-1000]}$ /$_{[-1000]}$ ) suggests that the alluvial ground water recharge largely occurs during summer storm events.s.s.

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A survey on the content of inorganic materials in ground-water of Northern Gyeonggi area (경기북부지역 지하수의 지역별 미량무기물질 함유실태 조사연구)

  • 오조교;손진석;배용수;정은희;박진호;황선민;정연훈
    • Journal of environmental and Sanitary engineering
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    • v.19 no.1
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    • pp.8-16
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    • 2004
  • Ground water samples were collected from residential, green" industrial, landfill and mining area and analyzed for 23 inorganics from March to October in 2002. The results are as follows; 1. The detection frequencies of inorganic materials such as As, Ba, B, Mo, Ca, Mg, Al, Cu, Fe, Mn, Zn, Na, K were 7.2∼77.1% which showed that these inorganics were detected in many ground waters. 2. The detection frequencies of 7 inorganics(Cd, Cr, Ph, Se, Sb, Be, Tl) were commonly low at ranging from 0.42 to 2.5%. These inorganics were contained in ground water partially. 3. Three inorganics such as Hg, Ni, Ag were not detected in any ground-water samples. 4. Compared to the other areas, ground water samples from landfill area contained greater concentration in many inorgainics and then showed higher levels in industral, residential, mining and green area in order. 5. Compared to noted concentrations of bottled water, inorganic minerals including Ca, Mg, Na, K related to taste were fluent in target samples. The results showed that the average concentrations of Mg, Na, K were 4.0 mg/l, 14.7 mg/l, 1.5 mg/l respectively. 6. The concentrations of inorganics such as Sb, Ba, Mo, Be, Tl, K in some ground water samples exceeded the water quality standards of WHO, the US and UK. Especially, Ba, Mo, K also showed relatively high detection frequencies so these inorganics need to be considered as analytes in Korea Drinking Water Regulation in further study.

Preparation, Characterization of activated carbon fiber (ACF) from loofah and its application in composite vertical flow constructed wetlands for Tetracycline removal from water

  • Ahmed, Sanjrani Manzoor;Zhou, Boxun;Wang, Yue;Yang, Hang;Zheng, You P.;ShiBin, Xia
    • Membrane and Water Treatment
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    • v.11 no.4
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    • pp.313-321
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    • 2020
  • ACF preparation from different materials and its application in constructed wetlands for wastewater treatment has been focused in environmental field. Different materials have been used to prepare ACF around the world. This study aims to prepare, characterize and use of ACF from loofah for removal of Tetracycline from water through composite vertical flow constructed wetlands. ACF was prepared and it was tested for characterization, later it was used for removal of Tetracycline from water through composite vertical flow constructed wetlands. In composite vertical flow constructed wetlands, three HRTs were set according to the experiment, 1D, 2D, and 3D is individually. Samples were transported immediately from collection point to laboratory for analyzing. Samples were measured for Tetracycline (TC), Total Phosphorus (TP), and Total nitrogen and COD. Tetracycline absorbance with respective 356nm was obtained good and HRT is important factor. Results show that composite vertical flow constructed wetlands with ACF from luffa is best option and it is recommended to study further deep analysis.

A Study on Heavy Metals at the Consumer s Tap in Seoul (서울市 一部 水道栓水中 重金屬에 관한 調査硏究)

  • Lee, Byung Mu
    • Journal of Environmental Health Sciences
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    • v.10 no.2
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    • pp.41-51
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    • 1984
  • This study was performed using samples collected at Myungryundong and at Reservoirs. The purpose of this study was to investigate the differences of water quality between tap and raw water, and to analyse drinking water quality by Fe, Zn from corroded galvanized steel pipe. Results were as follows 1. The older the pipe was, the higher the concentration of Ferrum and Zinc was (t-test : p<0.05). Ferrum and Zinc also exceeded the limits in the older galvanized steel pipe. I think that this comes from the corrosion of pipe. 2. Mercury, Arsenic, Cadmium, Lead, Chomium, Argentum and Aurum not detected in raw water were not detected in tap water. Cobalt, Bismuth and Molybudenum detected in raw water were not detected in tap water. I think that this comes from the quality of raw water, the result of water treatment and the improbability of detection of above metals in water delivery system. 3. Silicon measured 2.4698ppm in raw water, but it ranged from 0.4769ppm to 1.982 ppm in tap water. Manganese measured 0.0638ppm in raw water, but it ranged from 0.0026ppm to 0.0198ppm in 17cases(31%) out of 55samples in tap water. I think that this comes from the water treatment. 4. Aluminium not detected in raw water was found in 17 cases (31%) out of the samples (55cases). It may be considered as the use of coagulants $Al_2(SO_4)_3$. $18H_2O$ and PAC (Poly Aluminium Chloride). The concentration of copper in tap water was much higher in 2 cases(3.6%) out of the samples(55) than that of copper in raw water. I think that this may come from the use of ${CuSO}_4$, the preventive of algae growth, and the result of chlorination, but further study must be necoessary to support the proof.

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Occurrence and risk assessment of phenol and substituted phenols in water and fish collected from the streams in eastern Gangwon State, Korea

  • Sunyoung Park;Jaeseok Choi;Jaeyong Lee;Hekap Kim
    • Analytical Science and Technology
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    • v.36 no.5
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    • pp.224-235
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    • 2023
  • An analytical method was developed for the determination of phenol (P) and the seven substituted phenols in water samples and fish tissue samples collected from three streams located in eastern Gangwon State in spring and summer. The phenols were extracted and then derivatized to phenyl acetates using acetic anhydride. The derivatives were subsequently identified and quantified using gas chromatography coupled with mass spectrometry. P and 4-nitrophenol (4NP) were found at relatively high levels in water, ranging from below the method detection limit (MDL) to 3.32 ㎍/L and from < MDL to 4.91 ㎍/L, respectively. P and 4NP were also the dominant compounds in the fish tissue, ranging from < MDL to 407 ㎍/kg and from < MDL to 870 ㎍/kg, respectively. Phenol concentrations were significantly higher in spring than in summer. The ecological risk quotient calculated for P was higher than 4NP but not high enough to pose any risk of adverse effects to fish health.

Evaluation of Ecotoxicity and Characteristics on Indirect Effluents and Related Wastewater (간접방류사업장 관련 폐수의 생태독성수준 및 특성 평가)

  • Kim, Jongmin;Shin, Kisik;Lee, Soohyung;Lee, Jungseo;Lee, Taekjune
    • Journal of Korean Society on Water Environment
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    • v.33 no.4
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    • pp.481-486
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    • 2017
  • This paper aims to evaluate the characteristics of direct and indirect effluents'toxicity level and difference between two test durations (24 h and 48 h) of test method. The proportion of the indirect effluent samples which exceeded the ecotoxicity permit limitations (TU 1 or TU 2) showed more than 2 times higher than that of direct effluent samples. However, effluent toxicity of Wastewater Treatment Plants (WTPs) indicated less than TU 1 regardless of influent toxicity. From this results, treatment process was thought to have a good efficiency. WTP Salinity was very similar between influent and effluent. This trend could be reconfirmed by the component ratio of ion concentration between them and $Na^+$, $SO_4^{2-}$, $C^-$ lions which have a greater percentage than other ions. In addition, in case of high salinity, toxicity value also showed high level. To judge from above results, indirect effluents which were exempted from application of ecotoxicity standards, may need a new effluent limitations regardless of the treatment efficiency of WTP. According to circumstances, effective countermeasure may need to restrain the discharge of salinity-contained effluents which came from indirect-effluent factories. Test duration comparative study indicated that 48 h results were higher toxicity (exceeding rate of ecotoxicity criteria) than 24 h by the 5 to 5.4 percentage. 24 h test duration seemed to be useful in case of rapid detection, whereas 48 h test method could be applied for reinforcement of ecotoxicity regulatory system.

Assessment of Inhalation Exposure to Volatile Disinfection By-products Associated with Household Uses of Chlorinated Tap Water (가정에서의 수돗물 사용과 관련된 휘발성 염소소독부산물에 대한 흡입노출 평가)

  • 김희갑;김문숙;윤지현
    • Environmental Analysis Health and Toxicology
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    • v.17 no.2
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    • pp.125-133
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    • 2002
  • Volatile disinfection by-products (DBPs) contained in chlorinated tap water are released into household air during indoor activities (showering, cooking, dish -washing, etc.) associated with tap water uses and may cause adverse health effects on humans. Twenty seven subjects were recruited and their homes were visited during the winter of 2002. Tap water, household air, and exhaled breath samples were collected and analyzed for five volatile DBPs (chloroform, bromodichloromethane, dichloroacetonitrile, 1,1 -dichloropropanone and 1,1,1 trichloropropanone). Chloroform was a major DBP found in most samples. Tap water chloroform concentrations were not statistically correlated with its household air concentrations, probably due to individual variability in indoor activities such as showering, cooking, and dish - washing as well as household ventilation. Correlation of breath chloroform concentration with household air chloroform concentration showed its possible use as a biomarker of exposure to household air chloroform. Exposure estimates suggested that inhalation during household stay be a major route of exposure to volatile DBPs and that ingestion of tap water be a trivial contributor to the total exposure in Koreans.

36hrs Continuous Monitoring Methodology for Effluent and Receiving Water Quality (하천 수질에 대한 36시간 연속 모니터링 기법 연구)

  • 박정규;정홍배;문성환;류태권;류제영;황인영
    • Environmental Analysis Health and Toxicology
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    • v.16 no.4
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    • pp.153-159
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    • 2001
  • The main point source of pollution of the Keumho river in Taegu, Korea, stems from waste from the areas of industrial complexes . Although it is widely accepted that pollutants in waste water negatively effects general water quality, it is difficult to evaluate the effluent effect because of varying conditions in ambient water and inconclusive knowledge of causative pollutants. To analyze the water in relation to the industrial effluent in the area, pH. temperature, conductivity, and Microtox toxicity of various river samples were measured. Water samples were collected every 2 hours for 36 hours from Keumho river and Dalseo stream. Data from continuous monitoring for 36 hours showed that effluent in Keumho river originated from Dalseo stream, which is near adjacent to industrial complexes. Change in toxicity and other factors tested during the 36 hours indicated that continuous monitoring was necessary for a satisfactory effluent toxicity test Furthermore, in addition to water quality monitoring, it was concluded that sediment toxicity also needed to evaluate effluent effects.

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Primary Investigation for Evaluation of Abandoned Metal Mine Effect on Yeongsan and Seomjin Watershed (영산강.섬진강 유역 수계 폐금속광산 광해 영향 평가를 위한 개황조사)

  • Choi, Kyoung-Kyoon;Park, Ha-Seung;Oh, Da-Yeon;Kim, Kap-Soon;Huh, Yu-Jeong;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.15 no.6
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    • pp.81-90
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    • 2010
  • In this study, primary investigation for evaluation of abandoned metal mine effect on watershed has been done. 64 abandoned mines have been selected for primary investigation through literature and field survey. 216 soil and 90 water samples were collected and metal pollution concentrations were analyzed. 24 mines have mine water in the pits and acid water below pH 5 was not observed. Soils from 35 mines were over the soil basis of concern and 16 mines were over the soil basis of action. Arsenic average concentration was 188 times of average concentration of the natural background. Drinking water samples from 3 mines were over the drinking water standard and surface water samples from 12 mines were over the river water standard. Integrated pollution index, which was resulted from the integration of field survey, soil and water pollution concentration, showed that, abandoned metal mines had affected on watershed greatly in the order of Samgeum, Daedeok, Cheongdalgeum, Heungsin, Yeongdae and Myeongbong mines.