• Title/Summary/Keyword: Environmental friendly

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Influence of Radome Types on GNSS Antenna Phase Center Variation (GNSS 안테나 위상중심변동에 레이돔이 미치는 영향)

  • Yun, Seonghyeon;Lee, Hungkyu
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.38 no.1
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    • pp.11-21
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    • 2020
  • This paper deals with the impact of a GNSS (Global Navigation Satellite System) antenna radome on the PCV (Phase Center Variations) and the estimated kinematic coordinates. For the Trimble and Leica antennas, specially set up CORS (Continuously Operation Reference Stations) in Korea, the PCC (Phase Center Corrections) were calculated and compared for NONE, SCIS, SCIT, and TZGD radome from the PCV model published by the IGS (International GNSS Services). The results revealed that the PCC differences compared to the NONE were limited to about 1mm in the horizontal component while those of the vertical direction ranged from a few millimeters to a maximum of 7mm. Among the radomes of which PCV were compared, the SCIT had the most significant influence on the vertical component, and its GPS (Global Positioning System) L2 and L2 PCC (Phase Center Corrections) had opposite direction. As a result of comparing the kinematic coordinates estimated by the baseline processing of 7 CORSs with an application of the PCV models of the various radomes, the SCIS which was actually installed at CORS in Korea showed 3.4mm bias, the most substantial impact on the ellipsoidal height estimation whereas the SCIT model resulted in relatively small biases.

Polymeric Material Application for The Production of Ceramic Foam Catalyst

  • Sangsuriyan, Anucha;Yeetsorn, Rungsima;Tungkamani, Sabaithip;Sornchamni, Thana
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.21-30
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    • 2015
  • Ceramic foams are prepared as positive images corresponding to a plastic foam structure which exhibits high porosities (85-90%). This structure makes the ceramic foams attractive as a catalyst in a dry reforming process, because it could reduce a high pressure drop problem. This problem causes low mass and heat transfers in the process. Furthermore, the reactants would shortly contact to catalyst surface, thus low conversion could occur. Therefore, this research addressed the preparation of dry reforming catalysts using a sol-gel catalyst preparation via a polymeric sponge method. The specific objectives of this work are to investigate the effects of polymer foam structure (such as porosity, pore sizes, and cell characteristics) on a catalyst performance and to observe the influences of catalyst preparation parameters to yield a replica of the original structure of polymeric foam. To accomplish these objectives industrial waste foams, polyurethane (PU) and polyvinyl alcohol (PVA) foams, were used as a polymeric template. Results indicated that the porosity of the polyurethane and polyvinyl alcohol foams were about 99% and 97%. Their average cell sizes were approximate 200 and 50 micrometres, respectively. The cell characteristics of polymer foams exhibited the character of a high permeability material that can be able to dip with ceramic slurry, which was synthesized with various viscosities, during a catalyst preparation step. Next, morphology of ceramic foams was explored using scanning electron microscopy (SEM), and catalyst properties, such as; temperature profile of catalyst reduction, metal dispersion, and surface area, were also characterized by $H_2-TPR$ and $H_2-TPD$ techniques, and BET, respectively. From the results, it was found that metal-particle dispersion was relatively high about 5.89%, whereas the surface area of ceramic foam catalysts was $64.52m^2/g$. Finally, the catalytic behaviour toward hydrogen production through the dry reforming of methane using a fixed-bed reactor was evaluated under certain operating conditions. The approaches from this research provide a direction for further improvement of marketable environmental friendly catalyst production.

A Study on CFD Analysis to Investigate the Effects of Different Feed Rate into the High Temperature H2SO4 Transferring Pump at Fixed Frequency

  • Choi, Jung-Sik;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.20 no.3
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    • pp.304-311
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    • 2014
  • In this study, to apply hydrogen energy to ship engine and to generate effective hydrogen production, we investigated the effects of high temperature $H_2SO_4$ feed rate and cooling water rate to pump parts with fixed frequency needed to reciprocate motion and a simulation was conducted at each condition. In the fixed frequency and cooling water inlet flow rate of 0.5 Hz and 3.9 kg/s, we changed the high temperature $H_2SO_4$ flow rate to 47.46 kg/s (it is 105 % of 45.2 kg/s), 49.72 kg/s (110 %), and 51.98 kg/s (115 %). Also, at 0.5 Hz and 45.2 kg/s of frequency and high temperature $H_2SO_4$ flow, the thermal hydraulic analysis was performed at the condition of 95 % (3.705 kg/s), 90 % (3.51 kg/s), and 85 % (3.315 kg/s). In overall simulation cases, the physical properties of materials are more influential to the temperature increase in the pump part rather than the changes on the feed rate of high temperature $H_2SO_4$ and cooling water. A continuous operation of pump was also capable even if the excess feed of high temperature $H_2SO_4$ of about 15 % or the less feed of cooling water of about 15 % were performed, respectively. When the increasing feed of high temperature $H_2SO_4$ of up to 5 %, 10 %, and 15 % were compared with base flow (45.2 kg/s), the deviation of time period rose to a certain temperature and ranged from 0 to 4.5 s in the same position (same material). In case of cooling water, the deviation of time period rose to a certain temperature and ranged from 0 to 5.9 s according to the decreasing feed changes of cooling water at 5 %, 10 %, and 15 % compared to a base flow (3.9 kg/s). Finally, the additional researches related to the two different materials (Teflon and STS for Pitch and End-plate), which are concerned about the effects of temperature changes to the parts contacting different materials, are needed, and we have a plan to conduct a follow-up study.

Improvement Method of Sand Ground Using an Environmental Friendly Bio-grouting Material (친환경 바이오그라우팅을 이용한 모래지반 개량 공법)

  • Kim, Dae-Hyeon;Sagong, Myung;Park, Kyung-Ho
    • Journal of the Korean Society for Railway
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    • v.16 no.6
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    • pp.473-481
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    • 2013
  • The purpose of this research is to evaluate the improvements in the strength and injection range of loose ground after injecting $CaCO_3$(created by microorganism reaction). For this purpose, three cases of single-layer (Sand, SP, SW) specimens were made in a 150mm D ${\times}$ 200mm H space and two cases of multi-layer specimens (SW/SP, SP/SW) were made in a 150mm D ${\times}$ 300mm H space. The specimens were made with a relative density of 30% of soft ground and an injection was given over a time of one day. The uniaxial compression strength was measured with a cone penetrometer and the injection range was observed by checking the bulb formation around the injection nozzle. Also, the compositions of the specimens were assessed through XRD analyses. Based on the test results, a compressive strength of 500kPa and 15cm thick cementation were noted due to the cementation of the soil. This implies that there are significant effects of the pore condition and size on bio-grouting technology.

Development of Aqueous/Semi-Aqueous Cleaning Agent and its Field Application to Cleaning Process of Electronic Parts (수계/준수계 세정제의 개발 및 전자부품 세정공정 현장적용 연구)

  • Kim, Han-Seong;Cha, An-Jeong;Bae, Jae-Heum;Lee, Ha-Yeoul;Lee, Myung-Jin;Park, Byeong-Deog
    • Clean Technology
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    • v.10 no.2
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    • pp.61-72
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    • 2004
  • In this study, aqueous/semi-aqueous cleaning agents which consist of organic solvent, surfactant, cosurfactant, and water were developed by changing formulation parameters such as organic solvent type and contents, surfactant type and contents, and cosurfactant/surfactant(A/S) ratio, etc.. And physical properties and flux removal of the formulated cleaning agents have been evaluated. Also, the performance of oil-water separation from the rinse water contaminated during the cleaning process was evaluated for its recycling. The formulated cleaning agents in this work expected to have good penetration because of their low viscosity and low surface tension values of 30.2~32.5 dyne/cm. The flux removal with the terpene type cleaning agent was higher than that with hydrocarbon type cleaning agent and two commercial products (CPA(commercial product A), CPB(commercial product B)). And the performance of oil-water separation by gravity settling from the rinse water contaminated with formulated cleaning agent and soils was shown to be very good. The cleaning agents developed in this work were applied to surface mounting technology(SMT) cleaning process for manufacturing electronic parts at L electronic company. As a result, the newly developed cleaning agents showed two times better cleaning speed for removal of solder cream than the conventional ond containing ethanol and IPA(isopropyl alcohol). In addition, malodor and VOC problems generated by the previous organic cleaning agents have been solved in the manufacturing field through introduction of the non-volatile and environmental-friendly cleaning agents to the field.

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Development of Environmental-friendly N-Acyl Taurates Manufacturing Process and Evaluation of their Physical Properties (N-Acyl Taurates의 환경친화적인 제조공정 개발 및 이의 물성 연구)

  • Park, Ji Na;Song, Ah Ram;Jeong, Yong Wu;Bae, Jae Heum;Ji, Heung Jin;Lim, Ho
    • Clean Technology
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    • v.11 no.4
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    • pp.195-204
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    • 2005
  • A new condensation process for manufacturing N-acyl taurates which generates less pollutant and produces more than 60 % yield in comparison with the conventional process has been developed in this work. Its optimum process conditions are at $210{\sim}230^{\circ}C$ of reaction temperature and 6 ~ 9 hour of reaction time when Parasol 123 of petroleum refired oil is employed as process solvent and mixed catalysts of sulfonic acid and phosphoric acid are utilized as process catalyst. And the qualities of N-acyl taurates produced by this new process are similar to or better than those of imported product judging from their acid value, amine value and color. Thus, it can be said that the newly developed process for manufacturing N-acyl taurates in this work is better than the conventional process. The physical properties of N-acyl taurates produced in this work such as surface tension, foaming power, foaming stability, hard water stability, and emulsifying power etc. were compared with those of commercially available anionic surfactants. And the experimental results show that N-acyl taurates shows good physical properties and that they can be alternative to conventional anionic surfactants.

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Glycerol Carbonate Synthesis by Glycerol Oxidative Carbonylation over Copper Catalysts (구리 촉매상에서 글리세롤의 산화 카르보닐화 반응에 의한 글리세롤 카보네이트 합성)

  • Choi, Jae Hyung;Lee, Sang Deuk;Woo, Hee Chul
    • Clean Technology
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    • v.19 no.4
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    • pp.416-422
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    • 2013
  • In environmental friendly aspects, the synthesis of glycerol carbonate from glycerol using carbon monoxide and oxygen gases which were produced in petrochemical plants was studied. The oxidative carbonylation of glycerol under batch reaction system was performed on parameter conditions such as effect of various metals (Cu, Pd, Fe, Sn, Zn, Cr), oxidizing agents, mole ratio of carbon monoxide to oxygen, catalyst amount, solvent types, reaction temperature and time and dehydrating agents. In particular copper chloride catalysts showed the excellent activities, and the glycerol carbonate yields over CuCl and $CuCl_2$ catalysts were the maximum of 44% and 64%, respectively at the following reaction conditions: solvent as nitrobenzene, mole ratio of 1:3:0.15 (glycerol:carbon monoxide:catalyst), mole ratio of 2:1 (carbon monoxide:oxygen), the total pressure of 30 bar at 413 K for 4 hr. It was found that reactivity were significantly different depending on the oxidation number of Cu catalysts, and oxygen plays an important role as oxidizing agents in producing H2O during oxidation reaction after carbonylation of glycerol.

Decolorization Efficiency of Different Dyes by Extract from Spent Mushroom Substrates of Pleurotus eryngii (큰느타리(Pleurotus eryngii)의 수확 후 배지추출물을 이용한 다양한 염료의 탈색효과)

  • Lim, Seon Hwa;Kwak, A Min;Min, Gyeong Jin;Kim, Sang Su;Lee, Sang Yeop;Kang, Hee Wan
    • The Korean Journal of Mycology
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    • v.42 no.3
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    • pp.213-218
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    • 2014
  • Water extract from spent mushroom substrates (SMS) of Pleurotus eryngii was utilized in decolorization of eight synthetic dyes and wastewater from a textile factory. High laccase activity was detected in the extract of P. eryngii (SMSE). The SMSE showed that decolorization rate was 34~93% after 24 h incubation without any mediator on eight dyes including Rit-blue and Rit-red used in fiber dyeing. Dye decolorization rate more than 90% was observed on bromophenol blue and remazol brilliant blue R (RBBR). Dye in textile wastewater was decolorized at room temperature after three days by addition of P. eryngii SMSE. The results suggest that biological decolorization of dyes using the P. eryngii SMSE can be used as environmental friendly materials.

A Study on Renewable Energy Policy and Sustainable Development Strategy: German Model and Implication (재생에너지정책과 지속가능발전전략에 관한 연구: 독일모델과 시사점)

  • Park, Sang-Chul
    • Environmental and Resource Economics Review
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    • v.25 no.1
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    • pp.61-87
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    • 2016
  • Germany has carried out its environment friendly energy policy to prevent $CO_2$ emission that affects directly to the global warming phenomenon. Based on this direction, it has performed a sustainable development strategy through the R & D activities in environment and energy technologies. Accordingly, the core elements of German energy and sustainable development policies are renewable energy, ecological energy tax, and emission trading system. In particular, Germany has supported to develop renewable energy resources that prevents from consuming fossil energy resources. At the same time, it has set the ecological energy tax and initiated the emission trading system in order to support the renewable energy policy continuously. This paper analyze whether or not it is possible to generate an economic growth and a sustainable development while using renewable energy resources based on the renewable energy policy that minimize the negative effects on the environment. For that, the paper adopts Germany as a model country. In fact, it is possible to achieve the economic growth and the sustainable development if a nation can substitute increasing energy consumption for the economic growth to renewable energy resources that does not affect to the environment negatively. This model is the German energy policy and sustainable development strategy, and it is the purpose of the paper to prove it logically.

Synthesis of Prussian Blue Analogue and Magnetic and Adsorption Characteristics of MnFe2O4 (프러시안 블루 유사체의 합성 및 MnFe2O4의 자성과 흡착 특성)

  • Lee, Hye-In;Kang, Kuk-Hyoun;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.67-74
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    • 2016
  • The Prussian Blue Analogue(PBA) has three dimensional structure and the metal - organic framework material, and it has a variety configurations depending on the type of organic ligands. PBA has been receving an attention in the fields of biosensors, optical, catalytic, and hydrogen storage device. Also, it is an environmental friendly substance with a chemical stability. In addition, PBA is widely used in the filed of adsorption art since we can adjust the size of the fine pores. In this study, we synthesized $Mn_3[Fe(CN)_6]_2$, an organometallic framework chains by using a hydrothermal synthesis method. We used $K_4[Fe(CN)_6]$ and $MnCl_2$ as precursors. We also produced a manganese iron oxide, by baking the synthesized material. The effect of the size and shape of the particles was examined by controling pH of the precursor solution, the molar concentration of the precursor, and reaction time as the experimental variables. Synthesized absorbent was analyzed by XRD, SEM, FT-IR, UV-Vis, and TG / DTA to evaluate the adsorption properties of several dyes.