• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.749-756
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• 2019

Na-X and Na-A zeolites that give high adsorption capacity for heavy metals in an aqueous system were synthesized from the coal fly ash obtained from a thermoelectric power plant using a fusion method. The characteristics and Cu(II) adsorption capacity of the synthetic zeolites were also compared to those of using a commercial zeolite. For the selection of optimum conditions of zeolite synthesis, the effects of major parameters in the fusion method such as a dosage ratio of NaOH, aging time, hydrothermal reaction time, and also the dosage ratio of NaAlO₂ (Na-A) on the characteristics and Cu(II) adsorption capacity of the synthetic zeolites were studied. For the analysis of characteristics of the synthetic zeolites, X-ray diffraction (XRD), cation exchange capacity (CEC), Brunaue-Emmett-Teller (BET) and scanning electron microscopy (SEM) were used. The optimum conditions for the synthesis of zeolites with a high adsorption capacity for cationic heavy metals including Cu(II) were the aging time of 6 h, hydrothermal reaction time of 6 h and NaOH and NaAlO₂ dosage ratio of 1.5 and 0.5 (Na-A), respectively. According to the Langmuir isotherm test, maximum Cu(II) adsorption capacities of the synthetic and commercial Na-X and Na-A zeolites were found to be 90.1, 105.26, 102.05, and 109.89 mg/g, respectively. This indicates that the adsorption capacity of synthetic zeolites was comparable to commercial ones. The results of this study also suggest that the coal fly ash can be potentially used as a raw material for the zeolite synthesis.

• Proceedings of the Korean Environmental Health Society Conference
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• 2003.06a
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• pp.9-23
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• 2003

ㆍ These are not accidents ㆍ They are “unplanned incidents” that had multiple, obvious causes(both minor and egregious) ㆍ Prevention would have involved no more than good safety and good management practices ㆍ The outcome was predicable, and included loss of life, loss of prduction capacity, civil lawsuits, and OSHA citations.

• Proceedings of the Korea Environmental Mutagen Society Conference
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• 2002.05a
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• pp.93-93
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• 2002

• Journal of the Korean GEO-environmental Society
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• v.18 no.9
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• pp.19-31
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• 2017

In case of USA, the drilled shaft and the driven pile in the field showed a good correlation in the analysis of the bearing capacity between the dynamic load test and the static load test. However, in Korea, we mainly install the bored pile, which is not widely used overseas and we tried to confirm the reliability of the dynamic load test on the bored pile, because many people questioned the reliability of it. In this study, load tests were carried out on PHC bored piles in LH field (Cheonan, Incheon, Uijeongbu), and the bearing capacity of the dynamic load test (EOID 7times, Restrike 7times) and the static load test (7times) were compared and analyzed. As a result, the average of the bearing capacity of the static load test was 27% higher than that of the dynamic load test (reliability : 0.73, coefficient of variation : 0.3). And the average of the bearing capacity of the static load test (Davisson) was 27% higher than that of the bearing capacity of the dynamic load test (Davisson) (reliability : 0.73, coefficient of variation : 0.2). To reduce the difference between the bearing capacity of the dynamic load test and the static load test, we proposed modified bearing capacity of dynamic load test (base bearing capacity of EOID + skin frictional force of restrike) and difference between the bearing capacities was reduced to 9% (reliability : 0.91, coefficient of variation : 0.2). And the coefficient of variation was reduced to 0.2 and the consistency of analysis increased.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.27 no.1
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• pp.17-32
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• 2022

The buffer capacity of southern Korean waters in summer was quantified using data set of temperature, salinity, dissolved inorganic carbon, total alkalinity obtained from August 2020 cruise. The geographical distribution and variability of six buffer factors, which amended the existing Revelle factor, are discussed their relationship with the hydrological parameters of temperature and salinity. The calculated results of six buffer factors showed the spatial variations according to the distributions of various water masses. The buffer capacity was low in the East Sea Surface Mixed Water (ESMW) and South Sea Surface Mixed Water (SSMW) where upwelling occurred, and showed an intermediate value in the Yellow Sea Surface Water (YSSW). In addition, the buffer capacity increased in the order of high temperature Tsushima Warm Current (TWC) and Changjiang Diluted Water (CDW). This means that the Changjiang discharge water in summer strengthens the buffer capacity of the study area. The highest buffer capacity of CDW is due to its relatively higher temperature and biological productivity, and a summer stratification. Temperature showed a good positive correlation (R²=0.79) with buffer capacity in all water masses, whereas salinity exhibited a poor negative correlation (R²=0.30). High temperature strengthens buffer capacity through thermodynamic processes such as gas exchange and distribution of carbonate system species. In the case of salinity, the relationship with buffer capacity is reversed because salinity of the study area is not controlled by precipitation or evaporation but by a local freshwater input and mixing with upwelled water.

• Environmental Engineering Research
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• v.19 no.2
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• pp.157-163
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• 2014

The adsorption of Cr(VI) from aqueous solutions to activated carbon fiber (ACF) was investigated using both batch and flow-through column experiments. The batch experiments (adsorbent dose, 10 g/L; initial Cr(VI) concentration, 5-500 mg/L) showed that the maximum adsorption capacity of Cr(VI) to ACF was determined to 20.54 mg/g. The adsorption of Cr(VI) to ACF was sensitive to solution pH, decreasing from 9.09 to 0.66 mg/g with increasing pH from 2.6 to 9.9; the adsorption capacity was the highest at the highly acidic solution pHs. Kinetic model analysis showed that the Elovich model was the most suitable for describing the kinetic data among three (pseudo-first-order, pseudo-second-order, and Elovich) models. From the nonlinear regression analysis, the Elovich model parameter values were determined to be ${\alpha}$ = 162.65 mg/g/h and ${\beta}$ = 2.10 g/mg. Equilibrium isotherm model analysis demonstrated that among three (Langmuir, Freundlich, Redlich-Peterson) models, both Freundlich and Redlich-Peterson models were suitable for describing the equilibrium data. In the model analysis, the Redlich-Peterson model fit was superimposed on the Freundlich fit. The Freundlich model parameter values were determined to be $K_F$ = 0.52 L/g and 1/n = 0.56. The flow-through column experiments showed that the adsorption capacities of ACF in the given experimental conditions (column length, 10 cm; inner diameter, 1.5 cm; flow rate, 0.5 and 1.0 mL/min; influent Cr(VI) concentration, 10 mg/L) were in the range of 2.35-4.20 mg/g. This study demonstrated that activated carbon fiber was effective for the removal of Cr(VI) from aqueous solutions.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.5
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• pp.879-886
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• 2000

$H_2S$ adsorption characteristics of activated carbon adsorbent impregnated with NaOH were investigated. The concentrations of NaOH reagent were 1~8N and the particle size of activated carbon was $8{\times}30$ mesh. The experimental results showed that the BET surface area decreases from $1050m^2/g$ to $783m^2/g$ and acidity of activated carbon decreases from 0.541 meq/g-AC to 0 meq/g-AC, while pH increases from 9.56 to 10.86 when the impregnation ratio increases from 0.87% to 5.8%. It was also found that the $H_2S$ adsorption equilibrium capacity of activated carbon impregnated with NaOH increases with increasing temperature and $H_2S$ concentration and varies in the range of 17.87~30.34 mg/g-AC at adsorption temperature of $45^{\circ}C$, which is 2~3 times larger than that of pure activated carbon.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.18 no.6
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• pp.51-60
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• 2015

This study conducted shear strength test and plate bearing test to look into the characteristics of bearing capacity using geosynthetics case on forest road surface. The shear strength test showed that the internal friction angle at the time when geosynthetics was used was measured larger on average than that in the unreinforced case. Therefore, using geosynthetics case produced more bearing capacity reinforcement effect. The result from the comparison test of internal friction angle by geosynthetics type revealed that the internal friction angle at the time when geotextile case was used was measured larger. That was attributable to the difference between the area of the total cross section of geotextile made in type of non-woven fabric and its material. Plate bearing test showed that the settlement at the time when geosynthetics was used was measured smaller than that in the unreinforced case. Therefore, using geosynthetics produced more bearing power reinforcement effect. The result from the comparison test showed that geogrid case was measured smaller than geotextile case. Henceforth, It is seemed that it will be necessary to keep studying the reinforcement engineering and process of forest road surface which fits the characteristics and conditions of geosynthetics to prevent forest road demage.

• Journal of the Korean Geotechnical Society
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• v.33 no.1
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• pp.67-77
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• 2017

In the present study, uplift load carrying behavior of micropiles with installation angle and pile spacing was investigated based on uplift load tests using single and group micropiles. In addition, evaluation methods of uplift load carrying capacity of group micropiles were proposed based on FHWA (2005) and Madhav (1987) and they were compared with test results to confirm the validity of proposed methods. From the test results, uplift load carrying capacities of single and group micropiles increased with the increase of the installation angle up to $30^{\circ}$, whose values also increased slightly with increasing pile spacing. For the proposed method based on FHWA (2005), the estimated values were similar to measured values up to $15^{\circ}$ of installation angle and 5D of pile spacing. For the proposed method based on Madhav (1987), on the other hand, it was observed that the estimated values were in good agreement with measured values in all installation conditions.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.9
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• pp.686-691
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• 2011

The $CO_2$ adsorption and characteristics of mesoporous silica MCM-41 impregnated by MEA (Monoethanolamine) were examined in this study. The adsorbents were characterized by XRD (X-ray powder diffraction), FT-IR (Fourier transform infrared spectroscopy), $N_2$ adsorption-desorption isotherms. $CO_2$ adsorption measurements were carried out using a GC-TCD unit using 15% $CO_2$ gas. The $CO_2$ adsorption capacity of MCM-41 increased by MEA contents to 10~40 wt%, otherwise MEA content of 50 wt% was decreased $CO_2$ adsorption capacity. The amines tended to deform at MCM-41 surface if too many amines were provided. Therefore $CO_2$ adsorption capacity can be decreased. The results of this study suggest it is important to control content of MEA in MCM-41 for adsorption of $CO_2$.